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2012 Fiscal Year Final Research Report

Mechanisms of hydrogen production in hydrothermal reactions of sulfur and its application to a sustainable hydrogen production using geothermal energy

Research Project

  • PDF
Project/Area Number 23656556
Research Category

Grant-in-Aid for Challenging Exploratory Research

Allocation TypeMulti-year Fund
Research Field Earth system and resources enginnering
Research InstitutionTohoku University

Principal Investigator

WATANABE Noriaki  東北大学, 大学院・環境科学研究科, 助教 (60466539)

Project Period (FY) 2011 – 2012
Keywords再生可能資源・エネルギー / 硫黄 / 水熱反応 / 水素 / 地熱
Research Abstract

A new method of hydrogen (H_2) production was proposed. This method consists of H_2 production from water, with sulfide as a reducing agent of water, and sulfide regeneration, with biomass (e.g., glucose) as a reducing agent of S_n^<2-> and S_xO_y^<2->. Laboratory experiments revealed H2 production at pH 9-13 and 280-320 ℃, and sulfide regeneration at -60℃.

  • Research Products

    (7 results)

All 2013 2012 2011

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (4 results)

  • [Journal Article] Temperature- and pH-dependent mechanism of hydrogen production from hydrothermal reactions of sulfide2012

    • Author(s)
      P. Setiani, N. Watanabe, A. Kishita, N. Tsuchiya
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 37(24) Pages: 18679-18687

    • DOI

      DOI:10.1016/j.ijhydene.2012.10.013

    • Peer Reviewed
  • [Journal Article] Enhanced hydrogen production from biomass via the sulfur redox cycle under hydrothermal conditions2011

    • Author(s)
      P. Setiani, J. Vilcaez, N. Watanabe, A. Kishita, N. Tsuchiya
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 36(17) Pages: 10674-10682

    • DOI

      DOI:10.1016/j.ijhydene.2011.06.012

    • Peer Reviewed
  • [Journal Article] Sustainable and enhanced hydrogen production from biomass through sulfur redox cycle using georeactor2011

    • Author(s)
      P. Setiani, J. Vilcaez, N. Watanabe, A. Kishita, N. Tsuchiya
    • Journal Title

      Geothermal Resources Council Transactions

      Volume: 35 Pages: 135-138

    • URL

      https://www.geothermal-library.org/ index.php?mode=pubs&action=view&rec ord=1029227

    • Peer Reviewed
  • [Presentation] Mathematical model of hydrogen production from water-sulfide reactions under hydrothermal conditions2013

    • Author(s)
      P. Setiani, N. Watanabe, N. Tsuchiya
    • Organizer
      10th International Workshop on WATER DYNAMICS & ICDP Japan Beyond-Brittle Project
    • Place of Presentation
      仙台
    • Year and Date
      2013-03-12
  • [Presentation] Predictive model of hydrogen production from hydrothermal reactions of sulfide2012

    • Author(s)
      P. Setiani, N. Watanabe, N. Tsuchiya
    • Organizer
      G-COE symposium2012
    • Place of Presentation
      仙台
    • Year and Date
      2012-09-26
  • [Presentation] 硫黄の水熱反応における水素生成に及ぼす温度とpHの影響2011

    • Author(s)
      セティアニプトリ、渡邉則昭、木下睦、土屋範芳
    • Organizer
      日本地熱学会平成23年学術講演会
    • Place of Presentation
      指宿
    • Year and Date
      2011-11-09
  • [Presentation] Sustainable and enhanced hydrogen production from biomass through sulfur redox cycle using georeactor2011

    • Author(s)
      P. Setiani, J. Vilcaez, N. Watanabe, A. Kishita, N. Tsuchiya
    • Organizer
      Geothermal Resources Council 35th Annual Meeting
    • Place of Presentation
      サンディエゴ, 米国
    • Year and Date
      2011-10-25

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Published: 2014-09-25  

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