2014 Fiscal Year Final Research Report
Synthesis and Functionality of Aromatic Hemiporphyrazines
| Project/Area Number |
24685009
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| Research Category |
Grant-in-Aid for Young Scientists (A)
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| Allocation Type | Partial Multi-year Fund |
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| Research Field |
Organic chemistry
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| Research Institution | The Institute of Physical and Chemical Research |
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Principal Investigator |
MURANAKA Atsuya 独立行政法人理化学研究所, 内山元素化学研究室, 専任研究員 (20374902)
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| Project Period (FY) |
2012-04-01 – 2015-03-31
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| Keywords | 芳香族性 / ヘミポルフィラジン |
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| Outline of Final Research Achievements |
18π-electron benziphthalocyanines, which can be regarded as an intermediate between hemiporphyrazine and phthalocyanine, have been synthesized for the first time. It was found that the aromaticity and near-infrared absorption of the benziphthalocyanines can be controlled by chemical modification and by variation of the solvent. Aromatic hemiporphyrazines and their metal complexes have been synthesized and their molecular structures, aromaticity, and optical properties have been clarified.
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| Free Research Field |
物理有機化学
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