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2013 Fiscal Year Final Research Report

Development of nano-structured novel reaction space

Research Project

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Project/Area Number 23560928
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionChiba University

Principal Investigator

ICHIKUNI Nobuyuki  千葉大学, 工学(系)研究科(研究院), 准教授 (40261937)

Project Period (FY) 2011 – 2013
Keywordsナノクラスター / ニッケル触媒 / 酸化コバルト触媒 / XAFS / TEM / コロイド
Research Abstract

Less than a few nanometer size particle (nanocluster; NC) of non-precious metals, such as nickel and cobalt, was prepared and applied to the catalyst. Ni-NC and Co-NC showed the activity toward the coupling of thiophenol, water gas shift reaction, oxidation reaction of carbon monooxide. The remarkable NC size dependency on the reaction was revealed.

  • Research Products

    (13 results)

All 2014 2013 2012 2011

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (10 results)

  • [Journal Article] XAFS and HAADF STEM combined characterization for size regulated Ni nanocluster catalyst and its unique size dependence for water gas shift reaction2014

    • Author(s)
      Hirotake Kitagawa, Nobuyuki Ichikuni, Hanako Okuno, Takayoshi Hara, Shogo Shimazu
    • Journal Title

      Applied Catalysis A:General

      Volume: 478 Pages: 66-70

    • DOI

      10.1016/j.apcata.2014.03.031

    • Peer Reviewed
  • [Journal Article] Size control of Ni nanocluster by the carbon chain length of secondary alkoxide2012

    • Author(s)
      Hirotake Kitagawa, Nobuyuki Ichikuni, Songhai Xie, Tatsuya Tsukuda, Takayoshi Hara, Shogo Shimazu
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

      Volume: 10 Pages: 648-650

    • DOI

      10.1380/ejssnt.2012.648

    • Peer Reviewed
  • [Journal Article] Preparation and Catalysis of Supported NiO Nanocluster for Oxidative Coupling of Thiophenol2012

    • Author(s)
      Nobuyuki Ichikuni, Osamu Tsuchida, Jun Naganuma, Takayoshi Hara, Hironori Tsunoyama, Tatsuya Tsukuda, Shogo Shimazu
    • Journal Title

      Transactions of the Materials Research Society of Japan

      Volume: 37(2) Pages: 177-180

    • Peer Reviewed
  • [Presentation] 酸素前処理温度による酸化コバルトナノクラスターのCO酸化反応活性の変化2014

    • Author(s)
      藤井俊希, 一國伸之, 奥野華子, 井上泰徳, 中島清隆, 原亨和, 原孝佳, 島津省吾
    • Organizer
      第94日本化学会春季年会(2H3-42)
    • Place of Presentation
      名古屋
    • Year and Date
      2014-03-28
  • [Presentation] アルミナ担持Niナノクラスターによる水性ガスシフト反応のサイズ依存性2013

    • Author(s)
      一國伸之, 北川裕丈, 原孝佳, 島津省吾
    • Organizer
      第112回触媒討論会(1I13)
    • Place of Presentation
      秋田
    • Year and Date
      2013-09-18
  • [Presentation] コロイドを前駆体とした酸化コバルトナノクラスターの調製とCO酸化反応2013

    • Author(s)
      藤井俊希, 一國伸之, 原孝佳, 島津省吾
    • Organizer
      第112回触媒討論会(1I02)
    • Place of Presentation
      秋田
    • Year and Date
      2013-09-18
  • [Presentation] Preparation of size regulated Ni nanocluster catalyst by using alcoholate stabilized Ni colloid and its application for WGSR2013

    • Author(s)
      Hirotake Kitagawa, Nobuyuki Ichikuni, Takayoshi Hara, Shogo Shimazu
    • Organizer
      XIth European Congress on Catalysis (P2-T2-61)
    • Place of Presentation
      Lyon, FRANCE
    • Year and Date
      2013-09-03
  • [Presentation] ナノクラスター化による担持ニッケル触媒の高機能化2012

    • Author(s)
      一國伸之
    • Organizer
      岩澤コンファレンス2012「サステイナブル社会のための最先端触媒化学・表面科学」
    • Place of Presentation
      神戸
    • Year and Date
      2012-10-31
  • [Presentation] 二級アルコキシド保護基の炭素鎖長によるアルミナ担持Niナノクラスターのサイズ制御2012

    • Author(s)
      北川裕丈, 一國伸之, 謝頌海, 佃達哉, 原孝佳, 島津省吾
    • Organizer
      第110回触媒討論会(1G21)
    • Place of Presentation
      福岡
    • Year and Date
      2012-09-24
  • [Presentation] Preparation and catalysis of the alkoxide-stabilized Ni nanocluster catalyst, Nobuyuki Ichikuni2012

    • Author(s)
      Jun Naganuma, Hironori Tsunoyama, Tatsuya Tsukuda, Takayoshi Hara, Shogo Shimazu
    • Organizer
      XAFS theory workshop : XAFS theory and nano particles (oral)
    • Place of Presentation
      Chiba, JAPAN
    • Year and Date
      2012-07-20
  • [Presentation] Preparation of Alkoxide-Stabilized Ni Nanocluster Catalyst on Oxide Support and Its Catalysis for WGSR2012

    • Author(s)
      Nobuyuki Ichikuni, Jun Naganuma, Hironori Tsunoyama, Tatsuya Tsukuda, Takayoshi Hara, Shogo Shimazu
    • Organizer
      15th ICC2012 (1.05_6867)
    • Place of Presentation
      Munich, GERMANY
    • Year and Date
      2012-07-04
  • [Presentation] アルコキシド保護基を用いたアルミナ担持Niナノクラスター触媒の炭素鎖長依存性2012

    • Author(s)
      北川裕丈, 一國伸之, 佃達哉, 原孝佳, 島津省吾
    • Organizer
      第92日本化学会春季年会(1G1-02)
    • Place of Presentation
      横浜
    • Year and Date
      2012-03-25
  • [Presentation] 担持NiOナノクラスター触媒の調製とチオフェノールの酸化的カップリング反応2011

    • Author(s)
      一國伸之, 土田理, 長沼純, 原孝佳, 角山寛規, 佃達哉, 島津省吾
    • Organizer
      第21回日本MRS学術シンポジウム(M-05)
    • Place of Presentation
      横浜
    • Year and Date
      2011-12-20

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Published: 2015-07-16  

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