2013 Fiscal Year Final Research Report
Development of addtion of C-H bond to simple alkenes and alkynes by iridium catalysts
| Project/Area Number |
24850017
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tokyo Metropolitan University (2013)
Aoyama Gakuin University (2012) |
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Principal Investigator |
MIURA Hiroki 首都大学東京, 都市環境科学研究科, 助教 (20633267)
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| Project Period (FY) |
2012-08-31 – 2014-03-31
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| Keywords | 有機金属化学 / イリジウム / C-H活性化 / 単純アルケン / 活性メチレン |
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| Research Abstract |
Addition of carbon-hydrogen bonds to carbon-carbon multiple bond is environmental-benign molecular transformations to afford substituted alkenes with 100% atom-economy. In the present study, cationic iridium catalysts were found to show high activity and selectivity toward the addition of 1,3-dicarbonyl compounds to simple terminal alkenes. Among Ir catalysts examined, [Ir(cod)2]SbF6 showed the highest activity to afford the corresponding products in high yields. Reaction of various terminal alkenes and 1,3-diketones produced the corresponding products in good to high yields.
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Research Products
(8 results)
