2013 Fiscal Year Final Research Report
Efficient syntheses and functions of highly self-assembled metallamacrocycles
| Project/Area Number |
23550085
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Kinki University |
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Principal Investigator |
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| Project Period (FY) |
2011 – 2013
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| Keywords | Cu(I)錯体 / エチレン付加体 / 配位高分子 / メタラマクロサイクリック / アニオンレセプター / 自己組織化 / 分子認識 / アニオンテンプレート |
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| Research Abstract |
The C2H4 and CO adducts of novel Cu(I) coordination polymers and metallamacrocycles were self-assembled by the combinations of precursor Cu(I) complexes with different counter anions and the related 4,4'-bipyrimidine ligands. The roles of counter anions and reaction solvents were systematically proved in the formation processes. These new compounds are expected to become as a potential anion receptor. In addition, polymeric Cu(I)-{C2H4, CO} adducts should be contributed to study the chemical adsorption and the catalytic reaction sites.
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