Synthesis of heat-resistant alloy nanoparticles in aprotic solvent

2013 Fiscal Year Final Research Report

• Project/Area Number: 23560855
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Structural/Functional materials
• Research Institution: National Institute for Materials Science
• Principal Investigator: ABE Hideki 独立行政法人物質・材料研究機構, 環境再生材料ユニット, 主幹研究員 (60354156)
• Project Period (FY): 2011 – 2013
• Keywords: 超耐熱合金 / 粉末冶金 / ナノ粒子 / 前期遷移金属 / 液相反応 / 常温常圧 / ニッケル / アルミニウム

Research Abstract

We have established a synthetic method for the alloy nanoparticles (NPs, particle size =< 100 nm) which comprise Al or early d-metals and nickel or platinum: Ni-Al NPs, AlPt3 NPs, ZrPt3 NPs, NbPt3 NPs and TaPt3 NPs. These alloy NPs will be breakthrough materials for defects-free, super-heat-resistant products.

Research Products

• [Journal Article] Synthesis and electrocatalytic performance of atomically ordered nickel carbide (Ni_3C)nanoparticles (2014)
  • Author(s): Nor A. Fadil, Govindachetty Saravanan, Gubbala V. Ramesh, Futoshi Matsumoto, Hideki Yoshikawa, Shigenori Ueda, Toyokazu Tanabe, Toru Hara, Shinsuke Ishihara, Hideyuki Murakami, Katsuhiko Ariga and Hideki Abe
  • Journal Title: Chemical Communications Volume: 50 Pages: 6451-6453
  • DOI: 10.1039/c4cc01336k
  • Peer Reviewed
• [Journal Article] NbPt_3 Intermetallic Nanoparticles : Highly Stable and COTolerant Electrocatalyst for Fuel Oxidation (2014)
  • Author(s): Gubbala V. Ramesh, Rajesh Kodiyath, Toyokazu Tanabe, Maidhily Manikandan, Takeshi Fujita, Futoshi Matsumoto, Shinsuke Ishihara, Shigenori Ueda, Yoshiyuki Yamashita, Katsuhiko Ariga, and Hideki Abe
  • Journal Title: ChemElectroChem Volume: 1 Pages: 728-732
  • DOI: 10.1002/celc.201300240
  • Peer Reviewed
• [Journal Article] Wet Chemical Synthesis of Ni-Al Nanoparticles at Ambient Condition (2012)
  • Author(s): N. Fadil, G. Saravanan, H. Yoshikawa, Y. Yamashita, S. Ueda, K. Kobayashi, T. Tanabe, T. Hara, V. Gubbala, H. Murakami, Noda kazuhiko, H. Abe
  • Journal Title: ADVANCED MATERIALS RESEARCH Pages: 442-447, 557-559
  • DOI: 10.4028/www.scientific.net/AMR5
  • Peer Reviewed
• [Journal Article] Post-synthesis Dispersion of Metal Nanoparticles by Poly(amidoamine) Dendrimers : Size-selective Inclusion Water Solubilization (2012)
  • Author(s): G. Saravanan, T. Hara, H. Yoshikawa, Y. Yamashita, S. Ueda, K. Kobayashi, H. Abe
  • Journal Title: CHEMICAL COMMUNICATIONS Volume: 48 Pages: 7441-7443
  • DOI: 10.1039/C2CC31039B
  • Peer Reviewed
• [Presentation] Ordered Early-d-metal Alloy Nanoparticles : Stable, CO-tolerant and High-performance Catalysts for Environmental/energy Applications (2014)
  • Author(s): H. Abe
  • Organizer: AAMSD-2014
  • Place of Presentation: Nagpur, INDIA
  • Year and Date: 2014-01-17
• [Presentation] 有機-金属ハイブリッド燃料電池触媒 (2013)
  • Author(s): 阿部英樹
  • Organizer: ポリマーフロンティア21
  • Place of Presentation: 東京都(13-4)
  • Year and Date: 2013-10-18
• [Presentation] Intermetallic Pt_3Ti Nanoparticles : CO-poisoning Tolerant Electrocatalyst for the Polymer-membrane Electrolyte Fuel Cells (2013)
  • Author(s): Saravanan Govindachetty, V. Gubbala, R. Kodiyath, T. Tanabe, Matsumoto Futoshi, S. Ueda, S. Ishihara, K. Ariga, H. Abe
  • Organizer: India-Japan Symposium on Frontiers in Science & Technology
  • Place of Presentation: 東京都
  • Year and Date: 2013-10-11
• [Presentation] Interstitial Carbon Activates Transition Metals for Energy-conversion Catalysis (2012)
  • Author(s): N. Fadil, G. Saravanan, F. Matsumoto, H. Yoshikawa, Y. Yamashita, S. Ueda, K. Kobayashi, T. Tanabe, T. Hara, V. Gubbala, S. Ishihara, H. Murakami, K. Noda, K. Ariga, H. Abe
  • Organizer: Indian-Japan Symposium on Frontier in Science and Technology
  • Place of Presentation: 東京都
  • Year and Date: 2012-09-20
• [Presentation] Wet Chemical Synthesis of Ni-Al Nanoparticles at Ambient Condition (2012)
  • Author(s): N. Fadil, G. Saravanan, H. Yoshikawa, Y. Yamashita, S. Ueda, K. Kobayashi, T. Tanabe, T. Hara, V. Gubbala, H. Murakami, Kazuhiko NODA, H. Abe
  • Organizer: The 2012 Int. Con. on Chemical Engineering and Advanced Material
  • Place of Presentation: Guangzhou, CHINA
  • Year and Date: 2012-07-13
• [Presentation] 触媒材料の価電子状態を手掛かりとした排ガス清浄化活性の理解と予測 (2011)
  • Author(s): 阿部英樹, SARAVANAN Govindachetty, 吉川英樹, 許亜, 原徹, 山下良之, 上田茂典, 小林啓介
  • Organizer: 日本金属学会第4回触媒材料研究会
  • Place of Presentation: 宮城県
  • Year and Date: 2011-09-01
• [Patent(Industrial Property Rights)] 白金合金ナノ粒子、その製造方法、 白金合金ナノ粒子含有電極及び燃料電池 (2013)
  • Inventor(s): 阿部英樹, グバラベンカタラメシュ, 田邊豊和, コディヤ ス ラジェッシュ, マニカンダン マイディリ, 有賀克彦, 石原伸輔
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 特許願2013-245982号
  • Filing Date: 2013-11-28
  • Overseas
• [Patent(Industrial Property Rights)] 小径Ni_3Cナノ粒子及びその製 造方法、小径Ni_3Cナノ粒子含有電極触媒及びその製造方法 (2012)
  • Inventor(s): 阿部英樹, ノール アクマル フ ァディル, 村上秀之, 吉川英樹, 山下良之, 上田茂典, 田邊豊和, グバラベンカタラメッシュ, サラバナンゴビンダッチャリ, 有賀克彦, 石原伸輔
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 特許願2012-256243号
  • Filing Date: 2012-11-22
  • Overseas
• [Patent(Industrial Property Rights)] 非水溶媒中の無電解めっき方法 (2012)
  • Inventor(s): 阿部英樹, 村上秀之, ファデルノルアクマル, サラバナンゴバンダチェティ, 田邊豊和, グバラベンガタラメシュ
  • Industrial Property Rights Holder: 物質・材料研究機構
  • Industrial Property Number: 特許願2012-115600号
  • Filing Date: 2012-05-21
  • Overseas