2015 Fiscal Year Final Research Report
Synthesis, Properties and Reactivity of N-confused hexaphyrin Bis-Metal Complexes
| Project/Area Number |
25248039
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (A)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Bio-related chemistry
|
|---|
| Research Institution | Kyushu University |
|---|
Principal Investigator |
FURUTA HIROYUKI 九州大学, 工学(系)研究科(研究院), 教授 (40244157)
|
|---|
| Co-Investigator(Renkei-kenkyūsha) |
TOGANOH Motoki 九州大学, 大学院工学研究院, 助教 (80372754)
|
|---|
| Project Period (FY) |
2013-10-21 – 2016-03-31
|
| Keywords | ポルフィリン / 金属錯体 / 複核 / 近赤外色素 / ヘキサフィリン |
|---|
| Outline of Final Research Achievements |
“What’ll happen if the multiple metal ions are placed (or dropped) into the conjugated pi-electron pool (or sea)?”
We can expect the birth of new functional multiple metal complex whose properties are totally different from the porphyrin mono-metal because of strong electronic interactions between metal and ligand pi-electrons, could be expected if the two metal ions are wrapped in the conjugated pi-space. We have succeeded to synthesize a variety of bis-metal complexes of double N-confused hexaphyrins having rectangular shapes and investigated their basic properties in detail. As the results, we found the peculiar stable bismetal complexes having emission over 1500 nm.
|
| Free Research Field |
有機機能分子化学
|
