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2013 Fiscal Year Final Research Report

Anomalous Aggregation of Inorganic Anions into Ionic Nanostructures

Research Project

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Project/Area Number 23651091
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Nanostructural science
Research InstitutionOsaka University

Principal Investigator

TAKUMI KONNO  大阪大学, 理学(系)研究科(研究院), 教授 (50201497)

Co-Investigator(Renkei-kenkyūsha) NAKAZAWA Yasuhiro  大阪大学, 大学院・理学研究科, 教授 (60222163)
Project Period (FY) 2011 – 2012
Keywordsイオン結晶 / 自己組織化
Research Abstract

In this study, the creation of ionic nanostructures, in which complex cations are self-assembled through various, multiple non-covalent interactions accompanied by the unusual aggregation of inorganic anions into the interstices surrounded by cationic molecular aggregates, was investigated. This study evidenced that the introduction of multiple non-covalent interactions can lead to the aggregation of complex cations and that the close-packed arrangement of the created cationic aggregates in crystal results in the aggregation of a number of inorganic anions in its interstices.

  • Research Products

    (15 results)

All 2013 2012 2011 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (4 results) Remarks (1 results)

  • [Journal Article] Disproportionation of Achiral Nickel(II) Centers into Two Kinds of Chiral Nickel(II) Centers Caused by an Achiral Diimine Ligand2013

    • Author(s)
      A. Igashira-Kamiyama, A. Fukushima, and T. Konno
    • Journal Title

      Chem. Eur. J

      Volume: 19 Pages: 16532-16536

    • DOI

      10.1002/chem.201303731

    • Peer Reviewed
  • [Journal Article] Conversion of L-Cysteinato Rh^<III>_4Zn^<II>_4 Octanuclear to Rh^<III>_2Ag^I_3 Pentanuclear Structure by Ag^I Ions2013

    • Author(s)
      U. Yamashira, P. Lee, N. Kuwamura, N. Yoshinari, and T. Konno
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 86 Pages: 1450-1452

    • DOI

      10.1246/bcsj.20130200

    • Peer Reviewed
  • [Journal Article] A 1 : 1 intercluster compound consisting of +6 and -6 charged Rh^<III>_4Zn^<II>_4 octanuclear cations and anions with aminothiolate ligands2013

    • Author(s)
      N. Yoshinari, U. Yamashita, and T. Konno
    • Journal Title

      CrystEngComm

      Volume: 15 Pages: 10016-10019

    • DOI

      10.1039/C3CE41800F

    • Peer Reviewed
  • [Journal Article] Heteroleptic Palladium(II) Complexes with Mixed Thiol- and Sulfide-Containing Amino Acids : Self-assembly of Novel Heptanuclear Coordination Oligomers2013

    • Author(s)
      A. Yokoi, N. Yoshinari, and T. Konno
    • Journal Title

      Chem. Lett

      Volume: 42 Pages: 885-887

    • DOI

      10.1246/cl.130318

    • Peer Reviewed
  • [Journal Article] Halide-Controlled Construction and Structural Determination of A Series of Thiolato-Bridged 16-Nuclear Copper(I) Clusters from Benzothiazoline2012

    • Author(s)
      Y. Takino, N. Yoshinari, K. Tsuge, T. Kawamoto, and T. Konno
    • Journal Title

      Chem. Lett

      Volume: 41 Pages: 334-336

    • DOI

      10.1246/cl.2012.334

    • Peer Reviewed
  • [Journal Article] Aggregation of Chiral Hexanuclear Complex-cations into Cationic Metallosupramolecules with Concomitant Aggregation of Inorganic Counter-anions into Anionic Clusters2012

    • Author(s)
      R. Lee, A. Igashira-Kamiyama, H. Motoyoshi, and T. Konno
    • Journal Title

      CrystEngComm

      Volume: 14 Pages: 1936-1938

    • DOI

      10.1039/c2ce06539h

    • Peer Reviewed
  • [Journal Article] Thiolato-Bridged Au^I_2Cu^I_2 and Cu^I_4 Metallorings Derived from Benzothiazoline : Can Gold(I) Plus Copper(I) Make Silver(I)?2012

    • Author(s)
      Y. Takino, N. Yoshinari, T. Kawamoto, and T. Konno
    • Journal Title

      Chem. Lett

      Volume: 41 Pages: 834-836

    • DOI

      10.1246/cl.2012.834

    • Peer Reviewed
  • [Journal Article] A Remarkable Enantioselectivity of an L-Cysteinato Co^<III>_3 Complex-anion Toward a Racemic 2-Aminoethanethiolato Co^<III>_2Ag^I_3 Complex-cation2011

    • Author(s)
      H. Q. Yuan, A. Igashira-Kamiyama, and T. Konno
    • Journal Title

      Chem. Lett

      Volume: 40 Pages: 285-287

    • DOI

      10.1246/cl.2011.285

    • Peer Reviewed
  • [Journal Article] Metal-Crossing between Thiolato-Bridged Tetragold(I) and Tetrasilver(I) Metallorings2011

    • Author(s)
      Y. Takino, K. Tsuge, A. Igashira-Kamiyama, T. Kawamoto, and T. Konno
    • Journal Title

      Chem. Asian J

      Volume: 6 Pages: 2931-1935

    • DOI

      10.1002/asia.201100668

    • Peer Reviewed
  • [Journal Article] Self-assembly of D-Penicillaminato M_6M'_8 (M = Ni^<II>, Pd^<II>, Pt^<II>; M' = Cu^I, Ag^I) Clusters and Their Organization into Extended La^<III>M_6M'_8 Supramolecular Structures2011

    • Author(s)
      N. Yoshinari, and T. Konno
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 12191-12200

    • DOI

      10.1039/c1dt10778j

    • Peer Reviewed
  • [Presentation] Metallosupramolecular Architectures Controlled by Metal-Center Chirality of L-Cysteinato Cobalt(III) Octahedrons2013

    • Author(s)
      T. Konno, T, Aridomi, N. Yoshinari, and A. Igashira-Kamiyama
    • Organizer
      25th International Symposium on Chirality
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2013-07-07
  • [Presentation] Self-organization of D-Penicillaminato Metal Clusters into Metallosupramolecular Architectures2012

    • Author(s)
      T. Konno, and N. Yoshinari
    • Organizer
      2012 Collaborative Conference on Crystal Growth
    • Place of Presentation
      Orland, USA
    • Year and Date
      2012-12-13
  • [Presentation] Creation of Supramolecular Architectures Based on Chiral Gold(I) Metalloligands2012

    • Author(s)
      T. Konno
    • Organizer
      40 International Conference on Coordination Chemistry
    • Place of Presentation
      Valencia, Spain
    • Year and Date
      2012-09-10
  • [Presentation] 含硫アミノ酸をもつ金(I)錯体の配位化学2011

    • Author(s)
      今野巧
    • Organizer
      錯体化学会第61回討論会
    • Place of Presentation
      岡山大学
    • Year and Date
      2011-09-17
  • [Remarks]

    • URL

      http://www.chem.sci.osaka-u.ac.jp/lab/konno/

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Published: 2015-06-25  

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