2012 Fiscal Year Final Research Report
Re-definition of Solid State Chemistry of Metal Nitride Associated with Bond Lengths in Manganese Nitride
| Project/Area Number |
24655194
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Hiroshima University |
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Principal Investigator |
INUMARU Kei 広島大学, 大学院・工学研究院, 教授 (80270891)
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| Project Period (FY) |
2012
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| Keywords | 結晶成長 / 窒化物 / PLD / 固溶体 |
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| Research Abstract |
MnN, CoN thin films were prepared by PLD, and the correlation between deposition conditions and crystal structure of the crystalline films was investigated. Synthesis of (Gd,La)N and (Mn,Co)N was also attempted. Cubic MnN with an abnormally large lattice constant (a=4.445(3) A) was grown on MgO for the first time. It was revealed that another cubic phase with a=4.2 A was formed as a main phase. Currie temperature of (Gd,La)N was controllable by the composition, and formation of crystalline CoN was sensitive to the substrate temperature.
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