Dinitrogen Reduction by Metal Complexes in Specific Ionic Liquid Reaction Field

2013 Fiscal Year Final Research Report

• Project/Area Number: 24655048
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Single-year Grants
• Research Field: Inorganic chemistry
• Research Institution: Nagoya Institute of Technology
• Principal Investigator: MASUDA HIDEKI 名古屋工業大学, 工学(系)研究科(研究院), 教授 (50209441)
• Project Period (FY): 2012-04-01 – 2014-03-31
• Keywords: イオン液体 / 金属錯体 / 窒素固定化 / アンモニア

Research Abstract

Ammonia attracts attention as not only raw materials of manures and chemical products but also a next-generation energy source for the fossil fuel.We developed a new synthetic method of ammonia environmental-friendly as follows. We prepared the ammonia from dinitrogen gas and water-originated hydrogen in an ionic liquid electrochemically.

Research Products

• [Journal Article] Deprotonation/Protonation-Driven Change of The o-Donor Ability of a Sulfur Atom in Iron(II) Complexes with a Thioamide SNS Pincer Type Ligand (2014)
  • Author(s): T. Suzuki, Y. Kajita, and H. Masuda
  • Journal Title: Dalton Trans. Volume: (in press)
  • DOI: 10.1039/c4dt00524d
• [Journal Article] Adsorption and Detection of Escherichia coli using an Au substrate modified with a catecholate -type artificial siderophore-Fe^<3+> complex (2013)
  • Author(s): T. Inomata, H. Tanabashi, Y. Funahashi, T. Ozawa, and H. Masuda
  • Journal Title: Dalton Trans. Volume: 42(45) Pages: 16043- 16048
  • DOI: 10.1039/c3dt51448j
• [Journal Article] Enantioselective monofluoromethylation of aldehydes with 2-fluoro-1,3-benzodithiole- 1,1,3,3-tetraoxide catalyzed by a bifunctional cinchona alkaloid-derived thiourea-titanium complex (2013)
  • Author(s): H. Ma, K. Matsuzaki, Y. Yang, E. Tokunaga, D. Nakane, T. Ozawa, H. Masuda, and N. Shibata
  • Journal Title: Chem. Commun. Volume: 49(95) Pages: 11206-11208
  • DOI: 10.1039/C3CC46544F
• [Journal Article] SuperOxide Disproportionation Driven by Zinc Complexes with Various Steric and Electrostatic Properties (2013)
  • Author(s): A. Wada, K. Jitsukawa and H. Masuda
  • Journal Title: Angew. Chem. Int. Ed. Volume: 52(47) Pages: 12454-12459
  • DOI: 10.1002/anie.201305459
• [Journal Article] A Phosphonium-type Ionic Liquid-modified Au Electrode : A New Platform for Entrapping Functional Molecules on Substrate Surfaces (2013)
  • Author(s): T. Kitagawa, T. Inomata, Y. Funahashi, T. Ozawa, and H. Masuda
  • Journal Title: Chem Commun. Volume: 49 Pages: 10184-10186
  • DOI: 10.1039/C3CC45251D
• [Journal Article] Synthesis and Characterization of Tricarbonyl- Molybdenum Complexes Bearing Monoaza- Trithia-Macrocyclic Ligands (2013)
  • Author(s): T. Ogawa, K. Koike, J. Matsumoto, Y. Kajita, and H. Masuda
  • Journal Title: Inorg. Chim. Acta Volume: 401 Pages: 101-106
  • DOI: 10.1016/j.ica.2013.03.027
• [Journal Article] Highly selective binding of nitric oxide by Co^<III> and Fe^<III> complexes (2013)
  • Author(s): Z. Zhang, T. Suwabe, M Ishikawa, Y. Funahashi, T. Inomata, T. Ozawa and H. Masuda
  • Journal Title: Dalton Trans. Volume: 42(13) Pages: 4470-4478
• [Journal Article] Preparation, Characterization, and Reactivity of Dinitrogen Molybdenum Complexes with Bis(diphenylphosphino) amine Derivative Ligands that Form a Unique 4-Membered P-N-P Chelate Ring (2013)
  • Author(s): T. Ogawa, Y. Kajita, Y. Wasada-Tsutsui, H. Wasada, and H. Masuda
  • Journal Title: Inorg. Chem. Volume: 52(1) Pages: 182-195
  • DOI: 10.1021/ic301577a
• [Presentation] Syntheses and Reactivities of Dinuclear Copper Complexes as Structural/Functional Models of Tyrosinase (2013)
  • Author(s): H. Masuda
  • Organizer: The 2nd Japan-France Coordination Chemistry Symposium 2013
  • Place of Presentation: Nara, Japan
  • Year and Date: 20131124-28
  • Invited
• [Presentation] Electrochemical Hydrogenation of Dinitrogen to Ammonia Using Titanocene Dichloride in an Ionic Liquid (2013)
  • Author(s): H. Masuda
  • Organizer: 4th Asian Conference on Coordination Chemistry (ACCC4)
  • Place of Presentation: Jeju, Korea
  • Year and Date: 20131104-08
  • Invited
• [Presentation] 金属錯体の配位環境制御による機能発現 (2013)
  • Author(s): 増田秀樹
  • Organizer: 錯体化学会第63討論会
  • Place of Presentation: 琉球大学
  • Year and Date: 20131102-04
  • Invited
• [Presentation] 金属酵素活性中心を規範とした金属錯体による酸素の活性化戦略 (2012)
  • Author(s): 増田秀樹
  • Organizer: 第45回酸化反応討論会
  • Place of Presentation: 名古屋市立大学
  • Year and Date: 20121116-17
  • Invited
• [Presentation] Electro-chemical Reduction of Dioxygen by Diiron(II) Complex in an Ionic Liquid Modified on Gold Electrode (2012)
  • Author(s): H. Masuda
  • Organizer: 9^<th> Japan-China Joint Symposium on Metal Cluster Compounds
  • Place of Presentation: Fukuoka, Japan
  • Year and Date: 20120813-16
  • Invited
• [Presentation] Selective Preparation of (μ-η2 : η2-peroxo)dicopper(II) and Bis(μ-oxo) dicopper(III) Species as Hemocyanin and/or Tyrosinase Model (2012)
  • Author(s): H. Masuda
  • Organizer: 7^<th> Interational Conference on Porphyrins and Phthalocyanines (ICPP-7)
  • Place of Presentation: Jeju, Korea
  • Year and Date: 20120701-06
• [Presentation] 金属酵素を模倣した金属錯体による酸素の活性化 (2012)
  • Author(s): 増田秀樹
  • Organizer: 第22回金属の関与する生体関連反応シンポジウム
  • Place of Presentation: 金沢大学
  • Year and Date: 20120531-0601
  • Invited
• [Book] 「物質・エネルギー変換の未来を拓く高機能材料の開発」超ハイブリッド材料ポリマーフロンティア21講演録シリーズ34 (2012)
  • Author(s): 増田秀樹
  • Total Pages: 177-198
• [Book] 「健康・環境センサーの開発」ケミカルエンジニアリング、Vol. 57, No.1 (2012)
  • Author(s): 増田秀樹、小澤智宏、猪股智彦(共著)
  • Total Pages: 43-54
  • Publisher: 化学工業社
• [Remarks]
  • URL: http://www.ach.nitech.ac.jp/~inorg/masuda/Japanese/