Constructions of multifunctional coordination compounds exhibiting light and electric field switching properties

2016 Fiscal Year Final Research Report

• Project/Area Number: 25248014
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: University of Tsukuba
• Principal Investigator: OSHIO Hiroki 筑波大学, 数理物質系, 教授 (60176865)
• Project Period (FY): 2013-04-01 – 2017-03-31
• Keywords: スピン平衡 / 電子移動共役スピン転移 / 双安定性 / シアン化物イオン架橋 / 混合原子価錯体 / 磁性 / 誘電性 / 電気伝導性

Outline of Final Research Achievements

In this work, coordination compounds with a lot of flexibility of spin, charge, and structure have been designed and their highly assembled coordination archtectures have been constructed by bottom-up methods. It is considered that hierarchical structures of coordination compounds will have amplified electronic properties, and can show controlable optical, magnetic, electronic properties. In this project, the following three systems were investigated. (1) spin-crossover multinuclear systems, (2) cyanide bridged mixed valence self-assembled systems, (3) hybrid-systems of cyanide-bridged multinuclear complexes and proton donors.

Free Research Field

錯体化学