2014 Fiscal Year Final Research Report
Selective oxidation of assembled perovskite-type oxide catalyst
| Project/Area Number |
24560948
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Ehime University |
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Principal Investigator |
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| Co-Investigator(Kenkyū-buntansha) |
YAMAGUCHI Syuhei 愛媛大学, 大学院理工学研究科, 准教授 (50397494)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | ペロブスカイト型酸化物 / シアノ錯体 / シアノシリル化反応 |
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| Outline of Final Research Achievements |
Perovskite-type oxide was prepared by the thermal decomposition of cyano complex as a precursor. It was found that the formation of perovskite-type oxide was affected by the oxygen concentration during calcination process of precursor. In addition, the perovskite-type oxide was formed by the heat derived from oxidation of ligands. Catalytic activity for cyanosilylation increased with increasing calcination temperature of perovskite-type oxide catalyst. This result suggests that catalytic activity for cyanosilylation was influenced by increasing with crystallite size.
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| Free Research Field |
触媒化学
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