Development of nanospace materials based on layered metal multifunctional phosphonate structures

2014 Fiscal Year Final Research Report

• Project/Area Number: 24550230
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Inorganic industrial materials
• Research Institution: Tokyo University of Agriculture and Technology
• Principal Investigator: KAZUYUKI Maeda 東京農工大学, 工学(系)研究科(研究院), 准教授 (60343159)
• Co-Investigator(Renkei-kenkyūsha): KONDO Atsushi 東京農工大学, 大学院工学研究院, 助教 (60533619)
• Project Period (FY): 2012-04-01 – 2015-03-31
• Keywords: 多孔体 / 無機有機ハイブリッド / 金属ホスホネート / ナノシート / MOF

Outline of Final Research Achievements

The aim of the research was to develop nanospace materials based on layer structures derived from layered metal multifunctional phosphonates by using strategies established in inorganic layered materials. Monolayer nanosheets obtained via intercalation of surfactants in a layered zinc phosphonate and the subsequent exfoliation were successfully immobilized on substrates. It was also confirmed that the local structure of the original layered compound was retained throughout the nanosheet formation. Microporous pillared layered materials with specific layer structures and pillars such as organic cations and pillaring ligands were prepared, the crystal structures and adsorption properties of which were revealed.

Free Research Field

無機材料化学