Organic Synthesis Using Various Valences of Iodine Reagents

2015 Fiscal Year Final Research Report

• Project/Area Number: 25288047
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Synthetic chemistry
• Research Institution: Osaka University
• Principal Investigator: Minakata Satoshi 大阪大学, 工学(系)研究科(研究院), 教授 (90273599)
• Project Period (FY): 2013-04-01 – 2016-03-31
• Keywords: ヨウ素 / 超原子価ヨウ素 / 触媒反応 / アミノ化

Outline of Final Research Achievements

This research project was carried out for the development of novel iodine reagents, especially iodine(I), (III), and (V) compounds, and their use in organic synthesis. The synthesis of iodine(I) reagents, which has an unique Lewis acidity, and its application to organic reactions were achieved. In addition, novel iodine(III) reagents containing nitrogen functional groups as a ligand were successfully synthesized, and they could be applied to amination reactions. The new type of amination reaction using iodine(V) reagents was also developed.

Free Research Field

有機合成化学