2013 Fiscal Year Final Research Report
Synthesis of novel pincer-type complexes: Their applications to catalytic reactions using ammonia
| Project/Area Number |
23750064
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic chemistry
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| Research Institution | Osaka Prefecture University (2013)
Osaka City University (2011-2012) |
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Principal Investigator |
KAMEO Hajime 大阪府立大学, 理学(系)研究科(研究院), 助教 (50597218)
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| Project Period (FY) |
2011 – 2013
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| Keywords | 金属錯体 / 多座配位子 / 高電子供与性 / ゲルマニウム / スズ |
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| Research Abstract |
Rhodium and iridium complexes bearing a EP3- or PEP-type ligand (E = Si, Ge, Sn) were prepared. It should be noted that this synthetic method is the first exapmle to prepare GeP3, SnP3, PGeP, PSnP-type complexes. Systematic investigations using novel complexes enable to evaluate trans influence and electron donating ability of E; electron donating ability of E increases in the order Ge < Si < Sn and trans influence of E increases in the order Ge < Si = Sn. Further, we found that some of novel complexes catalized acceptorless dehydrogenation of ethanol.
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