配位アシンメトリー：非対称配位圏設計と異方集積化が拓く新物質科学

• Project Area: Coordination Asymmetry: Design of Asymmetric Coordination Sphere and Anisotropic Assembly for the Creation of Functional Molecules
• Project/Area Number: 16K21733
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Multi-year Fund
• Review Section: Science and Engineering
• Research Institution: The University of Tokyo
• Principal Investigator: 塩谷 光彦 東京大学, 大学院理学系研究科(理学部), 教授 (60187333)
• Co-Investigator(Kenkyū-buntansha): 寺西 利治 京都大学, 化学研究所, 教授 (50262598) ; 植村 卓史 東京大学, 大学院新領域創成科学研究科, 教授 (50346079) ; 君塚 信夫 九州大学, 工学研究院, 教授 (90186304)
• Project Period (FY): 2016-06-30 – 2023-03-31
• Project Status: Granted (Fiscal Year 2021)
• Budget Amount: ¥61,360,000 (Direct Cost: ¥47,200,000、Indirect Cost: ¥14,160,000); Fiscal Year 2020: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000); Fiscal Year 2019: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000); Fiscal Year 2018: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000); Fiscal Year 2017: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000); Fiscal Year 2016: ¥12,480,000 (Direct Cost: ¥9,600,000、Indirect Cost: ¥2,880,000)
• Keywords: 配位アシンメトリー / キラル金属錯体 / 多核金属錯体 / 非対称配位圏 / 非対称構造 / 金属錯体 / 分子集積化 / 不斉合成 / 異方集積化 / 錯体化学

Outline of Annual Research Achievements

新学術領域研究「配位アシンメトリ」は、錯体化学および関連分野において未開拓であった金属中心の非対称配位圏の設計・合成法と異方集積化法の新しい学理を確立することを目的としている。この新領域を広く普及させ可視化するためには、国際的なネットワーク形成や異分野交流が必要である。2021年度は国際融合バーチャルラボの協力体制の下に研究活動を推進した。約5年間で構築した国内外の研究ネットワークの多くが継続的な共同研究や人事交流につながっている。
主な領域全体の国際的活動の一つとして、新型コロナウイルスの感染症の影響により延期していた環太平洋国際化学会議（Pacifichem 2020、日本化学会等主催）の配位アシンメトリー（Coordination Asymmetry: Symposium #248）セッションがオンラインで開催された。国外6件、計画研究15件、公募・一般17件の口頭・ポスター発表に基づき、100名を超える参加者の間で、非対称配位圏に基づく構造・物性・機能に関する議論や情報交換が活発に行われた。また、2016年度から2020年度までに本新学術領域研究から1300報を超える国際学術論文が発表されたが、本年度はこれらの研究成果からナノアーキテクトニクスに関する論文の一部を選び、Bull. Chem. Soc. Jpn.の総説として、国際情報発信に努めた。まだ1年程しか経っていないが、すでに被引用回数が約40件に達しており、国際的な注目度が高いことが示された。

Current Status of Research Progress

2: Research has progressed on the whole more than it was originally planned.

Reason

2021年度は引き続き、配位アシンメトリーに関する国際共同研究を推進し、本領域の普及化と国際活動のための支援体制強化を図った。例えば、領域代表者の塩谷は「キラル@メタルラボ」において、2019 年度に中国の清華大学のWang教授のグループから招聘した２名の研究者を、国際活動支援経費および本学の経費により特任助教として雇用した。主に、新しい炭素中心金クラスターの不斉合成、およびそれらのリン光特性を利用した細胞イメージングを展開してきた。さらに、中国人留学生3名を研究室に受入れ、四面体型金属錯体のChiral-at-Metalの化学を精力的に推進した。また、ドイツのマールブルク大学とも研究交流を継続している。これらの新しい成果は、J. Am. Chem. Soc.などの著名な国際学術誌4報に発表し、さらにBull. Chem. Soc. Jpn.に総説を発表して国際情報発信に努めた。新型コロナウイルスの感染症の影響により延期していたPacifichem 2020のCoordination Asymmetryセッションを本年度にオンライン開催することができ、新しい学術領域が普及しつつあることを認識できた。また、本領域の研究グループの多くの研究成果がオンライン国際会議で発表された。残念ながら、2021年度も様々な国際交流や公開シンポジウムの予定が延期あるいは中止になったが、その状況に合わせた形で国際的に情報交換を行い、一定以上の研究成果や国際ネットワークの構築が実現された。

Strategy for Future Research Activity

2022年度は、配位アシンメトリーに関する国際共同研究を継続的に推進するとともに、研究成果の国際情報発信を強化し、本領域の普及化を推進する。具体的には、新型コロナウイルスの感染状況を考慮しつつ、2021年度に予定していた「配位アシンメトリー（あるいは全元素への発展型として、元素中心キラリティー）に関する国際会議（公開）」を対面形式で開催し、本領域のビジビリティーの向上を図る。また、本領域の多くの研究者が関連するアジア錯体化学国際会議 (ACCC8、台湾) への参加を促す。さらに、領域代表者の塩谷と計画班メンバーがそれぞれ編集委員長を務めている日本化学会の2誌、Chem. Lett.およびBull. Chem. Soc. Jpn.を活用して、本領域の研究成果の国際情報発信および若手研究者の奨励を進める。

Research Products

• [Int'l Joint Research] The Philipps University of Marburg(ドイツ)
• [Int'l Joint Research] Tsinghua University(中国)
• [Int'l Joint Research] 華東師範大学/清華大学/東呉大学(中国)
• [Int'l Joint Research] Philipps-Universitat Marburg(ドイツ)
• [Int'l Joint Research] Royal Melbourne Institute of Technology(オーストラリア)
• [Int'l Joint Research] KAIST(韓国)
• [Int'l Joint Research] Universidad de Castilla-La Mancha(スペイン)
• [Int'l Joint Research]
• [Int'l Joint Research] University of Marburg/University of Bonn/University of Muenster(ドイツ)
• [Int'l Joint Research] East China Normal University/Tsinghua University/Nankai University(中国)
• [Int'l Joint Research] University of Birmingham(英国)
• [Int'l Joint Research] University of Marburg/University of Munster/Technical University of Dortmund(Germany)
• [Int'l Joint Research] Indiana University(米国)
• [Int'l Joint Research] University if Amsterdam/University of Groningen(オランダ)
• [Int'l Joint Research] University of Edinburgh/University of Birmingham(英国)
• [Int'l Joint Research] East China Normal University/Nankai University/Peking University(China)
• [Int'l Joint Research]
• [Int'l Joint Research] University of Amsterdam(オランダ)
• [Int'l Joint Research] University of Edinburgh/University of Birmingham(英国)
• [Int'l Joint Research] University of Marburg/University of Munster/Technical University of Dortmund(Germany)
• [Int'l Joint Research] University of Strasbourg(France)
• [Int'l Joint Research] East China Normal University/Nankai University/Peking University(China)
• [Int'l Joint Research]
• [Journal Article] Asymmetric Twisting of <i>C</i>-Centered Octahedral Gold(I) Clusters by Chiral <i>N</i>-Heterocyclic Carbene Ligation (2022)
  • Author(s): Pei Xiao-Li、Zhao Pei、Ube Hitoshi、Lei Zhen、Nagata Koichi、Ehara Masahiro、Shionoya Mitsuhiko
  • Journal Title: Journal of the American Chemical Society Volume: 144 Issue: 5 Pages: 2156-2163
  • DOI: 10.1021/jacs.1c10450
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Reconstituting C-Centered Hexagold(I) Clusters with <i>N</i>-Heterocyclic Carbene Ligands (2021)
  • Author(s): Z. Lei, X.-L. Pei, H. Ube, M. Shionoya
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 94 Issue: 4 Pages: 1324-1330
  • DOI: 10.1246/bcsj.20210060
  • NAID: 130008037352
  • ISSN: 0009-2673, 1348-0634
  • Year and Date: 2021-04-15
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Nanoarchitectonics for Coordination Asymmetry and Related Chemistry (2021)
  • Author(s): K. Ariga, M. Shionoya
  • Journal Title: Bulletin of the Chemical Society of Japan Volume: 94 Issue: 3 Pages: 839-859
  • DOI: 10.1246/bcsj.20200362
  • NAID: 130008021843
  • ISSN: 0009-2673, 1348-0634
  • Year and Date: 2021-03-15
  • Peer Reviewed / Open Access
• [Journal Article] Site-Specific Polymerase Incorporation of Consecutive Ligand-Containing Nucleotides for Multiple Metal-Mediated Base Pairing (2021)
  • Author(s): T. Nakama, Y. Takezawa, M. Shionoya
  • Journal Title: Chemical Communications Volume: 57 Issue: 11 Pages: 1392-1395
  • DOI: 10.1039/d0cc07771b
  • Peer Reviewed
• [Journal Article] Face-selective adsorption of a prochiral compound on the chiral pore-surface of metal-macrocycle framework (MMF) directed towards stereoselective reactions (2021)
  • Author(s): Tashiro Shohei, Umeki Tsutomu, Kubota Ryou, Shionoya Mitsuhiko
  • Journal Title: Faraday Discussions Volume: 225 Pages: 197-209
  • DOI: 10.1039/d0fd00019a
  • Peer Reviewed
• [Journal Article] Mechanistic Studies on Photoinduced Catalytic Olefin Migration Reactions at the Pd(II) Centers of a Porous Crystal, Metal-Macrocycle Framework (2021)
  • Author(s): H. Yonezawa, T. Shiraogawa, M. Han, S. Tashiro, M. Ehara, M. Shionoya
  • Journal Title: Chemistry Asian Journal Volume: 16 Issue: 3 Pages: 202-205
  • DOI: 10.1002/asia.202001306
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Metal-responsive Reversible Binding of Triplex-forming Oligonucleotides with 5-Hydroxyuracil Nucleobases (2021)
  • Author(s): K. Nishiyama, K. Mori, Y. Takezawa, M. Shionoya
  • Journal Title: Chemical Communications Volume: 57 Issue: 20 Pages: 2487-2490
  • DOI: 10.1039/d1cc00553g
  • Peer Reviewed
• [Journal Article] Phase-Dependent Reactivity and Host-Guest Behaviors of a Metallo-Macrocycle in Liquid and Solid-State Photosensitized Oxygenation Reactions (2021)
  • Author(s): K. Omoto, S. Tashiro, M. Shionoya
  • Journal Title: Journal of the American Chemical Society Volume: 143 Issue: 14 Pages: 5406-5412
  • DOI: 10.1021/jacs.0c13338
  • Peer Reviewed
• [Journal Article] Self-assembled Porphyrin-based Cage Complexes, M₁₁L₆ (M = Zn^II, Cd^II), with Inner Coordination Sites in Their Crystal Structure (2020)
  • Author(s): F. Iizuka, H. Ube, H. Sato, T. Nakamura, M. Shionoya
  • Journal Title: Chemistry Letters Volume: 49 Issue: 3 Pages: 323-326
  • DOI: 10.1246/cl.190943
  • NAID: 130007805920
  • ISSN: 0366-7022, 1348-0715
  • Year and Date: 2020-03-05
  • Peer Reviewed
• [Journal Article] Multi-Stimuli Responsive Interconversion between Bowl- and Capsule-Shaped Self-Assembled Zinc(II) Complexes (2020)
  • Author(s): K. Endo, H. Ube, M. Shionoya
  • Journal Title: Journal of the American Chemical Society Volume: 142 Issue: 1 Pages: 407-416
  • DOI: 10.1021/jacs.9b11099
  • Peer Reviewed
• [Journal Article] Supramolecular DNA Three-way Junction Motifs with a Bridging Metal Center (2020)
  • Author(s): Y. Takezawa, M. Shionoya
  • Journal Title: Frontiers in Chemistry Volume: 7 Pages: 925-925
  • DOI: 10.3389/fchem.2019.00925
  • Peer Reviewed / Open Access
• [Journal Article] Novel Porous Crystals with Macrocycle-Based Well-Defined Molecular Recognition Sites (2020)
  • Author(s): S. Tashiro, and M. Shionoya
  • Journal Title: Acc. Chem. Res. Volume: 53 Issue: 3 Pages: 632-643
  • DOI: 10.1021/acs.accounts.9b00566
  • Peer Reviewed
• [Journal Article] Core-Shell Metal-Macrocycle Framework (MMF): Spatially Selective Dye Inclusion through Core-to-Shell Anisotropic Transport along Crystalline 1D-Channels Connected by Epitaxial Growth (2020)
  • Author(s): S. Tashiro, S. Mitsui, D. W. Burke, R. Kubota, N. Matsushita, M. Shionoya
  • Journal Title: CrystEngComm Volume: 22 Issue: 8 Pages: 1306-1309
  • DOI: 10.1039/d0ce00120a
  • Peer Reviewed
• [Journal Article] Ligand Effects on the Photophysical Properties of N,N’-Diisopropylbenzimidazolydene-Protected C-Centered Hexagold(I) Clusters (2020)
  • Author(s): Z. Lei, K. Nagata, H. Ube, M. Shionoya
  • Journal Title: Journal of Organometallic Chemistry Volume: 917 Pages: 121271-121271
  • Peer Reviewed
• [Journal Article] Allosteric Regulation of DNAzyme Activities through Intrastrand Transformation Induced by Cu(II)-Mediated Artificial Base Paring (2020)
  • Author(s): T. Nakama, Y. Takezawa, D. Sasaki, M. Shionoya
  • Journal Title: Journal of the American Chemical Society Volume: 142 Issue: 22 Pages: 10153-10162
  • DOI: 10.1021/jacs.0c03129
  • Peer Reviewed
• [Journal Article] Sharp Switching of DNAzyme Activity through the Formation of a Cu(II)-mediated Carboxyimidazole Base Pair (2020)
  • Author(s): Y. Takezawa, L. Hu, T. Nakama, M. Shionoya
  • Journal Title: Angewandte Chemie International Edition Volume: 59 Issue: 48 Pages: 21488-21492
  • DOI: 10.1002/anie.202009579
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Protonation-induced Self-assembly of Bis-phenanthroline Macrocycles into Nanofibers Arrayed with Tetrachloroaurate, Hexachloroplatinate or Phosphomolybdate Ions (2020)
  • Author(s): S. Tashiro, S. Shimizu, M. Kuritani, M. Shionoya
  • Journal Title: Dalton Transactions Volume: 49 Pages: 13948-13953
  • Peer Reviewed
• [Journal Article] Asymmetric construction of tetrahedral chiral zinc with high configurational stability and catalytic activity (2020)
  • Author(s): Endo Kenichi、Liu Yuanfei、Ube Hitoshi、Nagata Koichi、Shionoya Mitsuhiko
  • Journal Title: Nature Communications Volume: 11 Issue: 1 Pages: 6263-6263
  • DOI: 10.1038/s41467-020-20074-7
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Metal-Dependent DNA Base Pairing of 5-Carboxyuracil with Itself and All Four Canonical Nucleobases (2020)
  • Author(s): Y. Takezawa, A. Suzuki, M. Nakaya, K. Nishiyama, M. Shionoya
  • Journal Title: Journal of the American Chemical Society Volume: 142 Issue: 52 Pages: 21640-21644
  • DOI: 10.1021/jacs.0c11437
  • Peer Reviewed
• [Journal Article] Synthesis of Hetero-multinuclear Metal Complexes by Site-Selective Redox Switching and Transmetalation on a Homo-multinuclear Complex (2019)
  • Author(s): H. Ube, K. Endo, H. Sato, M. Shionoya
  • Journal Title: Journal of the American Chemical Society Volume: 141 Issue: 26 Pages: 10384-10389
  • DOI: 10.1021/jacs.9b04123
  • Peer Reviewed
• [Journal Article] Molecular Recognition of Planar and Non-Planar Aromatic Hydrocarbons through Multipoint Ag-π Bonding in a Dinuclear Metallo-Macrocycle (2019)
  • Author(s): K. Omoto, S. Tashiro, M. Shionoya
  • Journal Title: Chemical Sciences Volume: 10 Issue: 30 Pages: 7172-7176
  • DOI: 10.1039/c9sc02619c
  • Peer Reviewed
• [Journal Article] Enzymatic Synthesis of Cu(II)-responsive Deoxyribozymes through Polymerase Incorporation of Artificial Ligand-type Nucleotides (2019)
  • Author(s): Y. Takezawa, T. Nakama, M. Shionoya
  • Journal Title: Journal of the American Chemical Society Volume: 141 Issue: 49 Pages: 19342-19350
  • DOI: 10.1021/jacs.9b08955
  • Peer Reviewed
• [Journal Article] Carrier-Selective Blocking Layer Synergistically Improves the Plasmonic Enhancement Effect (2019)
  • Author(s): Kawawaki Tokuhisa、Nakagawa Tatsuo、Sakamoto Masanori、Teranishi Toshiharu
  • Journal Title: Journal of the American Chemical Society Volume: 印刷中 Issue: 21 Pages: 8402-8406
  • DOI: 10.1021/jacs.9b01419
  • Peer Reviewed
• [Journal Article] Transcription of Chirality from Metal?Organic Framework to Polythiophene (2019)
  • Author(s): Kitao Takashi、Nagasaka Yujiro、Karasawa Masanobu、Eguchi Toshiki、Kimizuka Nobuo、Ishii Kazuyuki、Yamada Teppei、Uemura Takashi
  • Journal Title: Journal of the American Chemical Society Volume: 141 Issue: 50 Pages: 19565-19569
  • DOI: 10.1021/jacs.9b10880
  • Peer Reviewed
• [Journal Article] A Carbon-Centered Hexagold(I) Cluster Supported by N-Heterocyclic Carbene Ligands (2018)
  • Author(s): H. Ube, Q. Zhang, M. Shionoya
  • Journal Title: Organometallics Volume: 37 Issue: 13 Pages: 2007-2009
  • DOI: 10.1021/acs.organomet.8b00291
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Rational synthesis of benzimidazole[3]arenes by CuII-catalyzed post-macrocyclization transformation (2018)
  • Author(s): Tashiro Shohei、Umeki Tsutomu、Kubota Ryou、Shionoya Mitsuhiko
  • Journal Title: Chemical Science Volume: 9 Issue: 39 Pages: 7614-7619
  • DOI: 10.1039/c8sc03086c
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Preferential Photoreaction in a Porous Crystal, Metal-Macrocycle Framework: PdII-Mediated Olefin Migration over [2+2] Cycloaddition (2018)
  • Author(s): H. Yonezawa, S. Tashiro, T. Shiraogawa, M. Ehara, R. Shimada, T. Ozawa, M. Shionoya
  • Journal Title: Journal of the American Chemical Society Volume: 140 Issue: 48 Pages: 16610-16614
  • DOI: 10.1021/jacs.8b08534
  • Peer Reviewed
• [Journal Article] Dynamic Nuclear Polarization of Metal-Organic Frameworks Using Photoexcited Triplet Electrons (2018)
  • Author(s): Saiya Fujiwara; Masanori Hosoyamada; Kenichiro Tateishi; Tomohiro Uesaka; Keiko Ideta; Nobuo Kimizuka; Nobuhiro Yanai
  • Journal Title: Journal of the American Chemical Society Volume: 140 Issue: 46 Pages: 15608-15610
  • DOI: 10.1021/jacs.8b10121
  • Peer Reviewed
• [Journal Article] Sequence-regulated copolymerization based on periodic covalent positioning of monomers along one-dimensional nanochannels (2018)
  • Author(s): Shuto Mochizuki, Naoki Ogiwara, Masayoshi Takayanagi, Masataka Nagaoka, Susumu Kitagawa, Takashi Uemura
  • Journal Title: Nature Commun. Volume: 9 Issue: 1 Pages: 329-329
  • DOI: 10.1038/s41467-017-02736-1
  • NAID: 120006380534
  • Peer Reviewed / Open Access
• [Journal Article] Near Infrared Light Induced Plasmonic Hot Hole Transfer at a Nano-Heterointerface (2018)
  • Author(s): Z. Lian M. Sakamoto H. Matsunaga J. J. M. Vequizo A. Yamakata M. Haruta H. Kurata W. Ota T. Sato T. Teranishi
  • Journal Title: Nat. Commun. Volume: 9 Issue: 1 Pages: 23141-7
  • DOI: 10.1038/s41467-018-04630-w
  • NAID: 120006488580
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Chiral Metallosupramolecular Architectures (2017)
  • Author(s): L.-J. Chen, H.-B. Yang, M. Shionoya
  • Journal Title: Chemical Society Reviews Volume: 46 Issue: 9 Pages: 2555-2576
  • DOI: 10.1039/c7cs00173h
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Artificial DNA Base Pairing Mediated by Diverse Metal Ions (2017)
  • Author(s): Makoto Ebine, Yuri Takada, Naoto Yanai, and Tohru Oishi
  • Journal Title: Chemistry Letters Volume: 46 Issue: 5 Pages: 622-633
  • DOI: 10.1246/cl.160985
  • NAID: 130005655669
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Chiral Metallosupramolecular Architectures (2017)
  • Author(s): Li-Jun Chen, Hai-Bo Yang, Mitsuhiko Shionoya
  • Journal Title: Chem. Soc. Rev. Volume: 印刷中
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Presentation] Coordination Asymmetry in Supramolecular Chemistry (2022)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: Norway-Japan symposium on theoretical and experimental chemistry of complex systems, Oslo-Tokyo
  • Int'l Joint Research / Invited
• [Presentation] From Self-Assembly to Steric Control: Supramolecular Approaches based on Molecular Design (2021)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: ISMSC 2021 Virtual Symposium, Award Lecture for International Izatt-Christensen Award 2020
  • Int'l Joint Research / Invited
• [Presentation] 超分子金属錯体から、配位アシンメトリーへ (2020)
  • Author(s): 塩谷光彦
  • Organizer: FBCシンポジウム
  • Invited
• [Presentation] 超分子金属錯体から、配位アシンメトリーへ (2020)
  • Author(s): 塩谷光彦
  • Organizer: 錯体若手の会 第7回Web勉強会
  • Invited
• [Presentation] アキラルな配位子のみで作る 不斉空間と不斉金属触媒 (2020)
  • Author(s): 塩谷光彦
  • Organizer: 第13回有機触媒シンポジウム
  • Invited
• [Presentation] Supramolecular Coordination Chemistry: Array, Space, and Motion (2019)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: 1st Meeting of Core-to-Core Program on Coordination Nanosheet
  • Int'l Joint Research / Invited
• [Presentation] Complexity in Coordination-Driven Self-Assembly: Molecular Design and Serendipity (2019)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: The 30th Anniversary Todai-Unisra Symposium on “Complexity”
  • Int'l Joint Research / Invited
• [Presentation] Metal-responsive DNAzymes based on Metal-mediated DNA Base Pairing (2019)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: ICBIC2019: 19th International Conference on Biological Inorganic Chemistry
  • Int'l Joint Research / Invited
• [Presentation] Molecular Design and Serendipity in Coordination-Driven Self-Assembly (2019)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: QSCC2019
  • Int'l Joint Research / Invited
• [Presentation] Coordination Asymmetry In Supramolecular Chemistry (2019)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: Complex Systems Made Simple
  • Int'l Joint Research / Invited
• [Presentation] Coordination-Driven Self-Assembly: Design and Serendipity (2019)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: 12th China-Japan Joint Symposium on Metal Cluster Compounds
  • Int'l Joint Research / Invited
• [Presentation] Coordination Asymmetry in Supramolecular Architectures (2019)
  • Author(s): Mitsuhiko Shionoya
  • Organizer: EPSRC-JSPS Core-to-Core International Workshop on Two-Dimensional Coordination Nanosheets
  • Int'l Joint Research / Invited
• [Presentation] Coordination Asymmetry based on Supramolecular Porous Crystals (2018)
  • Author(s): M. Shionoya
  • Organizer: International Symposium on Macrocyclic and Supramolecular Chemistry
  • Int'l Joint Research / Invited
• [Presentation] 超分子金属錯体:配列、空間、モーション (2018)
  • Author(s): 塩谷光彦
  • Organizer: 錯体化学会第68回討論会
  • Invited
• [Presentation] Molecular Behavior in Supramolecular Spaces (2018)
  • Author(s): M. Shionoya
  • Organizer: International Conference on Coordination Chemistry 2018
  • Int'l Joint Research / Invited
• [Presentation] Metal-mediated Supramolecular Array, Space and Motion (2018)
  • Author(s): M. Shionoya
  • Organizer: iJaDe2018: From Molecules to Materials
  • Int'l Joint Research / Invited
• [Presentation] Rational Design of Metal-based Supermolecules (2018)
  • Author(s): M. Shionoya
  • Organizer: 第28回光学活性化合物シンポジウム
  • Int'l Joint Research / Invited
• [Presentation] 超分子金属錯体:配列、空間、モーション (2018)
  • Author(s): 塩谷光彦
  • Organizer: 近畿化学協会 有機金属部会平成30年度第3回例会
  • Invited
• [Book] 錯体化合物事典 (2019)
  • Author(s): 塩谷光彦、竹澤悠典（分担執筆）
  • Total Pages: 1000
  • Publisher: 朝倉書店
  • ISBN: 9784254141054
• [Remarks] 新しい学理「配位アシンメトリー」の創出
  • URL: http://www.asymmetallic.jp
• [Remarks] 塩谷研究室 Bioinorganic Chemistry Laboratory
  • URL: http://www.chem.s.u-tokyo.ac.jp/users/bioinorg/index.html
• [Remarks] 配位アシンメトリー:非対称配位圏設計と異方集積化が拓く新物質科学
  • URL: http://www.asymmetallic.jp
• [Remarks] 塩谷研究室 Bioinorganic Chemistry Laboratory
  • URL: http://www.chem.s.u-tokyo.ac.jp/users/bioinorg/index.html
• [Remarks] 配位アシンメトリー：非対称配位圏設計と異方集積化が拓く新物質科学
• [Remarks] 配位アシンメトリー：非対称配位圏設計と異方集積化が拓く新物質科学
  • URL: http://www.asymmetallic.jp
• [Remarks] 塩谷研究室 Bioinorganic Chemistry Laboratory
  • URL: http://www.asymmetallic.jp
• [Funded Workshop] Pacifichem 2020: Sympossium session #248, Coordination Asymmetry (2021)