2014 Fiscal Year Final Research Report
Development of Efficient and Practical Synthetic Method of Organosilicon Compounds by Dehydrogenative Coupling
| Project/Area Number |
24550123
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
|
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| Research Institution | Meiji University |
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Principal Investigator |
|
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| Project Period (FY) |
2012-04-01 – 2015-03-31
|
| Keywords | 触媒設計・反応 / ルイス酸 / 脱水素シリル化 / インドール / アルキン / アルケン |
|---|
| Outline of Final Research Achievements |
During the research period of three years, I developed the following four types of deydrogenetive couplings for synthesizing useful organosilicon compounds: 1) zinc Lewis acid-catalyzed dehydrogenative N-silylation of N-unsubstituted indoles; 2) zinc Lewis acid-catalyzed dehydrogenative C3-silylation of N-substituted indoles; 3) zinc Lewis acid-catalyzed dehydrogenative silylation of terminal alkynes; 4) zinc Lewis acid-catalyzed dehydrogenative silylation of indenes.
|
| Free Research Field |
有機合成化学
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