2013 Fiscal Year Final Research Report
Control of Boron Functionality Introduction Reactions Through B-H Bond Activation and Their Applications
| Project/Area Number |
23550113
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Kitami Institute of Technology |
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Principal Investigator |
MURATA Miki 北見工業大学, 工学部, 教授 (40271754)
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| Project Period (FY) |
2011 – 2013
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| Keywords | 錯体・有機金属触媒 |
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| Research Abstract |
We investigated metal-catalyzed cross-coupling reactions of B-H compounds, which provides a direct method for conversion of C-X bonds or C-H bonds to C-B bonds. The present studies introduced several hydroboranes to participate in the catalytic borylation of aryl halides. For example, the reaction with a diazaborole showed the high level of functional group compatibility due to the low Lewis acidity. In addition, the present studies gave us some interesting information on the control of regioselectivity in the catalytic C-H borylations.
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