2015 Fiscal Year Final Research Report
Synthesis and Anion Recognition Behavior of Conjugated Polymers by Direct Arylation Polycondensation
| Project/Area Number |
26620173
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
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| Project Period (FY) |
2014-04-01 – 2016-03-31
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| Keywords | 高分子合成 / 有機導体 / 環境材料 |
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| Outline of Final Research Achievements |
1,8-Carbazole-based conjugated polymers were synthesized by environmentally-friendly polymerization methods. When direct arylation polycondensation was applied, the desired polymers could not be obtained due to the steric reason. In contrast, poly(1,8-carbazole)s could be produced by the azide-alkyne click polymerization. The resulting poly(1,8-carbazole)s showed the specific fluorescence changes in response to the cyanate anion and tin cation.
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| Free Research Field |
高分子化学
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