Synthesis of Organic Compounds with Three-dimensional Structures Based on the Transmetalation of Organopalladium Complexes

2015 Fiscal Year Final Research Report

• Project/Area Number: 25810059
• Research Category: Grant-in-Aid for Young Scientists (B)
• Allocation Type: Multi-year Fund
• Research Field: Synthetic chemistry
• Research Institution: Tokyo Institute of Technology
• Principal Investigator: Suzaki Yuji 東京工業大学, 資源化学研究所, 助教 (70436707)
• Project Period (FY): 2013-04-01 – 2016-03-31
• Keywords: トランスメタル化 / 環状分子 / 白金錯体 / パラジウム錯体 / トレーガー塩基

Outline of Final Research Achievements

Cationic organopalladium(II) complexes are known to has high reactivity for transmetalation reactions. Based on the high reactivity of the palladium complexes, we investigated the new synthetic approach for organic and organometallic compounds especially with macrocyclic structures. We succeeded to synthesize the cyclic oligomers with relatively high molecular weight, dinuclear cyclic platinum(II) complexes with Troger's base ligands and highly strained cyclic organic compounds. Transmetalation of arylplatinum(II) complexes are investigated in detail and its reversibility in solution are found to be highly affected by its supporting ligand.

Free Research Field

有機金属化学