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2013 Fiscal Year Final Research Report

Study on sonochemistry and sonoluminescence in a microreactor

Research Project

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Project/Area Number 23560917
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Reaction engineering/Process system
Research InstitutionThe University of Electro-Communications

Principal Investigator

HATANAKA Shin-ichi  電気通信大学, 大学院情報理工学研究科, 助教 (40334578)

Co-Investigator(Kenkyū-buntansha) TUZIUTI Toru  独立行政法人産業技術総合研究所, 計測フロンティア研究部門, 主任研究員 (70357515)
YASUI Kyuichi  独立行政法人産業技術総合研究所, 先進製造プロセス研究部門, 主任研究員 (30277842)
Co-Investigator(Renkei-kenkyūsha) KOZUKA Teruyuki  独立行政法人産業技術総合研究所, 先進製造プロセス研究部門, 主任研究員 (60357001)
Project Period (FY) 2011 – 2013
Keywordsマイクロリアクター / ソノケミストリー(超音波化学) / ソノルミネッセンス(音響発光) / ソノケミルミネッセンス(音響化学発光) / 音響キャビテーション / 気泡ダイナミクス / シングルバブル / ヒドロキシルラジカル定量
Research Abstract

Sonochemistry, chemical effects of ultrasound, in a microreactor was studied by a microfluidic experiment using a 0.1 mm x 0.1 mm microchannel and a single-bubble cavitation experiment. The microfluidic results demonstrated that, at relatively low levels of power density, selecting a solution of dissolved gas degree of saturation (DOS) in the supersaturation range at atmospheric pressure resulted in higher yields per unit volume in the 1D space compared to that obtained from the 3D space. This effect is attributed to a decrease in the cavitation threshold of the 1D reaction system. The single-bubble results showed that the hydroxyl radical amount for a dancing bubble, where the single bubble was dancing below the lower threshold of pressure amplitude for sonoluminescence, was greater than that for a stable bubble. The results imply that the instability of bubbles significantly enhances sonochemical efficiency in liquid phase.

  • Research Products

    (8 results)

All 2014 2013 2012 2011

All Journal Article (4 results) (of which Peer Reviewed: 2 results) Presentation (4 results) (of which Invited: 3 results)

  • [Journal Article] 外部からの超音波照射によるマイクロ流路内の化学反応2014

    • Author(s)
      辻内亨
    • Journal Title

      超音波テクノ

      Volume: Vol. 26、No. 2 Pages: 54-58

    • URL

      http://www.nikko-pb.co.jp/products/detail.php?product_id=3247

  • [Journal Article] Influence of Degree of Gas Saturation on Sonochemiluminescence Intensity Resulting from Microfluidic Reactions2013

    • Author(s)
      Toru Tuziuti
    • Journal Title

      J. Chem. Phys. A

      Volume: Vol. 117,No. 41 Pages: 10598–10603

    • DOI

      10.1021/jp407068n

    • Peer Reviewed
  • [Journal Article] Sonoluminescence, sonochemistry and bubble dynamics of single bubble cavitation2012

    • Author(s)
      Shin-ichi Hatanaka
    • Journal Title

      AIP Conf. Proc.

      Volume: Vol. 1474 Pages: 163-166

    • DOI

      10.1063/1.4749322

    • Peer Reviewed
  • [Journal Article] シングルバブル・キャビテーションの気泡ダイナミクスとラジカル生成量の関係2012

    • Author(s)
      畑中信一
    • Journal Title

      超音波テクノ

      Volume: Vol. 24、No. 2 Pages: 7-12

    • URL

      http://www.nikko-pb.co.jp/products/detail.php?product_id=2714

  • [Presentation] Effect of gases on radical production rate during single-bubble cavitation2013

    • Author(s)
      Shin-ichi Hatanaka
    • Organizer
      21^st International Congress of Acoustics (ICA2013)
    • Place of Presentation
      Palais des congrès de Montréal
    • Year and Date
      2013-06-07
  • [Presentation] 音響キャビテーション気泡のダイナミクスとソノルミネッセンス・ソノケミストリーの関係2012

    • Author(s)
      畑中信一
    • Organizer
      第16回オーガナイズド混相流フォーラム(OMF2012)
    • Place of Presentation
      松山市道後温泉葛城
    • Year and Date
      2012-12-07
    • Invited
  • [Presentation] ソノルミネッセンス気泡のダイナミクスとラジカル生成速度の関係2012

    • Author(s)
      畑中信一
    • Organizer
      第4回超音波とマイクロバブルの相互作用に関するシンポジウム
    • Place of Presentation
      名古屋駅前イノベーションハブ
    • Year and Date
      2012-01-20
    • Invited
  • [Presentation] Relationship between sonoluminescence, radical production and cavitation dynamics2011

    • Author(s)
      Shin-ichi Hatanaka
    • Organizer
      The 20^<th> annual meeting of Japan Society of Sonochemistry & The International Workshop on Advanced Sonochemistry
    • Place of Presentation
      名古屋大学
    • Year and Date
      2011-11-04
    • Invited

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Published: 2015-07-16  

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