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2013 Fiscal Year Final Research Report

Structure engineering of functional solid catalysts by unit-network methodology

Research Project

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Project/Area Number 23246135
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionHokkaido University

Principal Investigator

UEDA Wataru  北海道大学, 触媒化学研究センター, 教授 (20143654)

Co-Investigator(Kenkyū-buntansha) TAKEGUCHI Tatsuya  北海道大学, 触媒化学研究センター, 准教授 (30227011)
SHIMIZU Kenichi  北海道大学, 触媒化学研究センター, 准教授 (60324000)
MURAYAMA Toru  北海道大学, 触媒化学研究センター, 助教 (60583531)
Co-Investigator(Renkei-kenkyūsha) SADAKANE Masahiro  広島大学, 工学研究科, 准教授 (10342792)
KAMIYA Yuichi  北海道大学, 地球環境科学研究院, 准教授 (10374638)
Project Period (FY) 2011-04-01 – 2014-03-31
Keywords複合酸化物 / 高次構造 / 細孔構造 / ソフト合成 / 固体触媒
Research Abstract

Structure engineering of functional solid catalysts has been conducted on the basis of unit-network methodology of molecular-type polyoxide units under hydrothermal condition for creating three-dimensional network structure of the units. The methods were applied to metal oxide components in 6, 5 and 4 element group and successfully gave various solids with nano-size structure with a heptagonal structural unit, confirming the applicability of the method for creating high-dimensional solid structures. This method was also found useful for creating a new three-dimensional zeolite-type porous solid based on molecular-type polyoxide units. The materials are totally new and showed unique adsorption property for CO2 and ethane. These obtained materials showed solid-acid property and incomparable catalytic property based on an asymmetric porous structure.

  • Research Products

    (18 results)

All 2014 2013 2012 2011

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (7 results) Book (1 results)

  • [Journal Article] Tetrahedral Connection of ε -Keggin-type Polyoxometalates To Form an All-Inorganic Octahedral Molecular Sieve with an Intrinsic 3D Pore System2014

    • Author(s)
      Z. X. Zhang, M. Sadakane, T Murayama, S. Izumi, N. Yasuda, N. Sakaguchi, W. Ueda
    • Journal Title

      Inorg. Chem.

      Volume: 53 Pages: 903-911

    • Peer Reviewed
  • [Journal Article] Layered Perovskite Oxide : A Reversible Air Electrode for Oxygen Evolution/Reduction in Rechargeable Metal-Air Batteries2013

    • Author(s)
      T. Takeguchi, T. Yamanaka, H. Takahashi, H. Watanabe, T. Kuroki, H. Nakanishi, Y. Orikasa, Y. Uchimoto, H. Takano, N. Ohguri , M. Matsuda, T. Murota, K. Uosaki , and W. Ueda
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 135(30) Pages: 11125-11130

    • Peer Reviewed
  • [Journal Article] Synthesis of novel orthorhombic Mo and V based complex oxides coordinating alkylammonium cation in its heptagonal channel and their application as a catalyst2013

    • Author(s)
      S. Ishikawa,T. Murayama, S. Ohmura, M. Sadakane, W. Ueda
    • Journal Title

      Chemistry of Materials

      Volume: 25 Pages: 2211-2219

    • Peer Reviewed
  • [Journal Article] Single-Crystalline-Phase Mo3VOx : An Efficient Catalyst for the Partial Oxidation of Acrolein to Acrylic Acid2013

    • Author(s)
      C. Chen, N. Kosuke. T. Murayama, W. Ueda
    • Journal Title

      Chem CatChem

      Volume: 5(10) Pages: 2869-2873

    • Peer Reviewed
  • [Journal Article] An orthorhombic Mo3VOx catalyst most active for oxidative dehydrogenation of ethane among related complex metal oxides2013

    • Author(s)
      T. Konya, T Katou, T, Murayama, S, Ishikawa, M, Sadakane, D, Buttrey, W, Ueda
    • Journal Title

      Catalysis Science & Technology

      Volume: 3 Pages: 380-387

    • Peer Reviewed
  • [Journal Article] Establishment of crystalline complex Mo-V-oxides as selective oxidation catalysts2013

    • Author(s)
      W. Ueda
    • Journal Title

      J. Japan Petro. Inst.

      Volume: 56 Pages: 122-132

    • Peer Reviewed
  • [Journal Article] Assembly of a Pentagonal Polyoxomolybdate Building Block, [Mo6O21]6-, into Crystalline MoV Oxides2013

    • Author(s)
      M. Sadakane, K. Endo, K. Kodato, S. Ishikawa,; T. Murayama, W. Ueda
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 10-11 Pages: 1731-1736

    • Peer Reviewed
  • [Journal Article] Hydrothermal synthesis of W-Nb complex metal oxides and their application to catalytic dehydration of glycerol to acrolein2013

    • Author(s)
      K. Omata, S. Izumi, T. Murayama, W. Ueda
    • Journal Title

      Catal. Today

      Volume: 201 Pages: 7-11

    • Peer Reviewed
  • [Journal Article] Synthesis of porous and acidic complex metal oxide catalyst based on group 5 and 6 elements2012

    • Author(s)
      T. Murayama, N. Kuramata, S. Takatama, K. Nakatani, S. Izumi, X. Yi, W. Ueda
    • Journal Title

      Catalysis Today

      Volume: 185 Pages: 224-229

    • Peer Reviewed
  • [Journal Article] Redox tunable reversible molecular sieves : Orthorhombic molybdenum vanadium oxide2011

    • Author(s)
      M. Sadakane, S. Ohmura, K. Kodato, T. Fujisawa, K. Kato, K. Shimidzu, T. Murayama, W. Ueda
    • Journal Title

      Chem. Commun.

      Volume: 47 Pages: 10812-10814

    • Peer Reviewed
  • [Presentation] New Octahedral Molecular Sieve Constructed by Polyoxometalates and Bismuth Linkers with Zeolite-like 3D Micropores2013

    • Author(s)
      Z.X. Zhang S, Izumi T, Murayama, W. Ueda
    • Organizer
      APCAT-6
    • Place of Presentation
      台北インターナショナルコンベンションセンター(台湾)
    • Year and Date
      2013-10-17
  • [Presentation] 層構造を有する W-Ti-O複合酸化物の水熱合成およびその酸触媒活性2013

    • Author(s)
      平田純 村山徹 上田渉
    • Organizer
      第62回石油学会研究発表会
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2013-05-28
  • [Presentation] 界面活性剤を用いた結晶性 Mo-V-O複合酸化物の合成および低級アルカン選択酸化活性2012

    • Author(s)
      石川理史、 Yi Xiaodong、村山徹、上田渉
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学 (福岡県)
    • Year and Date
      2012-09-25
  • [Presentation] 三方晶 Mo-V-O複合酸化物の構造解析と酸化触媒活性2012

    • Author(s)
      小林大地、石川理史、村山徹、上田渉
    • Organizer
      第110回触媒討論会
    • Place of Presentation
      九州大学 (福岡県)
    • Year and Date
      2012-09-25
  • [Presentation] Mo3VOX with High Dimensional Structures as True Active Phase for Catalytic Acrolein Oxidation and Ethane Oxidation2011

    • Author(s)
      T. Murayama, K. Nakatani, T. Konya, and W. Ueda
    • Organizer
      Europacat X
    • Place of Presentation
      グラスゴー(イギリス)
    • Year and Date
      20110828-0902
  • [Presentation] Catalytic oxidation property of Mo3VOX in unit network structure with pore2011

    • Author(s)
      W. Ueda, T. Murayama, K. Nakatani, T. Konya
    • Organizer
      ADHOC2011
    • Place of Presentation
      Bankoku Shinryokan(沖縄)
    • Year and Date
      20110703-08
  • [Presentation] Synthesis of porous and acidic complex metal oxide catalyst based on group 5 and 6 elements2011

    • Author(s)
      T. Murayama, N. Kuramata, S. Takatama, K. Nakatani, S. Izumi, X. Yi, W. Ueda
    • Organizer
      The 13th Korea-Japan Symposium on Catalysis
    • Place of Presentation
      済州島(韓国)
    • Year and Date
      20110423-25
  • [Book] Comprehensive Inorganic Chemistry II, Vol. 7 Oxford: Elsevier2013

    • Author(s)
      M. Sadakane, Y. Kamiya, W, Ueda
    • Total Pages
      185-204
    • Publisher
      Heteropoly Compounds

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Published: 2015-06-25  

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