2012 Fiscal Year Final Research Report
Development of Carbon-Carbon Bond Formation Reaction via Formation of Chiral Ion Pair
| Project/Area Number |
23655083
|
|---|
| Research Category |
Grant-in-Aid for Challenging Exploratory Research
|
| Allocation Type | Multi-year Fund |
|---|
| Research Field |
Synthetic chemistry
|
|---|
| Research Institution | Osaka University |
|---|
Principal Investigator |
BABA Akio 大阪大学, 大学院・工学研究科, 教授 (20144438)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
NISHIMOTO Yoshihiro (30550115)
|
|---|
| Project Period (FY) |
2011 – 2012
|
| Keywords | 有機合成化学 |
|---|
| Research Abstract |
The coupling reaction of alcohol-derivatives with enol acetates was accomplished. This reaction is accelerated by a catalytic amount of indium trihalide to afford various types of α-alkylated ketones and aldehydes. Alkyl ethers, alkyl acetates, and silyl ethers were applicable to this reaction system.
|
-
-
-
-
-
-
-
-
-
-
-
[Journal Article] Stabilization of Excited State Using Through-Space Interaction between Independent π-Systems Mediated by a peri-Substituted Hydroxy Group in 1-Arylnaphthalenes: Unexpected Blue Emission of 1,3,5-Tris(peri-hydroxynaphthyl)benzene2011
Author(s)
Nakajima, H.; Yasuda, M.; Shimizu, K.; Toyoshima, N,; Tsukahara, Y.; Kobayashi, T.; Nakamura, S.; Chiba, K.; Baba, A
-
Journal Title
Bull. Chem. Soc. Jpn.
Volume: 84
Pages: 1118-1129
DOI
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
[Presentation]2011
Author(s)
Onishi, Y.; Nishimoto, Y.; Yasuda, M.; Baba, A.
Organizer
The Seventh International Symposiumon Integrated Synthesis (ISIS-7)
Place of Presentation
Kobe, Japan
Year and Date
20111009-10
-
-
-
