2012 Fiscal Year Final Research Report
Development of Carbon-Carbon Bond Formation Reaction via Formation of Chiral Ion Pair
| Project/Area Number |
23655083
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Synthetic chemistry
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| Research Institution | Osaka University |
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Principal Investigator |
BABA Akio 大阪大学, 大学院・工学研究科, 教授 (20144438)
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| Co-Investigator(Renkei-kenkyūsha) |
NISHIMOTO Yoshihiro (30550115)
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| Project Period (FY) |
2011 – 2012
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| Keywords | 有機合成化学 |
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| Research Abstract |
The coupling reaction of alcohol-derivatives with enol acetates was accomplished. This reaction is accelerated by a catalytic amount of indium trihalide to afford various types of α-alkylated ketones and aldehydes. Alkyl ethers, alkyl acetates, and silyl ethers were applicable to this reaction system.
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Research Products
(31 results)
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[Journal Article] Stabilization of Excited State Using Through-Space Interaction between Independent π-Systems Mediated by a peri-Substituted Hydroxy Group in 1-Arylnaphthalenes: Unexpected Blue Emission of 1,3,5-Tris(peri-hydroxynaphthyl)benzene2011
Author(s)
Nakajima, H.; Yasuda, M.; Shimizu, K.; Toyoshima, N,; Tsukahara, Y.; Kobayashi, T.; Nakamura, S.; Chiba, K.; Baba, A
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Journal Title
Bull. Chem. Soc. Jpn.
Volume: 84
Pages: 1118-1129
DOI
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[Presentation]2011
Author(s)
Onishi, Y.; Nishimoto, Y.; Yasuda, M.; Baba, A.
Organizer
The Seventh International Symposiumon Integrated Synthesis (ISIS-7)
Place of Presentation
Kobe, Japan
Year and Date
20111009-10
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