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2013 Fiscal Year Final Research Report

Developement of New Synthetic Methods for Nitrogen-containing Compounds

Research Project

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Project/Area Number 23350041
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionKyoto University

Principal Investigator

MURAKAMI Masahiro  京都大学, 工学(系)研究科(研究院), 教授 (20174279)

Project Period (FY) 2011-04-01 – 2014-03-31
Keywords有機合成 / 反応開発 / 遷移金属触媒 / 含窒素化合物
Research Abstract

In this project, we have embarked on the development of new synthetic methods for nitrogen-containing compounds by exploiting transition metal catalysis. For example, we have developed (1) methods to incorporate nitrogen and oxygen, carbon, sulfur into unsaturated molecules, (2) new methods to generate reactive metallacycles and their synthetic applications, (3) new methods to synthesize nitrogen heterocycles via cleavage of a carbon–hydrogen bond. These new methods offer efficient ways to nitrogen-containing compounds that are otherwise difficult to access.

  • Research Products

    (14 results)

All 2014 2013 2012 2011 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (3 results) Remarks (1 results)

  • [Journal Article] Intramolecular Dearomatizing [3+2] Annulation of α-Imino Carbenoids with Aryl Rings Furnishing 3,4-Fused Indole Skeletons2014

    • Author(s)
      Tomoya Miura, Yuuta Funakoshi, and Masahiro Murakami
    • Journal Title

      J. Am. Chem. Soc

      Volume: 136 Pages: 2272-2275

    • DOI

      10.1021/ja412663a

    • Peer Reviewed
  • [Journal Article] Enantioselective Synthesis of anti-Homoallylic Alcohols from Terminal Alkynes and Aldehydes Based on Concomitant Use of Cationic Iridium Complex/Chiral Phosphoric Acid2013

    • Author(s)
      Tomoya Miura, Yui Nishida, Masao Morimoto, and Masahiro Murakami
    • Journal Title

      J. Am. Chem. Soc

      Volume: 135 Pages: 11497-11500

    • DOI

      10.1021/ja405790t

    • Peer Reviewed
  • [Journal Article] Pyridine-Directed Palladium-Catalyzed Phosphonation of C(sp2)-H Bonds2013

    • Author(s)
      Changkun Li, Takaaki Yano, Naoki Ishida, and Masahiro Murakami
    • Journal Title

      Angew. Chem., Int. Ed

      Volume: 52 Pages: 9801-9804

    • DOI

      10.1002/anie.201305202

    • Peer Reviewed
  • [Journal Article] Stereoselective Synthesis of 2,3-Dihydropyrroles from Terminal Alkynes, Azides, and α,β-Unsaturated Aldehydes via N-Sulfonyl-1,2,3-triazoles2013

    • Author(s)
      Tomoya Miura, Takamasa Tanaka, Kentaro Hiraga, Scott G. Stewart, and Masahiro Murakami
    • Journal Title

      J. Am. Chem. Soc

      Volume: 135 Pages: 13652-13655

    • DOI

      10.1021/ja407166r

    • Peer Reviewed
  • [Journal Article] 1,5-Rhodium Shift in Rearrangement of N-Arenesulfonylazetidin-3-ols into Benzosultams2013

    • Author(s)
      Naoki Ishida, Yasuhiro Shimamoto, Takaaki Yano, and Masahiro Murakami
    • Journal Title

      J. Am. Chem. Soc

      Volume: 135 Pages: 19103-19106

    • DOI

      10.1021/ja410910s

    • Peer Reviewed
  • [Journal Article] Synthesis of α-Amino Ketones from Terminal Alkynes via Rhodium-Catalyzed Denitrogenative Hydration of N-Sulfonyl-1,2,3-triazoles2012

    • Author(s)
      Tomoya Miura, Tsuneaki Biyajima, Tetsuji Fujii, and Masahiro Murakami
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 194-196

    • DOI

      10.1021/ja2104203

    • Peer Reviewed
  • [Journal Article] Synthesis of Enaminones by Rhodium-Catalyzed Denitrogenative Rearrangement of 1-(N-Sulfonyl-1,2,3-triazole-4-yl)alkanol s2012

    • Author(s)
      Tomoya Miura, Yuuta Funakoshi, Masao Morimoto, Tsuneaki Biyajima, and Masahiro Murakami
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 17440-17443

    • DOI

      10.1021/ja308285r3

    • Peer Reviewed
  • [Journal Article] Rhodium-Catalyzed Ring Opening of Benzocyclobutenols with Site-Selectivity Complementary to Thermal Ring Opening2012

    • Author(s)
      Naoki Ishida, Shota Sawano, Yusuke Masuda, and Masahiro Murakami
    • Journal Title

      J. Am. Chem. Soc

      Volume: 134 Pages: 17502-17504

    • DOI

      10.1021/ja309013a

    • Peer Reviewed
  • [Journal Article] Solar-Driven Incorporation of Carbon Dioxide into α-Amino Ketones2012

    • Author(s)
      Naoki Ishida, Yasuhiro Shimamoto, and Masahiro Murakami
    • Journal Title

      Angew. Chem., Int. Ed

      Volume: 51 Pages: 11750-11752

    • DOI

      10.1002/anie.201206166

    • Peer Reviewed
  • [Journal Article] One-Pot Procedure for the Introduction of Three Different Bonds onto Terminal Alkynes through N-Sulfonyl-1,2,3-Triazole Intermediates2012

    • Author(s)
      Tomoya Miura, Takamasa Tanaka, Tsuneaki Biyajima, Akira Yada, and Masahiro Murakami
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 52 Pages: 3883-3886

    • DOI

      10.1002/anie.201209603

    • Peer Reviewed
  • [Presentation] Multi-Functionalization of Terminal Alkynes2013

    • Author(s)
      Masahiro Murakami
    • Organizer
      Catalysis and Fine Chemicals 2013 (C&FC 2013)
    • Place of Presentation
      Renmin University of China
    • Year and Date
      2013-12-03
  • [Presentation] Formal σ-bond Metathesis between C-C Bonds and Organosilicons Catalyzed by Palladium2013

    • Author(s)
      Naoki Ishida
    • Organizer
      International Symposium on Olefin Metathesis and Related Chemistry (ISOM2013)
    • Place of Presentation
      Todaiji-temple Lecture Hall Nara
    • Year and Date
      2013-07-16
  • [Presentation] Construction of Carbon Frameworks through Cleavage of Carbon-Carbon Single Bonds2011

    • Author(s)
      Masahiro Murakami
    • Organizer
      10th International Symposium on Organic Reaction (ISOR10)
    • Place of Presentation
      Keio University
    • Year and Date
      2011-11-23
  • [Remarks]

    • URL

      http://www.sbchem.kyoto-u.ac.jp/murakami-lab/

URL: 

Published: 2015-06-25  

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