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2012 Fiscal Year Final Research Report

A study for the sum-frequency-selected-detection of circular polarized luminescenc

Research Project

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Project/Area Number 23655113
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionTohoku University

Principal Investigator

ARAKI Yasuyuki  東北大学, 多元物質科学研究所, 助教 (80361179)

Project Period (FY) 2011 – 2012
Keywords蛍光円二色性
Research Abstract

In this study, we tried to establish a new detection method of circular polarized luminescence (CPL), and the application of fluorescence sum frequency detection method. At first, a newly synthesized chiral perylenediimide dimer indicating the CPL for the purpose of this study. We have performed a sum frequency selective CPL detection and obtained the basic knowledge for the study future development. Moreover, using the photon counting method with a streak scope, we were able to get the CPL spectra and their decays simultaneously. Based on the research results of this time, it has become possible to development of research from a new perspective about the CPL measurement.

  • Research Products

    (8 results)

All 2013 2012 2011

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (5 results)

  • [Journal Article] Remarkable Enhancement of Sensitivity with the Second Generation of Elliptically Polarization-detected Circular Dichroism Spectroscopy2013

    • Author(s)
      Murakami, M.; Araki, Y.; Sakamoto, S.; Hamada, Y.; Wada, T.
    • Journal Title

      Chem. Lett

      Volume: 42 Pages: 261-262

    • URL

      http://dx.doi.org/10.1246/cl.2013.261

    • Peer Reviewed
  • [Journal Article] Fullerene- and Pyromellitdiimide-Appended Tripodal Ligands Embedded in Light-Harvesting Porphyrin Macrorings2011

    • Author(s)
      Kuramochi, Y.; Satake, A.; Sandanayaka, A. S. D.; Araki,Y.; Ito,O.; Kobuke, Y.
    • Journal Title

      Inorg. Chem.

      Volume: 50 Pages: 10249-10258

    • DOI

      DOI:10.1021/ic201250q

    • Peer Reviewed
  • [Journal Article] Multiple photosynthetic reaction centres composed of supramolecular assemblies of zinc porphyrin dendrimers with a fullerene acceptor2011

    • Author(s)
      Fukuzumi, S.; Saito, K.; Ohkubo, K.; Khoury, T.; Kashiwagi, Y.; Absalom, M. A.; Gadde, S.; D'Souza, F.; Araki, Y. ;Ito, O. ; Crossley, M. J.
    • Journal Title

      Chem. Commun.

      Volume: 47 Pages: 7980-7982

    • DOI

      DOI:10.1039/C1CC11725D

    • Peer Reviewed
  • [Presentation] 内部標準を用いたキラルなペリレンジイミドの蛍光円二色性測定とその時間分解測定への応用2013

    • Author(s)
      荒木保幸,村上慎,坂本清志,和田健彦
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      滋賀県草津市
    • Year and Date
      20130322-20130325
  • [Presentation] Photophysical and Phtochemical Behavior of Chiral Perylenediimide Dimer Studied by Time-resolved Circular Polarized Spectroscopy2012

    • Author(s)
      Y.Araki, M.Murakami, R.Uematsu, Y.Hamada, S.Sakamoto, T.Wada
    • Organizer
      7th Asian Photochemistry Conference 2012
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      20121112-20121115
  • [Presentation] キラルなペリレンジイミド二量体の光励起挙動2012

    • Author(s)
      荒木保幸,村上慎,濱田芳生,上松亮平,坂本清志,和田健彦
    • Organizer
      2012年光化学討論会
    • Place of Presentation
      東京
    • Year and Date
      20120912-20120914
  • [Presentation] Ellipticity-change-detected CD apparatus toward theapplication to the DNA/RNA conformational change2011

    • Author(s)
      Araki, Y.; Murakami, M.;Hamada, Y.; Sakamoto, S.;,Wada, T.
    • Organizer
      The 38th International Symposium on NucleicAcid Chemistry
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      20111109-11
  • [Presentation] 円二色性の高感度検出へ向けた楕円率変化検出型円二色性測定法2011

    • Author(s)
      荒木保幸・村上慎・濱田芳生・坂本清志・和田健彦
    • Organizer
      2011年光化学討論会
    • Place of Presentation
      宮崎
    • Year and Date
      20110906-08

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Published: 2014-09-25  

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