2014 Fiscal Year Final Research Report
Creation of PCP/metal nanoparticles for high density and rapid hydrogen storage material
Project/Area Number |
25870350
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
Organic and hybrid materials
|
Research Institution | Kyoto University |
Principal Investigator |
|
Project Period (FY) |
2013-04-01 – 2015-03-31
|
Keywords | 金属ナノ粒子 / 多孔性金属錯体 / 水素吸蔵 |
Outline of Final Research Achievements |
Remarkably enhanced capacity and speed of hydrogen storage in Pd nanocrystals were discovered by coating with the metal–organic framework (MOF) HKUST-1 (copper(II) 1,3,5-benzenetricarboxylate). The Pd nanocrystals covered with the MOF have twice the storage capacity of the bare Pd nanocrystals. The significantly enhanced hydrogen storage capacity was confirmed by hydrogen pressure composition isotherms. The speed of hydrogen absorption in the Pd nanocrystals is also enhanced by the MOF coating.
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Free Research Field |
化学
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