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2013 Fiscal Year Final Research Report

Comprehensive research about an extraction of improving factor for hydrogen absorption/desorption properties and high functionality of laminate type hydrogen storage alloys

Research Project

  • PDF
Project/Area Number 23560794
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Physical properties of metals
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

KOJI Tanaka  独立行政法人産業技術総合研究所, ユビキタスエネルギー研究部門, 主任研究員 (40357439)

Co-Investigator(Kenkyū-buntansha) TAKESHITA Hiroyuki  関西大学, 化学生命工学部, 教授 (20351497)
Co-Investigator(Renkei-kenkyūsha) MIYAMURA Hiroshi  滋賀県立大学, 工学部, 准教授 (90275165)
Project Period (FY) 2011 – 2013
Keywords積層型 / 水素吸蔵合金 / 水素吸蔵・放出特性 / 向上因子 / 初期水素化 / 競合反応 / 初期構造
Research Abstract

3 reactions have happened during the initial hydrogenation of Mg/Cu super-laminate composites: (1) a hydrogenation of Mg, (2) an alloying Mg with Cu to Mg2Cu, (3) a hydrogenation of Mg2Cu formed through an alloying Mg with Cu. There exist 3 reaction processes depending on the timing of the reaction (1). : The reaction (1) occurs earlier than the reaction (2), earlier than the reaction (3), or later than the reaction (3). The three reaction processes make 3 types of microstructures different from each other. And about a hydrogenation of Mg, an incubation time does not appear although a clear incubation time appears during a dehydrogenation of MgH2.

  • Research Products

    (12 results)

All 2014 2013 2012

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (8 results)

  • [Journal Article] Micro/Nano-Structural Transition and Hydrogen Absorption Mechanism in Mg/Cu Super-Laminate Composites2014

    • Author(s)
      Koji Tanaka, Hiroyuki T. Takeshita, Ho Shin, Kosuke Kurumatani,Tetsu Kiyobayashi, Nobuhiko Takeichi, Hiroshi Miyamura and Shiomi Kikuchi
    • Journal Title

      Materials Transactions

      Volume: 55

    • URL

      http://www.jim.or.jp/journal/e/

    • Peer Reviewed
  • [Journal Article] Hydrogen Absorption and Desorption Behavior of Magnesium Hydride : Incubation Period and Reaction Mechanism2014

    • Author(s)
      Nobuhiko Takeichi, Yasuhiro Sakaida, Tetsu Kiyobayashi and Hiroyuki T. Takeshita
    • Journal Title

      Materials Transactions

      Volume: 55

    • URL

      http://www.jim.or.jp/journal/e/

    • Peer Reviewed
  • [Journal Article] MgCu_2の水素化特性:Mg/Cu超積層体の水素化におけるMgCu_2の生成機構について2013

    • Author(s)
      柴田和也、田中孝治、車谷孝介、近藤亮太、竹下博之
    • Journal Title

      日本金属学会誌

      Volume: 77 Pages: 631-635

    • URL

      http://www.jim.or.jp/journal/j/77/12/631-635.html

    • Peer Reviewed
  • [Journal Article] "The effect of initial structures of Mg/Cu super-laminates on hydrogen absorption/desorption properties2013

    • Author(s)
      Koji Tanaka, Hiroyuki T. Takeshita, Kosuke Kurumatani, Hiroshi Miyamura, Shiomi Kikuchi
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 580 Pages: S222–S225

    • DOI

      10.1016/j.jallcom.2013.03.155

    • Peer Reviewed
  • [Presentation] A Variety of Microstructures in Mg/Cu Super-laminate Composites Caused by Competitive Reactions during Hydrogenation2014

    • Author(s)
      Koji Tanaka
    • Organizer
      The 14th International Symposium on Metal-Hydrogen Systems
    • Place of Presentation
      Dresden, Germany
    • Year and Date
      2014-08-25
  • [Presentation] Formation Mechanism of Micro/nano-structures through Competitive Reactions in Mg/Cu Super-laminate Composites during Initial Hydrogenation2014

    • Author(s)
      Koji Tanaka
    • Organizer
      The 14th International Symposium on Metal-Hydrogen Systems
    • Place of Presentation
      Manchester, UK.
    • Year and Date
      2014-07-22
  • [Presentation] 積層型水素吸蔵合金の水素吸蔵・放出特性と微細構造2014

    • Author(s)
      田中孝治
    • Organizer
      2014年(第154回)日本金属学会春期講演大会
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都)
    • Year and Date
      2014-03-22
  • [Presentation] Relation between hydrogenation properties and initial microstructures for Mg-Cu super-laminate composites prepared by accumulative cold rolling2013

    • Author(s)
      Hiroyuki Takeshita
    • Organizer
      7th International Symposium in Science and Technology
    • Place of Presentation
      Penang, Malaysia
    • Year and Date
      2013-08-30
  • [Presentation] Evidence for Existence and Generality of Competitive Reactions during Hydrogenation of Mg/Cu Super-laminate Composites2013

    • Author(s)
      Koji Tanaka
    • Organizer
      8th Pacific Rim International Congress on Advanced Materials and Processing (PRICM-8)
    • Place of Presentation
      Waikoloa, Hawaii, USA
    • Year and Date
      2013-08-06
  • [Presentation] Proposal for Formation Mechanism of Microstructures in Mg/Cu Super-laminate Composites Related to Competitive Reactions during Hydrogenation2013

    • Author(s)
      Koji Tanaka
    • Organizer
      XIV International Conference on Intergranular and Interphase Boundaries in Materials (iib2013)
    • Place of Presentation
      Sithonia, Halkidiki, Greece
    • Year and Date
      2013-06-26
  • [Presentation] About Changes of Hydrogen Absorption/desorption Properties depending on the Initial Structures of Mg/Cu Super-laminates2012

    • Author(s)
      Koji Tanaka
    • Organizer
      International Symposium on Metal-Hydrogen Systems -Fundamentals and Applications-
    • Place of Presentation
      京都テルサ(京都府)
    • Year and Date
      2012-10-22
  • [Presentation] Effects of Initial Structures of Mg/Cu Super-laminates on Hydrogen Absorption/desorption Properties2012

    • Author(s)
      Koji Tanaka
    • Organizer
      The 2nd Asian Symposium on Hydrogen Storage Materials 2012
    • Place of Presentation
      済州島、大韓民国
    • Year and Date
      2012-04-23

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Published: 2015-07-16  

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