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2013 Fiscal Year Final Research Report

Synthesis of carbon nano-junglegym and its use for high-performance electric double-layer capacitors

Research Project

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Project/Area Number 23685041
Research Category

Grant-in-Aid for Young Scientists (A)

Allocation TypeSingle-year Grants
Research Field Functional materials/Devices
Research InstitutionTohoku University

Principal Investigator

NISHIHARA Hirotomo  東北大学, 多元物質科学研究所, 准教授 (80400430)

Co-Investigator(Renkei-kenkyūsha) KYOTANI Takashi  東北大学, 多元物質科学研究所, 教授 (90153238)
Project Period (FY) 2011-04-01 – 2014-03-31
KeywordsSupercapacitors / Pseudocapacitors / Graphene / Acrivated carbons / Quinone
Research Abstract

Towards the development of high-performance electric double-layer capacitors (EDLCs), new electrode materials were synthesized by using zeolite as a template. By introducing very large amount of carbon into the zelite nanochannels, very unique nanocarbon having a fullerene-like framework was successfully synthesized. By using zeolite membrane as a template, a continuous film consisting of nanoporous carbon was formed directly on a current collector film. The porous carbon membrane thus prepared is free from polymer binders, and exhibited very fast charge/discharge property. Moreover, the edge site of the nanocarbon was functionalized by quinone-type functional groups. The quinone-doped carbons showed ultra-high capacitance up to 500 F/g, and sufficient rate capability and cyclability.

  • Research Products

    (35 results)

All 2014 2013 2012 2011

All Journal Article (9 results) (of which Peer Reviewed: 8 results) Presentation (22 results) (of which Invited: 13 results) Book (2 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 2 results)

  • [Journal Article] Large Pseudocapacitance in Quinone-Functionalized Zeolite-Templated Carbon2014

    • Author(s)
      H. Itoi, H. Nishihara, T. Ishii, K. Nueangnoraj, R. Berenguer, T. Kyotani
    • Journal Title

      Bull. Chem. Soc. Jpn

      Volume: 87 (※BCSJ賞受賞※論文の図が雑誌の表紙に採用される) Pages: 250-257

    • Peer Reviewed
  • [Journal Article] Carbon-Carbon Asymmetric Aqueous Capacitor by Pseudocapacitive Positive and Stable Negative Electrodes2014

    • Author(s)
      K. Nueangnoraj, R. Ruiz-Rosas, H. Nishihara, S. Shiraishi, E. Morallón, D. Cazorla-Amorós, T. Kyotani
    • Journal Title

      Carbon

      Volume: 67 Pages: 792-794

    • Peer Reviewed
  • [Journal Article] Formation of crosslinked-fullerene-like framework as negative replica of zeolite Y2013

    • Author(s)
      K. Nueangnoraj, H. Nishihara, K. Imai, H. Itoi, T. Ishii, M. Kiguchi, Y. Sato, M. Terauchi, T. Kyotani
    • Journal Title

      Carbon

      Volume: 62 Pages: 455-464

    • Peer Reviewed
  • [Journal Article] Binderless thin films of zeolite-templated carbon electrodes useful for electrochemical microcapacitors with ultrahigh rate performance2013

    • Author(s)
      Á. Berenguer-Murcia, R. Ruiz-Rosas, J. García-Aguilar, K. Nueangnoraj, H. Nishihara, E. Morallón, T. Kyotani, D. Cazorla Amorós
    • Journal Title

      Phys. Chem. Chem. Phys

      Volume: 15 Pages: 10331-10334

    • Peer Reviewed
  • [Journal Article] Amorphous water in three-dimensional confinement of zeolite-templated carbon2013

    • Author(s)
      H. Kyakuno, K. Matsuda, Y. Nakai, T. Fukuoka, Y. Maniwa, H. Nishihara, T. Kyotani
    • Journal Title

      Chem. Phys. Lett

      Volume: 571 Pages: 54-60

    • Peer Reviewed
  • [Journal Article] Electrochemical generation of oxygen-containing groups in an ordered microporous zeolite-templated carbon2013

    • Author(s)
      R. Berenguer, H. Nishihara, H. Itoi, T. Ishii, E. Morallón, D. Cazorla-Amorós, T. Kyotani
    • Journal Title

      Carbon

      Volume: 54 (※論文の図が雑誌の表紙に採用される) Pages: 94-104

    • Peer Reviewed
  • [Journal Article] Tailoring the Surface Chemistry of Zeolite Templated Carbon by Electrochemical Methods2013

    • Author(s)
      R. Berenguer, E. Morallon, D. Cazorla-Amoros, H. Nishihara, H. Itoi, T. Ishii, T. Kyotani
    • Journal Title

      Boletin del Grupo Espanol del Carbon

      Volume: 28 Pages: 10-14

    • Peer Reviewed
  • [Journal Article] ゼオライト鋳型を利用したユニークな構造の炭素の合成とその特異な性質2013

    • Author(s)
      京谷隆, 西原洋知
    • Journal Title

      触媒

      Volume: 55 Pages: 376-381

  • [Journal Article] Templated Nanocarbons for Energy Storage2012

    • Author(s)
      H. Nishihara, T. Kyotani
    • Journal Title

      Adv. Mater

      Volume: 24 (※論文の図がinside coverに採用される) Pages: 4473-4498

    • Peer Reviewed
  • [Presentation] 鋳型ナノカーボンの合成とエネルギー貯蔵への応用2014

    • Author(s)
      西原洋知
    • Organizer
      研究会:グラフェンを「作る・測る・使う」技術開発の将来
    • Place of Presentation
      岡山, (発表日3/14)
    • Year and Date
      20140314-15
    • Invited
  • [Presentation] Carbon-carbon asymmetric capacitor by using pseudocapacitive zeolite-templated carbon as one of the electrodes2013

    • Author(s)
      ヌーアンノラドカニン、Ruiz-Rosas Ramiro、西原洋知、白石壮志、Morallón Emilia、Cazorla-Amorós Diego、京谷隆
    • Organizer
      第40回炭素材料学会年会
    • Place of Presentation
      京都, (発表日12/5オーラル)
    • Year and Date
      20131203-05
  • [Presentation] Pseudocapacitance of zeolite-templated carbon2013

    • Author(s)
      H. Nishihara, T. Kyotani
    • Organizer
      The 7th Asian Conference on Electrochemical Power Sources (ACEPS‐7)
    • Place of Presentation
      (Osaka), Japan, (発表日11/25)
    • Year and Date
      20131124-27
    • Invited
  • [Presentation] Template carbonization for advanced nanomaterials2013

    • Author(s)
      H. Nishihara
    • Organizer
      4th Asian Conference on Coordination Chemistry (ACCC4)
    • Place of Presentation
      (Jeju), Korea, (発表日11/5)
    • Year and Date
      20131104-07
    • Invited
  • [Presentation] Electrochemical behavior of activated carbons with phosphorous surface groups2013

    • Author(s)
      A. Gallardo-Fuentes, R. Ruiz-Rosas, R. Berenguer, E. Morallón, D. Cazorla-Amorós, H. Nishihara, T. Kyotani, Jose Rodríguez-Mirasol, Tomas Cordero
    • Organizer
      XII Meeting of the Spanish Carbon Group (GEC13)
    • Place of Presentation
      Madrid, Spain, (発表日10/22)
    • Year and Date
      20131020-23
    • Invited
  • [Presentation] Energy storage in nanocarbons and nanocomposites2013

    • Author(s)
      H. Nishihara
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      (Sendai), Japan, (発表日9/28)
    • Year and Date
      20130928-30
    • Invited
  • [Presentation] High Performance Asymmetric Capacitor Based on Zeolite−Templated Carbon and KOH−Activated Carbon2013

    • Author(s)
      Khanin Nueangnoraj, Ramiro Ruiz−Rosas, Hirotomo Nishihara, Emilia Morallón, Takashi Kyotani, Diego Cazorla−Amorós
    • Organizer
      Carbon2013
    • Place of Presentation
      Windsor Atlântica Hotel, Rio de Janeiro, Brazil, (発表日7/16オーラル)
    • Year and Date
      20130714-19
  • [Presentation] Large Pseudocapacitance Induced by Redox Reactions on Microporous Carbon in Organic Electrolyte2013

    • Author(s)
      H. Nishihara, K. Nueangnoraj, R. Berenguer, H. Itoi, M. Ito, T. Kyotani
    • Organizer
      Carbon2013
    • Place of Presentation
      Windsor Atlântica Hotel, Rio de Janeiro, Brazil, (発表日7/15オーラル)
    • Year and Date
      20130714-19
  • [Presentation] Unique Electrochemical Capacitance of Zeolite-Templated Carbons2013

    • Author(s)
      H. Nishihara, T. Kyotani
    • Organizer
      2013 International Conference on Advanced Capacitors
    • Place of Presentation
      (Osaka), Japan, (発表日5/27)
    • Year and Date
      20130527-30
    • Invited
  • [Presentation] Synthesis of Ordered Porous Carbon and Its Application to Energy Fields2013

    • Author(s)
      H. Nishihara, T. Kyotani
    • Organizer
      8th International Mesostructured Materials Symposium (IMMS 2013)
    • Place of Presentation
      (Awajishima), Japan, (発表日5/21)
    • Year and Date
      20130520-24
    • Invited
  • [Presentation] Insight into the Framework Structure of Zeolite-Templated Carbon : Experimental and Theoretical Study2013

    • Author(s)
      H. Nishihara, H. Fujimoto, H. Itoi, K. Nueangnoraj, H. Tanaka, A. Maki, M. Miyahara, T. Kyotani
    • Organizer
      17th International Symposium on Intercalation Compounds (ISIC17)
    • Place of Presentation
      (Sendai), Japan, (発表日5/14ポスター)
    • Year and Date
      20130512-16
  • [Presentation] Enhancement of electrochemical capacitance of zeolite-templated carbon by expanding a potential window2012

    • Author(s)
      K. Nueangnoraj、H. Nishihara、R. Berenguer、H. Itoi、M. Ito、T. Kyotani
    • Organizer
      第39回炭素材料学会年会
    • Place of Presentation
      長野, (発表日11/29オーラル)
    • Year and Date
      20121128-30
  • [Presentation] Carbon Electrochemical Capacitors based on Pseudocapacitance -from Supercapacitor to Battery Behaviour-2012

    • Author(s)
      R. Berenguer, H. Nishihara, H. Itoi, I. Takafumi, D. Cazorla-Amorós, E. Morallón and T. Kyotani
    • Organizer
      Carbon 2012, AGH University of Science and Technology
    • Place of Presentation
      Krakow, Poland, (発表日6/19(ポスター)
    • Year and Date
      20120617-22
  • [Presentation] Nanocarbons for energy storage applications2012

    • Author(s)
      H. Nishihara, H. Itoi, S. Iwamura, T. Kyotani
    • Organizer
      ISPlasma 2012
    • Place of Presentation
      (Nagoya), Japan, (発表日3/6)
    • Year and Date
      20120304-08
    • Invited
  • [Presentation] 配列ナノ空間をもつカーボン系多孔性材料の調製と応用2012

    • Author(s)
      西原洋知
    • Organizer
      2012年度触媒学会北海道支部札幌講演会
    • Place of Presentation
      札幌
    • Year and Date
      2012-12-07
    • Invited
  • [Presentation] Unique Structure of Zeolite Templated Carbon and Its Performance as an Energy Storage Medium2012

    • Author(s)
      H. Nishihara, T. Kyotani
    • Organizer
      The International Conference on Emerging Advanced Nanomaterials–2012
    • Place of Presentation
      Brisbane, Australia
    • Year and Date
      2012-10-25
    • Invited
  • [Presentation] 高表面積ナノグラフェン構造体「ゼオライト鋳型炭素」のキャパシタ特性2012

    • Author(s)
      西原洋知
    • Organizer
      キャパシタ技術委員会平成24年度第1回研究会
    • Place of Presentation
      大阪
    • Year and Date
      2012-01-27
    • Invited
  • [Presentation] 超多孔性炭素の製造、構造、応用2012

    • Author(s)
      西原洋知
    • Organizer
      活性炭技術委員会第145回講演会
    • Place of Presentation
      大阪
    • Year and Date
      2012-01-25
    • Invited
  • [Presentation] 規則性ナノグラフェン構造体による超高容量電気化学キャパシタ2011

    • Author(s)
      糸井弘行, 西原洋知, 石井孝文, Raúl Berenguer-Betrián, 京谷隆
    • Organizer
      日本化学会東北支部平成23年度化学系学協会東北大会
    • Place of Presentation
      仙台,東北大学, (発表日9/17ポスター※ポスター賞受賞)
    • Year and Date
      20110917-18
  • [Presentation] A Possible Structure of a Negatively Curved Graphene Network Formed Inside the Zeolite Nanochannels2011

    • Author(s)
      K. Nueangnoraj, H. Nishihara, Y. Sato, M. Terauchi, T. Kyotani
    • Organizer
      Carbon2011, East China University of Science and Technology
    • Place of Presentation
      Shanghai, China, (発表日7/25 (ポスター)※ポスター賞受賞)
    • Year and Date
      20110724-29
  • [Presentation] Electrochemical capacitor performances of zeolite-templated carbons containing heteroatoms2011

    • Author(s)
      H. Nishihara, H. Itoi, R. Berenguer, T. Ishii, and T. Kyotani
    • Organizer
      2^<nd> International Symposium on Enhanced Electrochemical Capacitors (ISEE'Cap 2011), Poznan University of Technology
    • Place of Presentation
      Poznan, Poland, (発表日6/13 (オーラル))
    • Year and Date
      20110612-16
  • [Presentation] Energy Storage in Nano-Structured Carbons2011

    • Author(s)
      Hirotomo Nishihara, Takashi Kyotani
    • Organizer
      The 6th ICF and 2011 Fall Meeting of the Korean Carbon Society
    • Place of Presentation
      Jeonju, Korea, (発表日11/2)
    • Year and Date
      2011-11-02
    • Invited
  • [Book] 鋳型法によるナノカーボンの合成法,カーボン材料実験技術2013

    • Author(s)
      京谷隆,折笠広典,西原洋知,干川康人
    • Total Pages
      126-134
    • Publisher
      炭素材料学会 (※著書の図が、書籍(ソフトカバー)の表紙絵に採用される)
  • [Book] "Zeolite-Templated Carbon–Its Unique Characteristics and Applications", Novel Carbon Adsorbents, in Chapter 102012

    • Author(s)
      Hirotomo Nishihara, Takashi Kyotani
    • Total Pages
      295-322
    • Publisher
      Elsevier (※著書の図が、書籍(ハードカバー)の表紙絵に採用される)
  • [Patent(Industrial Property Rights)] 電気化学キャパシタ用電極およびその製造方法2012

    • Inventor(s)
      伊藤仁、京 谷隆、西 原洋知、ヌーア ンノラド カニン、糸井弘行、ベレンガー-ベトリアンラウル
    • Industrial Property Rights Holder
      日産自動車株式会社、東北大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特許出願2012-258055
    • Filing Date
      2012-11-26
    • Overseas
  • [Patent(Industrial Property Rights)] ミクロポーラス炭素系材料の製造方法2012

    • Inventor(s)
      西原洋知、京 谷隆、伊藤仁
    • Industrial Property Rights Holder
      日産自動車株式会社、東北大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      特許出願2012-23203、 特許公開2013-159526
    • Filing Date
      2012-02-06
    • Overseas

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Published: 2015-07-16  

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