2012 Fiscal Year Final Research Report
Programmable synthesis of porphyrin/phthalocyanine one-dimensional stacked arrays via rotaxane formation
| Project/Area Number |
23750061
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
YAMADA Yasuyuki 名古屋大学, 物質科学国際研究センター, 助教 (10385552)
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| Project Period (FY) |
2011 – 2012
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| Keywords | ポルフィリン / フタロシアニン / ロタキサン / プログラム構築 |
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| Research Abstract |
We have developed the method to arrange porphyrins and/or phthalocyanines inside one-dimensional stacked nanoarrays in a programmable manner by means of multipoint rotaxane formation. We exhibited that the dinuclear Cu^complex of the porhyrin-phthalocyanine stacked dimer shows unique switchable spin-spin communication between two Cu^centers induced by protonation and deprotonation.
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