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2012 Fiscal Year Final Research Report

Molecular spintronics based on hybrid compounds between organic conductors and transition metal complexes.

Research Project

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Project/Area Number 23655114
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Functional materials chemistry
Research InstitutionIbaraki University

Principal Investigator

NISHIKAWA Hiroyuki  茨城大学, 理学部, 教授 (40264585)

Project Period (FY) 2011 – 2012
Keywords分子性導体 / 電気物性 / 磁性 / 常磁性金属錯体 / スピントロニクス / 自己組織化
Research Abstract

Paramagnetic metal complexes with TTF moieties in their ligands were newly synthesized; TTF denotes tetrathiafulvalene and its derivatives are well known as the component molecules for molecular conductors. Crystal structures and physical properties including electrical conductivity of the TTF-based metal complexes were investigated. We succeeded in the development of thin layer film of Cu(II) complex by the vacuum evaporation process and the fabrication of its FET device. Because the FET properties were not observed in the device of the Cu(II) complex, we modified the TTF based metal complex in order to apply the wet process for device construction. We prepared a new metal complex having self-assembling ability; the cubic metal complex with long alkyl chains attached to the TTF ligands exhibited gelation for some organic solevents.

  • Research Products

    (23 results)

All 2013 2012 2011 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (12 results) Remarks (2 results)

  • [Journal Article] Dimerized spin-crossover iron(II) complexes as supramolecular anion capsules2013

    • Author(s)
      T. Shiga, E. Oshiro, N. Nakayama, K. Mitsumoto, G. N. Newton, H. Nishikawa, and H. Oshio
    • Journal Title

      Eur. J. Inorg. Chem

      Volume: 56 Pages: 781-787

    • DOI

      DOI:10.1002/ejic.201201365.

    • Peer Reviewed
  • [Journal Article] Encapsulation controlled single molecular magnetism in tetra- thiafulvalene-capped cyanide-brided cubes2012

    • Author(s)
      K. Mitsumoto, H. Nishikawa, G. N. Newton, and H. Oshio
    • Journal Title

      Dalton Trans

      Volume: 41 Pages: 13601-13608

    • DOI

      DOI:10.1039/C2DT30908D

    • Peer Reviewed
  • [Journal Article] Syntheses and properties of new metal complexes based on TTF-ligands with multidentate coordination sites2012

    • Author(s)
      H. Nishikawa, R. Kitabatake, K. Mitsumoto, and H. Oshio
    • Journal Title

      Phys. Status Solidi

      Volume: C9 Pages: 1140-1142

    • DOI

      DOI:10.1002/pssc.201100626

    • Peer Reviewed
  • [Journal Article] One-pot synthesis of Cu(II) complex with partially oxidized TTF moieties2012

    • Author(s)
      H. Nishikawa, R. Kitabatake, K. Mitsumoto, T. Shiga and H. Oshio
    • Journal Title

      Crystals

      Volume: 2 Pages: 935-945

    • DOI

      DOI:10.3390/cryst2030935

    • Peer Reviewed
  • [Journal Article] Face-to-face dimeric tetrathiafulvalenes and their cation radical and dication species as models of mixed valence and π-dimer states2012

    • Author(s)
      M. Hasegawa, K. Daigoku, K. Hashimoto, H. Nishikawa, and M. Iyoda
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 85 Pages: 51-60

    • DOI

      DOI:10.1246/bcsj.20110224

    • Peer Reviewed
  • [Journal Article] Cyanide bridged tetranuclear complex with a novel terthiophene based ligand2011

    • Author(s)
      K. Mitsumoto, H. Nishikawa, and H. Oshio
    • Journal Title

      Polyhedron

      Volume: 30 Pages: 3245-3248

    • DOI

      DOI:10.1016/j.poly.2011.04.035

    • Peer Reviewed
  • [Journal Article] Cyanide-bridged [Fe8M6] clusters displaying single-molecule magnetism (M=Ni) and electron-transfer-coupled spin transitions (M=Co)2011

    • Author(s)
      K. Mitsumoto, E. Oshiro. H. Nishikawa, T. Shiga, Y. Yamamura, K. Saito, and H. Oshio
    • Journal Title

      Chem. Eur. J.

      Volume: 17 Pages: 9612-9618

    • DOI

      DOI:10.1002/chem.201101404

    • Peer Reviewed
  • [Journal Article] Spin-crossover behavior and electrical conduction property in iron(II) complexes with tetrathiafulvalvene moieties2011

    • Author(s)
      M. Nihei, N. Takahashi, H. Nishikawa, and H. Oshio
    • Journal Title

      Dalton Trans

      Volume: 40 Pages: 2154-2156

    • DOI

      DOI:10.1039/C0DT01092H

    • Peer Reviewed
  • [Journal Article] Optical and structural studies of a two-dimensional organic Mott insulator dimethylphenazine-tetrafluorotetracyanoquinodimethane2011

    • Author(s)
      M. Ohkura
    • Journal Title

      Phys. Rev. B

      Volume: 84 Pages: 085136

    • DOI

      DOI:10.1103/PhysRevB.84.085136

    • Peer Reviewed
  • [Presentation] 新規DH-TTPの合成と電気化学的性質2013

    • Author(s)
      渡邉健、太田貴之、西川浩之
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学
    • Year and Date
      2013-03-23
  • [Presentation] Structural study on charge ordering insulating state of β″-(DODHT)_2AsF_62012

    • Author(s)
      H. Nishikawa
    • Organizer
      MDF2012
    • Place of Presentation
      Miyazaki, Japan
    • Year and Date
      2012-12-02
  • [Presentation] β″-(DODHT)_2AsF_6の電荷秩序絶縁体転移2012

    • Author(s)
      新崎洋一、西川浩之、近藤隆祐、中尾朗子、熊井玲児、野上由夫
    • Organizer
      第23回日本化学会関東支部茨城地区研究交流会
    • Place of Presentation
      いばらき量子ビーム研究センター
    • Year and Date
      2012-11-30
  • [Presentation] 新規ハロゲン置換DH-TTPの合成2012

    • Author(s)
      太田貴之、西川浩之
    • Organizer
      第22回日本化学会関東支部茨城地区研究交流会
    • Place of Presentation
      いばらき量子ビームセンター
    • Year and Date
      2012-11-04
  • [Presentation] 縮小π系ドナーDODHTの新規ラジカル塩の合成と物性2012

    • Author(s)
      新崎洋一、西川浩之、三ツ元清隆、大塩寛紀
    • Organizer
      第22回日本化学会関東支部茨城地区研究交流会
    • Place of Presentation
      いばらき量子ビームセンター
    • Year and Date
      2012-11-04
  • [Presentation] β″-(DODHT)_2AsF_6の電荷秩序絶縁体転移2012

    • Author(s)
      新崎洋一、西川浩之、近藤隆祐、中尾朗子、熊井玲児、野上由夫
    • Organizer
      第6回分子科学討論会
    • Place of Presentation
      東京大学
    • Year and Date
      2012-09-19
  • [Presentation] 縮小π系ドナーDODHTのBr塩の構造と物性2012

    • Author(s)
      新崎洋一、西川浩之、三ツ元清隆、大塩寛紀
    • Organizer
      日本化学会第92春季年会
    • Place of Presentation
      慶応大学
    • Year and Date
      2012-03-26
  • [Presentation] Structural study on charge ordered state of β″-DODHT salts2011

    • Author(s)
      西川浩之、新崎洋一、近藤隆祐、中尾朗子、熊井玲児、野上由夫
    • Organizer
      物構研シンポジウム'11「量子ビーム科学の展望」
    • Place of Presentation
      つくば国際会議場
    • Year and Date
      2011-12-06
  • [Presentation] Molecular conductor with chiral structure based on reduced π-electron donor2011

    • Author(s)
      H. Nishikawa
    • Organizer
      MDF Internationl mini-Workshop, Development of Molecular Degree of Freedom towards Novel Functionality
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      2011-11-25
  • [Presentation] Magnetic properties of TTF-based paramagnetic metal complexes2011

    • Author(s)
      H. Nishikawa, R. Kitabatake, K. Mitsumoto, H. Oshio
    • Organizer
      MDF Internationl Workshop Open-shell Organic Molecules ? Synthesis and Electronic Structure Freedom
    • Place of Presentation
      Osaka, Japan
    • Year and Date
      2011-10-07
  • [Presentation] Syntheses and properties of new metal complexes based on TTF-ligands with multidentate coordination sites2011

    • Author(s)
      H. Nishikawa, R. Kitabatake, K. Mitsumoto, H. Oshio
    • Organizer
      ISCOM2011
    • Place of Presentation
      Gniezno, Poland
    • Year and Date
      2011-09-26
  • [Presentation] 縮小π系ドナーDODHTの新規ラジカル塩の合成と物性2011

    • Author(s)
      新崎洋一、西川浩之、三ツ元清隆、大塩寛紀
    • Organizer
      第5回分子科学討論会
    • Place of Presentation
      札幌コンベンションセンター
    • Year and Date
      2011-09-22
  • [Remarks]

    • URL

      http://info.ibaraki.ac.jp/Profiles/20/0001920/profile.html

  • [Remarks]

    • URL

      http://nihsikawalab.sci.ibaraki.ac.jp/index2.html

URL: 

Published: 2014-09-25   Modified: 2015-11-04  

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