Magnetic probe to investigate weakly aggregated molecular complex

2016 Fiscal Year Final Research Report

• Project/Area Number: 25410013
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Multi-year Fund
• Section: 一般
• Research Field: Physical chemistry
• Research Institution: Kyoto University
• Principal Investigator: Kato Tatsuhisa 京都大学, 国際高等教育院, 教授 (80175702)
• Project Period (FY): 2013-04-01 – 2017-03-31
• Keywords: 内包フラーレン / 電子スピン共鳴分光 / 分子錯体 / 分子磁性

Outline of Final Research Achievements

Three major investigations were accomplished by this research project. The first, the magnetic properties of the radical cation of cycloparaphenylene (CPP) were obtained by an electron spin resonance (ESR) and an electron nuclear double resonance (ENDOR) measurements. Secondarily the parallel measurement of X-ray diffraction and ESR spectroscopy was done for the host-gust system of radical molecule PTIO in TPP metal- organic framework crystal. Finally the ground state of electron spin triplet was confirmed for O2@openC60 molecule by using multi-frequncy ESR measurements.

Free Research Field

物理化学