1988 Fiscal Year Final Research Report Summary
Indirect Amperometric Detection of Aliphatic Amine in Flow System
Project/Area Number |
62570966
|
Research Category |
Grant-in-Aid for General Scientific Research (C)
|
Allocation Type | Single-year Grants |
Research Field |
Physical pharmacy
|
Research Institution | Osaka University |
Principal Investigator |
MASUI MASAICHIRO Professor of Pharmaceutical Scienses, Osaka University, 薬学部, 教授 (20028822)
|
Project Period (FY) |
1987 – 1988
|
Keywords | Electrochemical detector / Indirect amperometric detection / Aliphatic amine / N-Hydroxyphthalimide / ハイドロキノン |
Research Abstract |
N-Hydroxyphthalimede(NHPI) was used for amperometric detection of aliphatic amines in flow systems by monitoring the current of amine-NHPI complexes. The principles of the tecnique were discussed through cyclic voltammetries of butylamine-NHPI systemes in 0.1M tetraethyl-ammonium perchlorate/acetonitrile. The priority of the detection with respect to the potential dependence and a linear relationship between the observed peak current and the amount of the amine up to 120 ng injection were demonstrated.
|
Research Products
(2 results)