2014 Fiscal Year Final Research Report
Preparation of heter-layers with pKa gradient based on carbon materials toward proton conductor
| Project/Area Number |
25870746
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanomaterials chemistry
Organic and hybrid materials
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| Research Institution | Chuo University |
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Principal Investigator |
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Keywords | ルテニウム / 酸化還元 / HOPG |
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| Outline of Final Research Achievements |
We synthesized functional redox-active Ru complexes with different number of pyrene anchors. Pyrene anchors can be absorbed to pai-conjugated carbon materials such as graphene and carbon nanotubes. The adsorption stability of the Ru complex onto nano-carbon surfaces such as graphene and single-walled carbon nanotube (SWNT) were evaluated by electrochemical measurements, which provides a fundamental guideline to design the functional molecule/carbon materials nano-composites through non-covalent interactions. Additionally, we calculated the electron transfer rate from ruthenium complex to carbon materials such as single, multi-walled carbon nanotube, and HOGP.
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| Free Research Field |
錯体化学
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