2013 Fiscal Year Final Research Report
Preparation of hierarchically-designed materials based on polysaccharides and analysis of energy response properties
| Project/Area Number |
24780168
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Wood science
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| Research Institution | Nagoya University |
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Principal Investigator |
AOKI Dan 名古屋大学, 生命農学研究科, 助教 (80595702)
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| Co-Investigator(Renkei-kenkyūsha) |
AOKI Dan 名古屋大学, 大学院生命農学研究科, 助教 (80595702)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Keywords | セルロース / リビング重合 / ATRP / ポリマーブラシ / 高次構造 |
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| Research Abstract |
Novel polymer material based on a cellulose derivative was prepared. The purpose of the study is to control the primary structure by a chemical modification, the secondary structure by a molecular orientation, and the tertiary and higher structures by an accumulation of them. Cellulose derivatives having reaction sites in the side group were synthesized. Living radical polymerization was applied to a film of the cellulose derivative to introduce well-defined vinyl polymer side chains. Chemical structures, molecular weights, and their higher structures were investigated by NMR, GPC, and polarized FT-IR measurements.
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