2014 Fiscal Year Final Research Report
Control of synergistically working multi-functions designed in conductive molecular magnets
| Project/Area Number |
24245012
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tohoku University |
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Principal Investigator |
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| Co-Investigator(Renkei-kenkyūsha) |
KOSAKA Wataru 東北大学, 金属材料研究所, 助教 (70620201)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 電子ドナー・アクセプター / 金属―有機物骨格体 / 導電性分子磁石 / 電荷移動 / 協奏的多重機能 |
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| Outline of Final Research Achievements |
The aim of the research project is to establish multi-functional molecular materials using electron-donor/-acceptor-based conductive molecular magnets or highly redox-active molecular framework compounds, in which not only ‘physical responses’ such as magnetic ordering, electron transporting, and dielectric responses resulted from their frameworks, but also ‘chemical reactions’ involving chemical adsorption/desorption of gaseous molecules in nano-sized pores are synergistically functioned. We discovered tunable selective NO adsorption behavior in a series of electron-donor-type chain compounds based on paddlewheel-type diruthenium(II, II) complexes, and succeeded to capture modifications involving gas adsorptions as gate-opening gas adsorption transitions and chemical interactions caused by host-guest interactions as electric signals by applying ac electric fields in situ gas handling.
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| Free Research Field |
化学
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