Creation of novel reaction processes by precise control of highly active hydrogen

• Project Area: HYDROGENOMICS: Creation of Innovative Materials, Devices, and Reaction Processes using Higher-Order Hydrogen Functions
• Project/Area Number: 18H05517
• Research Category: Grant-in-Aid for Scientific Research on Innovative Areas (Research in a proposed research area)
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyushu University
• Principal Investigator: 山内 美穂 九州大学, 先導物質化学研究所, 教授 (10372749)
• Co-Investigator(Kenkyū-buntansha): 吉信 淳 東京大学, 物性研究所, 教授 (50202403) ; 張 浩徹 中央大学, 理工学部, 教授 (60335198) ; 島 隆則 国立研究開発法人理化学研究所, 開拓研究本部, 専任研究員 (60391976) ; 藤田 健一 京都大学, 人間・環境学研究科, 教授 (80293843)
• Project Period (FY): 2018-06-29 – 2023-03-31
• Project Status: Granted (Fiscal Year 2022)
• Budget Amount: ¥202,540,000 (Direct Cost: ¥155,800,000、Indirect Cost: ¥46,740,000); Fiscal Year 2022: ¥37,700,000 (Direct Cost: ¥29,000,000、Indirect Cost: ¥8,700,000); Fiscal Year 2021: ¥39,520,000 (Direct Cost: ¥30,400,000、Indirect Cost: ¥9,120,000); Fiscal Year 2020: ¥39,390,000 (Direct Cost: ¥30,300,000、Indirect Cost: ¥9,090,000); Fiscal Year 2019: ¥39,130,000 (Direct Cost: ¥30,100,000、Indirect Cost: ¥9,030,000); Fiscal Year 2018: ¥46,800,000 (Direct Cost: ¥36,000,000、Indirect Cost: ¥10,800,000)
• Keywords: 反応促進 / 高活性水素 / クラスター / 膜 / ナノ粒子 / 原子状水素 / ヒドリド / プロトン / 反応高活性化 / 水素 / ハイドロジェノミクス / 高次水素機能 / 反応 / ナノ構造体 / 合金ナノ粒子 / 錯体 / 新反応 / 高効率プロセス

Outline of Annual Research Achievements

高活性水素を選択的に生成するナノ構造体界面を構築する技術を確立するため、ナノ構造体（ナノ粒子、薄膜、クラスター）界面での高活性水素（原子状水素H0、ヒドリドH-、プロトンH+）の高選択的生成法を確立することを目的とする。本年度には以下のような成果が得られた。
金属ナノ粒子界面に生成する原子状水素は高い反応性を示すと期待できる。新規ナノ構造体として、高表面積を有する多孔性配位高分子であるMIL-101を金属Pdで被覆することでPdナノカプセル（Pd/MIL-101）を作製した。Pd/MIL-101はMIL-101への物理吸着とPd内部の化学吸着の協同効果により温和な条件（223 K、10気圧）で高い水素吸蔵特性を示すことがわかった。2H NMRや水素圧力下ESR測定からナノカプセル界面にはPd表面からMOF上にスピルオーバーした原子状（重）水素が存在することが明らかとなった。Pd膜上でのスピルオーバー水素のその場XPS測定に成功するなど、高活性水素の観察方法の開発も大きく進んだ。また、シクロペンタジエニル基C5Me4SiMe3を有する希土類金属や4族遷移金属からなる高活性ヒドリドを含む水素クラスターの構築に初めて成功した(J. Phy. Soc. Jpn., 2020)。特に、C5Me4SiMe3基を有する多核チタン水素クラスターは、窒素分子の切断と水素化や、芳香族化合物の炭素－炭素結合切断と骨格変換反応など、非常に高い反応性を示すことが明らかとなった(J. Am. Chem. Soc. 2019)。さらに、プロトン/電子プーリング機能を有する二置換芳香族分子に対する光照射により活性水素ラジカルの選択的放出に関する官能基依存性を定量的に初めて明らかにした。

Current Status of Research Progress

1: Research has progressed more than it was originally planned.

Reason

Pdナノカプセルの内部界面には、高い活性を示すと期待される原子状のスピルオーバー水素が生成することや、新規に作製した体心立法型RuFeナノ合金上では、N2およびH2が高度に活性化され、高いNH3合成活性を示すことが明らかにななるなど、当初の予想を超える成果が得られている。また、Pd単原子合金モデル触媒上での、水素分子の解離吸着、Cuサイトへの水素原子のスピルオーバー現象、ギ酸の分解とフォルメート種の水素化反応についての知見も得られてきた。さらに、水素クラスターや遷移金属錯体の化学状態及び水素との相互作用をオペランドX線光電子分光を使って調べるための実験が進んでいる。

Strategy for Future Research Activity

領域内連携での量子化学計算によるメカニズム解析とともに、A04とA05-1で開発をすすめるその場変調励起減衰分光(MES)やオペランド計測を組み合わせて、ナノ合金界面に生成する原子状水素や基質分子の化学状態の解明を行うことや、A05-2との連携により実験・理論の両面から高活性水素の電子状態と反応メカニズムの関連性を解明することで高活性水素の特性を活用した高選択、高難度、高効率の反応プロセスを開拓する。

Research Products

• [Journal Article] A computational examination of the electric-field-induced proton transfer along the interface hydrogen bond between proton donating and accepting self-assembled monolayers (2020)
  • Author(s): Kanematsu Yusuke、Kato Hiroyuki S.、Yoshimoto Shinya、Ueda Akira、Yamamoto Susumu、Mori Hatsumi、Yoshinobu Jun、Matsuda Iwao、Tachikawa Masanori
  • Journal Title: ChemCatChem Volume: 741 Pages: 137091-137091
  • DOI: 10.1016/j.cplett.2020.137091
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Electrosynthesis of amino acids from biomass-derivable acids on titanium dioxide (2019)
  • Author(s): Fukushima Takashi、Yamauchi Miho
  • Journal Title: Chem. Commun. Volume: 55 Pages: 14721-14724
  • DOI: 10.1039/c9cc07208j
  • Peer Reviewed
• [Journal Article] Catalytic enhancement on Ti-Zr complex oxide particles for electrochemical hydrogenation of oxalic acid to produce an alcoholic compound by controlling electronic states and oxide structures (2019)
  • Author(s): Yamauchi M.、Hata S.、Eguchi H.、Kitano S.、Fukushima T.、Higashi M.、Sadakiyo M.、Kato K.
  • Journal Title: Cat. Sci. Tec. Volume: 9 Pages: 6561-6565
  • DOI: 10.1039/c9cy01541h
  • Peer Reviewed
• [Journal Article] Electrochemical hydrogenation of non-aromatic carboxylic acid derivatives as a sustainable synthesis process: from catalyst design to device construction (2019)
  • Author(s): Sadakiyo Masaaki、Hata Shinichi、Fukushima Takashi、Juh?sz Gergely、Yamauchi Miho
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 21 Pages: 5882-5889
  • DOI: 10.1039/c8cp07445c
  • Peer Reviewed
• [Journal Article] Tailoring Widely Used Ammonia Synthesis Catalysts for H and N Poisoning Resistance (2019)
  • Author(s): K. Ghuman, K. Tozaki, M. Sadakiyo, S. Kitano, T. Oyabe, M. Yamauchi
  • Journal Title: Physical Chemistry Chemical Physics Volume: 21 Pages: 5117-5122
  • DOI: 10.1039/c8cp05800h
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Mass transport in the PdCu phase structures during hydrogen adsorption and absorption studied by XPS under hydrogen atmosphere (2019)
  • Author(s): Tang Jiayi、Yamamoto Susumu、Koitaya Takanori、Yoshigoe Akitaka、Tokunaga Takuma、Mukai Kozo、Matsuda Iwao、Yoshinobu Jun
  • Journal Title: Applied Surface Science Volume: 480 Pages: 419-426
  • DOI: 10.1016/j.apsusc.2019.02.180
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Direct Evidence of Interfacial Hydrogen Bonding in Proton-Electron Concerted 2D Organic Bilayer on Au Substrate (2019)
  • Author(s): Yamamoto Susumu、Kato Hiroyuki S.、Ueda Akira、Yoshimoto Shinya、Hirata Yasuyuki、Miyawaki Jun、Yamamoto Kohei、Harada Yoshihisa、Wadati Hiroki、Mori Hatsumi、Yoshinobu Jun、Matsuda Iwao
  • Journal Title: e-J. Surf. Sci. Nanotech Volume: 17 Issue: 0 Pages: 137091-137091
  • DOI: 10.1380/ejssnt.2019.49
  • NAID: 130007638859
  • ISSN: 1348-0391
  • Peer Reviewed / Open Access
• [Journal Article] Experimental and Computational Studies of Dinitrogen Activation and Hydrogenation at a Tetranuclear Titanium Imide/Hydride Framework (2019)
  • Author(s): T. Shima, G. Luo, S. Hu, Y. Luo, Z. Hou
  • Journal Title: J. Am. Chem. Soc. Volume: 141 Pages: 2713-2720
  • DOI: 10.1021/jacs.8b13341
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Impact of TiO2-II phase stabilized in anatase matrix by high-pressure torsion on electrocatalytic hydrogen production (2019)
  • Author(s): Edalati Kaveh、Wang Qing、Eguchi Hiroto、Razavi-Khosroshahi Hadi、Emami Hoda、Yamauchi Miho、Fuji Masayoshi、Horita Zenji
  • Journal Title: Mater. Res. Lett. Volume: 7 Pages: 334-339
  • DOI: 10.1080/21663831.2019.1609111
  • NAID: 120006844839
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] The Impact of Group‐10 Metals on the Solvent‐induced Disproportionation of o‐Semiquinonato Complexes (2019)
  • Author(s): Shota Yamada Takeshi Matsumoto Ho-Chol Chang
  • Journal Title: Che. Eur. J. Volume: in press Pages: 8268-8278
  • DOI: 10.1002/chem.201900172
  • Peer Reviewed
• [Journal Article] Rh/Ce0.25Zr0.75O2Catalyst for Steam Reforming of Propane at Low Temperature (2019)
  • Author(s): Yu Lin、Sato Katsutoshi、Nagaoka Katsutoshi
  • Journal Title: ChemCatChem Volume: 11 Pages: 1472-1479
  • DOI: 10.1002/cctc.201801824
  • Peer Reviewed
• [Journal Article] Recyclable Rh-PVP nanoparticles catalyzed hydrogenation of benzoic acid derivatives and quinolines under solvent-free conditions (2019)
  • Author(s): Chaudhari Chandan、Imatome Hirotaka、Nishida Yoshihide、Sato Katsutoshi、Nagaoka Katsutoshi
  • Journal Title: Catalysis Communications Volume: 126 Pages: 55-60
  • DOI: 10.1016/j.catcom.2019.02.019
  • Peer Reviewed
• [Journal Article] Development and Application of New Iridium Catalysts for Efficient Dehydrogenative Reactions of Organic Molecules (2019)
  • Author(s): Fujita, K.
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 92 Issue: 2 Pages: 344-351
  • DOI: 10.1246/bcsj.20180301
  • NAID: 130007596693
  • ISSN: 0009-2673, 1348-0634
  • Peer Reviewed / Open Access
• [Journal Article] Convenient Method for the Production of Deuterium Gas Catalyzed by an Iridium Complex and Its Application to the Deuteration of Organic Compounds (2019)
  • Author(s): Enomoto, A.; Kajita, S.; Fujita, K.
  • Journal Title: Chem. Lett. Volume: 48 Issue: 2 Pages: 106-109
  • DOI: 10.1246/cl.180870
  • NAID: 130007590311
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed
• [Journal Article] Development of Efficient Methods for Organic Synthesis, Hydrogen Storage, and Hydrogen Production Based on Catalytic Dehydrogenation of Organic Molecules (2019)
  • Author(s): 藤田健一
  • Journal Title: J. Syn. Org. Chem., Jpn. Volume: 77 Issue: 2 Pages: 112-119
  • DOI: 10.5059/yukigoseikyokaishi.77.112
  • NAID: 130007592650
  • ISSN: 0037-9980, 1883-6526
  • Peer Reviewed
• [Journal Article] Hydrogen adsorption and absorption on a Pd-Ag alloy surface studied using in-situ X-ray photoelectron spectroscopy under ultrahigh vacuum and ambient pressure (2019)
  • Author(s): Tang Jiayi、Yamamoto Susumu、Koitaya Takanori、Yoshikura Yuki、Mukai Kozo、Yoshimoto Shinya、Matsuda Iwao、Yoshinobu Jun
  • Journal Title: Applied Surface Science Volume: 463 Pages: 1161-1167
  • DOI: 10.1016/j.apsusc.2018.07.078
  • Peer Reviewed
• [Journal Article] Tuning the Electron Acceptability of the [Mo6S8] Cluster Core by Decorating It with Methyl Groups on the Face-Bridging μ3-Sulfides (2018)
  • Author(s): Matsumoto Takeshi、Namiki Ryoya、Chang Ho-Chol
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2018 Pages: 3900-3904
  • DOI: 10.1002/ejic.201800587
  • Peer Reviewed
• [Journal Article] Direct Photochemical C-H Carboxylation of Aromatic Diamines with CO2 under Electron-Donor- and Base-free Conditions (2018)
  • Author(s): Matsumoto Takeshi、Uchijo Daiki、Koike Takuji、Namiki Ryoya、Chang Ho-Chol
  • Journal Title: Sci. Rep. Volume: 8 Pages: 1-10
  • DOI: 10.1038/s41598-018-33060-3
  • Peer Reviewed / Open Access
• [Journal Article] Ru/La0.5Pr0.5O1.75 Catalyst for Low-Temperature Ammonia Synthesis (2018)
  • Author(s): Ogura Yuta、Tsujimaru Kotoko、Sato Katsutoshi、Miyahara Shin-ichiro、Toriyama Takaaki、Yamamoto Tomokazu、Matsumura Syo、Nagaoka Katsutoshi
  • Journal Title: ACS Sustainable Chemistry & Engineering Volume: 6 Pages: 17258-17266
  • DOI: 10.1021/acssuschemeng.8b04683
  • Peer Reviewed
• [Journal Article] Influence of the Crystal Structure of Titanium Oxide on the Catalytic Activity of Rh/TiO2 in Steam Reforming of Propane at Low Temperature (2018)
  • Author(s): Yu Lin、Sato Katsutoshi、Toriyama Takaaki、Yamamoto Tomokazu、Matsumura Syo、Nagaoka Katsutoshi
  • Journal Title: Chemistry - A European Journal Volume: 24 Pages: 8742-8746
  • DOI: 10.1002/chem.201800936
  • Peer Reviewed
• [Journal Article] Selective Hydrogenation of Nitriles to Secondary Imines over Rh-PVP Catalyst under Mild Conditions (2018)
  • Author(s): Nishida Yoshihide、Chaudhari Chandan、Imatome Hirotaka、Sato Katsutoshi、Nagaoka Katsutoshi
  • Journal Title: Chem. Lett. Volume: 47 Issue: 7 Pages: 938-940
  • DOI: 10.1246/cl.180349
  • NAID: 130007402753
  • ISSN: 0366-7022, 1348-0715
  • Peer Reviewed
• [Journal Article] Photocatalytic chemoselective cleavage of C-O bonds under hydrogen gas- and acid-free conditions (2018)
  • Author(s): Kazuya Imamura， Hiroko Kato， Yuichiro Wada，b Kazuhiro Makabe， Ayumu Onda， Atsuhiro Tanaka， Hiroshi Kominami， Katsutoshi Satobd and Katsutoshi Nagaoka
  • Journal Title: Chemical Communications Volume: 54 Pages: 7298-7301
  • DOI: 10.1039/c8cc03362e
  • Peer Reviewed
• [Journal Article] H-D Exchange Mechanism of Butene on a D-Absorbed Pd-Au Alloy Surface (2018)
  • Author(s): Ogura Shohei、Ohno Satoshi、Mukai Kozo、Yoshinobu Jun、Fukutani Katsuyuki
  • Journal Title: The Journal of Physical Chemistry C Volume: 123 Pages: 7854-7860
  • DOI: 10.1021/acs.jpcc.8b06964
  • Peer Reviewed
• [Presentation] 高効率物質変換のための無機ナノ粒子触媒の創製 (2020)
  • Author(s): M. Yamauchi
  • Organizer: 日本物理学会 第75回年次大会（2020年）
  • Invited
• [Presentation] Hydrogenation of formate on the Pd-Cu single atom alloy model catalysts (2020)
  • Author(s): J. Yoshinobu
  • Organizer: 1st International Symposium “Hydrogenomics” combined with 14th International Symposium Hydrogen & Energy
• [Presentation] Double-4-Ring型分子性Si/Alクラスターの熱化学的性質 (2020)
  • Author(s): 橋本 賢弥
  • Organizer: 日本化学会 第100春季年会 (2020)
• [Presentation] 四座型テトラアミンを有するo-フェニレンジアミン/ベンゾキノジイミン錯体の合成 (2020)
  • Author(s): 高橋 良季
  • Organizer: 日本化学会 第100春季年会 (2020)
• [Presentation] 分子性Si/Al多核錯体をプリカーサーとしたアルミノシリケートの熱合成 (2020)
  • Author(s): 今泉 暁
  • Organizer: 日本化学会 第100春季年会 (2020)
• [Presentation] CO2を用いた芳香族アミン類の光カルボキシル化に対する置換基効果 (2020)
  • Author(s): 阿部 叶
  • Organizer: 日本化学会 第100春季年会 (2020)
• [Presentation] 有機配位子を利用した電子・プロトンプーリングと光化学エネルギー変換 (2020)
  • Author(s): 張 浩徹
  • Organizer: Symposium on Materials Chemistry for Sustainable Energy in Chuo University
• [Presentation] 「窒素分子活性化による三核クロムイミド錯体の合成と水素化反応」 (2020)
  • Author(s): 島 隆則
  • Organizer: 第100回日本化学会春季年会第100回日本化学会春季年会
  • Invited
• [Presentation] Dinitrogen Activation by Molecular Multimetallic Titanium Polyhydrides (2020)
  • Author(s): T. Shima
  • Organizer: International Symposium Hydrogenomics
  • Int'l Joint Research
• [Presentation] Nanomaterials to achieve electrochemical hydrogenation for efficient materials conversions (2019)
  • Author(s): M. Yamauchi
  • Organizer: 12th China-Japan Joint Symposium on Metal Cluster Compounds
  • Int'l Joint Research / Invited
• [Presentation] Inorganic Nanomaterials to Achieve Efficient Electrochemical Hydrogenation for Energy Storage and Materials Conversions (2019)
  • Author(s): M. Yamauchi
  • Organizer: 7th Asian Conference on Coordination Chemistry
  • Int'l Joint Research / Invited
• [Presentation] 水素化を介した無機ナノ粒子上での高効率エネルギー変換 (2019)
  • Author(s): 山内美穂
  • Organizer: 日本金属学会 2019年秋期講演大会
  • Invited
• [Presentation] Inorganic Nanocatalysts to Achieve Efficient Electrochemical Hydrogenation for Energy Storage and Materials Conversions (2019)
  • Author(s): M. Yamauchi
  • Organizer: ETA-ICAT joint symposium on catalysis
  • Int'l Joint Research / Invited
• [Presentation] Inorganic Nanocatalysts for Efficient Power Storage into liquid (2019)
  • Author(s): M. Yamauchi
  • Organizer: 2nd International Conference on Materials Science and Chemistry
  • Int'l Joint Research / Invited
• [Presentation] Pd蒸着Cuモデル触媒における水素吸着およびフォルメートの低温水素化 (2019)
  • Author(s): J. Yoshinobu
  • Organizer: 第125回触媒討論会
• [Presentation] Ptステップ表面におけるメタンの吸着と活性化 (2019)
  • Author(s): J. Yoshinobu
  • Organizer: 日本物理学会2019年秋季大会（物性）
• [Presentation] Adsorption, activation and reaction of inert molecules on model catalysts (2019)
  • Author(s): J. Yoshinobu
  • Organizer: 81st Okazaki Conference「Forefront of Measurement Technologies for Surface Chemistry and Physics in Real-Space, k-Space, and Real-Time」
  • Int'l Joint Research / Invited
• [Presentation] New Challenges in the Molecular Functional Chemistry of Redox-active Ligands (2019)
  • Author(s): H.-C. Chang
  • Organizer: 12th China-Japan Joint Symposium on Metal Cluster Compounds
  • Int'l Joint Research / Invited
• [Presentation] Photochemical H2 Evolution and CO2 Fixation Using an ortho-Phenylenediamine Fe(II) Complex (2019)
  • Author(s): A. Nakada
  • Organizer: 7th Asian Conference on Coordination Chemistry
  • Int'l Joint Research / Invited
• [Presentation] New Challenges in the Molecular Functional Chemistry of Redox-active Ligands (2019)
  • Author(s): H.-C. Chang
  • Organizer: China-Japan Symposium of Functional Coordination Chemistry”
  • Int'l Joint Research / Invited
• [Presentation] Molecular lattice engineering for valence tautomerism (2019)
  • Author(s): H.-C. Chang
  • Organizer: 錯体化学会第６９回討論会
  • Invited
• [Presentation] 2-アミノフェノラート錯体によるメタノールの光脱水素化に対する軸配位子効果 (2019)
  • Author(s): 小池 翔太
  • Organizer: 錯体化学会第６９回討論会
• [Presentation] CO2 を用いた置換アニリンの選択的光カルボキシル (2019)
  • Author(s): 阿部 叶
  • Organizer: 錯体化学会第６９回討論会
• [Presentation] CO2 を用いた置換アニリンの選択的光カルボキシル (2019)
  • Author(s): 阿部 叶
  • Organizer: 2019年光化学討論会
• [Presentation] CO2 を用いた置換アニリンの選択的光カルボキシル (2019)
  • Author(s): 阿部 叶
  • Organizer: 第31回配位化合物の光化学討論会(2019)
• [Presentation] 分子性Si/Al多核錯体を用いたゼオライト骨格の構築築 (2019)
  • Author(s): 今泉 暁
  • Organizer: 錯体化学会第６９回討論会
• [Presentation] 分子性Si/Al多核錯体を用いたゼオライト骨格の構築築 (2019)
  • Author(s): 今泉 暁
  • Organizer: 第26回ゼオライト夏の学校
• [Presentation] 分子性Si/Al多核錯体を用いたゼオライト骨格の構築築 (2019)
  • Author(s): 今泉 暁
  • Organizer: 第２３回ケイ素化学協会シンポジウム
• [Presentation] 四座型テトラアミンを有するo-フェニレンジアミン/ベンゾキノジイミン錯体の合成 (2019)
  • Author(s): 高橋 良季
  • Organizer: 第９回CSJ化学フェスタ
• [Presentation] Dinitrogen Activation by a Trinuclear Chromium Hydride Complex (2019)
  • Author(s): T. Shima
  • Organizer: 錯体化学会第69回討論会
• [Presentation] Synthesis and reactivity of a titanium dinitrogen hydride complex with a rigid PNP ligation (2019)
  • Author(s): Z. Mo
  • Organizer: 錯体化学会第69回討論会
• [Presentation] Multinuclear hydride clusters: Activation and transformation of small molecules (2019)
  • Author(s): T. Shima
  • Organizer: International Symposium Hydrogenomics
  • Int'l Joint Research / Invited
• [Presentation] 多金属ヒドリドによる新規物質変換反応 (2019)
  • Author(s): 島 隆則
  • Organizer: 第13回物性科学領域横断研究会
• [Presentation] 多金属ヒドリドクラスターによる 小分子の活性化と物質変換反応の開発 (2019)
  • Author(s): 島隆則
  • Organizer: 日本化学会春季年会
  • Invited
• [Presentation] o-アミノフェノラート3d金属錯体が示すメタノールの光脱水素化における補助配位子効果 (2019)
  • Author(s): 小池 翔太
  • Organizer: 日本化学会第99春季年会
• [Presentation] 二置換芳香族アミン/アルコール/チオール類のCO2下における光化学反応 (2019)
  • Author(s): 阿部 叶
  • Organizer: 日本化学会第99春季年会
• [Presentation] 電子吸引基を有する新規o-フェニレンジアミンFe(II)錯体の合成と光反応性 (2019)
  • Author(s): 高橋 良季
  • Organizer: 日本化学会第99春季年会
• [Presentation] Tailored rare-earth oxide supported Ru catalysts for utilizing renewable energy (2019)
  • Author(s): K. Nagaoka
  • Organizer: Cardiff Catalysis Institute - Hokkiado ICAT Joint International Symposium on Catalysis
  • Int'l Joint Research / Invited
• [Presentation] エネルギーキャリアとしてのアンモニアを合成・分解するための特殊反応場の構築に関する基盤技術の創成 (2019)
  • Author(s): 永岡 勝俊
  • Organizer: 第158回HESS定例研究会 水素・エネルギーキャリアの製造・利用のための革新的基盤技術会
  • Invited
• [Presentation] イリジウム錯体の触媒的脱水素化機能を活用する水素製造・貯蔵法の開発 (2019)
  • Author(s): 藤田健一
  • Organizer: 日本化学会第99春季年会
  • Invited
• [Presentation] イリジウム錯体と金属酸化物の複合による再利用可能な脱水素化用触媒の開発 (2019)
  • Author(s): 空田大地郎, 和田健司, 馮旗, 西岡正明, 藤田健一
  • Organizer: 日本化学会第99春季年会
• [Presentation] 電子的ならびに立体的特性の異なるシクロペンタジエニル配位子を持つイリジウム錯体の合成とその触媒性能 (2019)
  • Author(s): 丁在瑛, 新林卓也, 藤田健一
  • Organizer: 日本化学会第99春季年会
• [Presentation] イリジウム触媒による1,4-ブタンジオールの脱水素的ラクトン化とその逆反応 (2019)
  • Author(s): 藤田健一, 小野田光貴, 永野祐大
  • Organizer: 日本化学会第99春季年会
• [Presentation] Inorganic nanocatalysts for efficient power storage into liquid (2019)
  • Author(s): M, Yamauchi
  • Organizer: "2nd International Conference on Materials Chemistry "
  • Int'l Joint Research / Invited
• [Presentation] Molecular Multimetallic Polyhydrides: Activation and Functionalization of Dinitrogen and Aromatics (2018)
  • Author(s): Takanori Shima
  • Organizer: "I2CNER International Workshops 2018 (Kyusyu Univ.) "
  • Int'l Joint Research / Invited
• [Presentation] Redox-active Ligands as Photo-responsive Electron/Proton Poolers (2018)
  • Author(s): H.-C. Chang
  • Organizer: International Conference on Coordination Chemistry 2018
  • Int'l Joint Research / Invited
• [Presentation] o-フェニレンジアミン/o-ベンゾキノジイミン錯体の多電子・多プロトン移動反応 (2018)
  • Author(s): 秋澤 秀明
  • Organizer: 第68回錯体化学討論会
• [Presentation] レドックス活性錯体によるメタノールの光脱水素反応の制御 (2018)
  • Author(s): 小池 翔太
  • Organizer: 第68回錯体化学討論会
• [Presentation] Tailored catalysts for H2 storage and transportation (2018)
  • Author(s): K. Nagaoka
  • Organizer: Japan-Germany Joint Symposium on Advanced Catalysis Material and Characterization
  • Int'l Joint Research / Invited
• [Presentation] Design of rare earth oxide supported Ru catalysts for ammonia synthesis as hydrogen carrier (2018)
  • Author(s): K. Nagaoka
  • Organizer: 2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology
  • Int'l Joint Research / Invited
• [Presentation] Self-heating of Supported Ru Catalysts as a Trigger for Hydrogen Production by Ammonia Oxidative Decomposition from Room Temperature (2018)
  • Author(s): K. Nagaoka
  • Organizer: The 8th Tokyo Conference on Advanced Catalytic Science and Technology
  • Int'l Joint Research / Invited
• [Presentation] アンモニアを用いたエネルギーキャリア技術の創成 (2018)
  • Author(s): 永岡 勝俊
  • Organizer: 第50回化学工学会
  • Invited
• [Presentation] クリーンエネルギー社会の実現に向けて-アンモニア合成・分解触媒の開発 (2018)
  • Author(s): 永岡 勝俊
  • Organizer: 平成30年度触媒技術セミナー
  • Invited
• [Presentation] A Sustainable Method for the Synthesis of Acetic Acid Based on Dehydrogenation of an Ethanol-Water Solution Catalyzed by an Iridium Complex (2018)
  • Author(s): K. Fujita
  • Organizer: Catalysis and Fine Chemicals 2018
  • Int'l Joint Research / Invited
• [Presentation] Iridium Complex-Catalyzed Synthesis of Acetic Acid Based on Dehydrogenation of an Ethanol-Water Solution (2018)
  • Author(s): K. Fujita, M. Kuwahara, M. Nishioka, M. Yoshida
  • Organizer: 14th International KyotoConference on New Aspects of Organic Chemistry (IKCOC-14)
  • Int'l Joint Research
• [Presentation] 新規イリジウム錯体を用いた効率的な環境調和型新規酢酸合成法 (2018)
  • Author(s): 西岡正明, 桑原雅人, 吉田真人, 藤田健一
  • Organizer: 第38回有機合成若手セミナー
• [Presentation] A Sustainable Method for the Synthesis of Acetic Acid from Ethanol-Water Solution by Iridium-Catalyzed Dehydrogenation (2018)
  • Author(s): K. Fujita, M. Kuwahara, M.Nishioka, M. Yoshida
  • Organizer: JGP Chem & ChemEn International Workshop: Sustainability-Oriented Organic Synthesis
  • Int'l Joint Research
• [Presentation] 機能性ビピリドナート配位子を有するイリジウム錯体触媒を用いたエタノール水溶液の脱水素化による酢酸合成 (2018)
  • Author(s): 西岡正明, 桑原雅人, 吉田真人, 藤田健一
  • Organizer: 第8回CSJ化学フェスタ2018
• [Presentation] Convenient Method for the Generation of Deuterium Gas Catalyzed by an Iridium Complex (2018)
  • Author(s): A. Enomoto, S. Kajita, T. Shimbayashi, K. Fujita
  • Organizer: 14th International KyotoConference on New Aspects of Organic Chemistry (IKCOC-14)
  • Int'l Joint Research
• [Presentation] Inorganic Nanocatalysts for Efficient Power Storage into Liquid (2018)
  • Author(s): M. Yamauchi
  • Organizer: International Congress on Pure & Applied Chemistry Langkawi, (ICPAC Langkawi)
  • Int'l Joint Research / Invited
• [Presentation] Inorganic Nanocatalysts for Efficient Power Storage into liquid (2018)
  • Author(s): M. Yamauchi
  • Organizer: 2018 International Symposium on Advancement and Prospect of Catalysis Science & Technology
  • Int'l Joint Research / Invited
• [Presentation] Structure Controlled Inorganic Nanoparticles for Efficient Energy & Material Conversion (2018)
  • Author(s): M. Yamauchi
  • Organizer: Themec'2018 International Conference on Processing & Manufacturing of Advanced Materials
  • Int'l Joint Research / Invited
• [Presentation] Structure Controlled Inorganic Nanomaterials for Efficient Energy & Materials Conversion (2018)
  • Author(s): M. Yamauchi
  • Organizer: Japan-Germany Joint Symposium on Advanced Catalytic Materials and Characterization
  • Int'l Joint Research / Invited
• [Presentation] Gas exposure effects on monolayer pentacene FET studied by using non-invasive GaIn probes (2018)
  • Author(s): Jun Yoshinobu
  • Organizer: 9th Workshop on Advanced Spectroscopy of Organic Materials for Electronic Applications
  • Int'l Joint Research / Invited
• [Book] 月刊「ケミカルエネジニアリング」 (2020)
  • Author(s): 福嶋 貴, 北野 翔, 山内 美穂
  • Total Pages: 4
  • Publisher: 化学工業社
• [Book] 月刊「化学」 (2020)
  • Author(s): 福嶋 貴, 山内 美穂
  • Total Pages: 4
  • Publisher: 化学同人
• [Book] 月刊「ケミカルエネジニアリング」 (2019)
  • Author(s): 福嶋 貴, 北野 翔, 山内 美穂
  • Total Pages: 6
  • Publisher: 化学工業社
• [Book] 錯体化合物辞典 (2019)
  • Author(s): 島隆則
  • Total Pages: 1
  • Publisher: 朝倉書店
• [Book] e-J. Surf. Sci. Nanotechnol. (2019)
  • Author(s): T. Koitaya, S. Yamamoto, I. Matsuda and J. Yoshinobu
  • Total Pages: 9
  • Publisher: The Japan Society of Vacuum and Surface Science