Construction of avalanche photochromic system

• Project Area: New Horizons of Photochromism: Customized Molecular Design and Novel Applications
• Project/Area Number: 19050009
• Research Category: Grant-in-Aid for Scientific Research on Priority Areas
• Allocation Type: Single-year Grants
• Review Section: Science and Engineering
• Research Institution: Kyoto University (2008-2010); Kyushu University (2007)
• Principal Investigator: MATSUDA Kenji Kyoto University, 大学院・工学研究科, 教授 (80262145)
• Co-Investigator(Kenkyū-buntansha): FUKAMINATO Tuyoshi 九州大学, 大学院・工学研究院, 助教 (80380583) ; HASEGAWA Jun-ya 京都大学, 大学院・工学研究科, 講師 (30322168) ; HIGASHIGUCHI Kenji 京都大学, 大学院・工学研究科, 助教 (90376583)
• Project Period (FY): 2007 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥36,800,000 (Direct Cost: ¥36,800,000); Fiscal Year 2010: ¥9,200,000 (Direct Cost: ¥9,200,000); Fiscal Year 2009: ¥9,200,000 (Direct Cost: ¥9,200,000); Fiscal Year 2008: ¥9,200,000 (Direct Cost: ¥9,200,000); Fiscal Year 2007: ¥9,200,000 (Direct Cost: ¥9,200,000)
• Keywords: ナノ材料 / 複合材料・物性 / 光物性 / 光スイッチ / 分子コンダクタンス / STM / 2次元相分離

Research Abstract

A diarylethene-pyrene-diarylethene triad were synthesized to investigate the photoinduced two-dimensional ordering change at a solution-HOPG interface. A new ordering appeared upon irradiation with UV light and returned to the original ordering upon subsequent irradiation with visible light. The new arrangement was assigned to the ordering of the closed-closed isomers.

Research Products

• [Journal Article] Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the SolidState (2011)
  • Author(s): T.Hirose, K.Higashiguchi, K.Matsuda
  • Journal Title: Chem.Asian J. 6 Pages: 1057-1063
  • Peer Reviewed
• [Journal Article] π-Conjugation of Two Nitronyl Nitroxides-Attached Diarylethenes (2011)
  • Author(s): S.Yokojima, T.Kobayashi, K.Shinoda, K.Matsuda, K.Higashiguchi, S.Nakamura
  • Journal Title: J.Phys.Chem.B 115 Pages: 5685-5692
  • Peer Reviewed
• [Journal Article] π-Conjugation of Two Nitronyl Nitroxides-Attached Diarylethenes (2011)
  • Author(s): S.Yokojima, et al.
  • Journal Title: J.Phys.Chem.B Volume: 115(In press)
  • Peer Reviewed
• [Journal Article] Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the Solid State (2011)
  • Author(s): T.Hirose, et al.
  • Journal Title: Chem.Asian J. Volume: 6 Pages: 1057-1063
  • Peer Reviewed
• [Journal Article] Theoretical Investigation on the Origin of the CD Signal Reversal for the Closed-ring Isomer of Diarylethene with Peripherical π-Conjugated Substituents (2010)
  • Author(s): T.Hirose, J.-y.Hasegawa, K.Matsuda
  • Journal Title: Chem.Lett. 39 Pages: 516-517
  • NAID: 10027180759
  • Peer Reviewed
• [Journal Article] Evaluation of the β Value of the Phenylene Unit by Probing Exchange Interaction between Two Nitroxides (2010)
  • Author(s): K.Higashiguchi, et al.
  • Journal Title: Org.Lett. Volume: 12 Pages: 5284-5286
  • Peer Reviewed
• [Journal Article] Theoretical Investigation on the Origin of the CD Signal Reversal for the Closed-ring Isomer of Diarylethene with Periphericalπ-Conjugated Substituents (2010)
  • Author(s): T.Hirose, et al.
  • Journal Title: Chem.Lett. 39 Pages: 516-517
  • Peer Reviewed
• [Journal Article] Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains : Core-Chain Ratio Dependence on Supramolecular Structures (2009)
  • Author(s): T.Hirose, M.Irie, K.Matsuda
  • Journal Title: Chem.Asian J. 4 Pages: 58-66
  • Peer Reviewed
• [Journal Article] The Photochromic and Self-Assembling Properties of Diarylethenes Having Chiral Amphiphilic Chains at the Reactive Carbon Atoms (2009)
  • Author(s): T.Hirose, M.Irie, K.Matsuda
  • Journal Title: New J.Chem. 33 Pages: 1332-1334
  • Peer Reviewed
• [Journal Article] Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission : Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment (2009)
  • Author(s): T.Hirose, K.Matsuda
  • Journal Title: Chem.Commun. Pages: 5832-5834
  • Peer Reviewed
• [Journal Article] Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission: Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment (2009)
  • Author(s): T. Hirose, K. Matsuda
  • Journal Title: Chem. Commun. 39 Pages: 5832-5834
  • Peer Reviewed
• [Journal Article] Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Core-Chain Ratio Dependence on Supramolecular Structures (2009)
  • Author(s): T. Hirose, M. Irie, K. Matsuda
  • Journal Title: Chem. Asian J. 4,(1) Pages: 58-66
  • Peer Reviewed
• [Journal Article] The Photochromic and Self-Assembling Properties of Diarylethenes Having Chiral Amphiphilic Chains at the Reactive Carbon Atoms (2009)
  • Author(s): T.Hirose, et al.
  • Journal Title: New J.Chem. 33 Pages: 1332-1334
  • Peer Reviewed
• [Journal Article] Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission : Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment (2009)
  • Author(s): T.Hirose, et al.
  • Journal Title: Chem.Commun. 2009 Pages: 5832-5834
  • Peer Reviewed
• [Journal Article] Control of the Photoreactivity of Diarylethene Derivatives by Quaternarization of the Pyridylethynyl Group (2008)
  • Author(s): K.Yumoto, M.Irie, K.Matsuda
  • Journal Title: Org.Lett. 10 Pages: 2051-2054
  • Peer Reviewed
• [Journal Article] Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution-HOPG Interface (2008)
  • Author(s): R.Arai, S.Uemura, M.Irie, K.Matsuda
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 9371-9379
  • Peer Reviewed
• [Journal Article] Temperature-Light Dual Control of Clouding Behavior of an Oligo(ethyleneglycol)-Diarylethene Hybrid System (2008)
  • Author(s): T.Hirose, M.Irie, K.Matsuda
  • Journal Title: Adv.Mater. 20 Pages: 2137-2141
  • Peer Reviewed
• [Journal Article] Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution-HOPG Interface (2008)
  • Author(s): R. Arai, S. Uemura, M. Irie, K. Matsuda
  • Journal Title: J. Am. Chem. Soc. 130,(29) Pages: 9371-9379
  • Peer Reviewed
• [Journal Article] Control of the Photoreactivity of Diarylethene Derivative by Quaternarization of the Pyridylethynyl (2008)
  • Author(s): K. Yunioto, et.al.
  • Journal Title: Org. Lett 10 Pages: 2051-2054
  • Peer Reviewed
• [Journal Article] Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution-HOPG Interface (2008)
  • Author(s): R. Arai, et.al.
  • Journal Title: J. Am. Chem. Soc 130 Pages: 9371-9379
  • Peer Reviewed
• [Journal Article] Temperature-Light Dual Control of Clouding Behavior of an Oligo(ethylene glycol)-Diarylethene Hybrid System (2008)
  • Author(s): T. Hirose, et. al.
  • Journal Title: Adv. Mater. 20(In press)
  • Peer Reviewed
• [Journal Article] Photoswitching of Solvatochromism Using Diarylethenes with 2,5-Disubstituted3-Thienyl Unit (2007)
  • Author(s): N.Tanifuji, M.Irie, K.Matsuda
  • Journal Title: Chem.Lett. 36 Pages: 1232-1233
  • Peer Reviewed
• [Journal Article] Photoswitching of conductance of diarylethene-Aunanoparticlenetwork (2007)
  • Author(s): M., Ikeda, et. al.
  • Journal Title: Chem. Commun. Pages: 1355-1357
  • Peer Reviewed
• [Journal Article] Photoswitching of Solvatochromism Using Diarylethenes with 2,5-Disu bstituted 3-Thienyl Unit (2007)
  • Author(s): N., Tanifuji, et. al.
  • Journal Title: Chem. Lett. 36 Pages: 1232-1233
  • Peer Reviewed
• [Presentation] Self-Assembly and Photochromic Behavior of Diarylethenes Carrying Amphiphilic Side Chain (2010)
  • Author(s): K.Matsuda, T.Hirose
  • Organizer: 6th International Symposium on Organic Photochromism
  • Place of Presentation: Yokohama, Japan
  • Year and Date: 2010-10-19
• [Presentation] 4-フェニルピリジンを配位したテトラフェニルポルフィリンRh錯体のSTMによるコンダクタンス測定 (2010)
  • Author(s): 坂野豪
  • Organizer: 第21回基礎有機化学討論会
  • Place of Presentation: 名古屋市
  • Year and Date: 2010-09-10
• [Presentation] Photochromic Molecules for Switching Units (2009)
  • Author(s): K.Matsuda
  • Organizer: The 4th International Symposium on Atomic Technologies
  • Place of Presentation: Kobe, Japan
  • Year and Date: 2009-11-19
• [Presentation] Photoswitching of Diarylethene for Nanoscience (2009)
  • Author(s): K.Matsuda
  • Organizer: International Workshop on Organic Photoswitchable Multifunctional Materials
  • Place of Presentation: Shanghai, China
  • Year and Date: 2009-10-25
• [Presentation] 水溶液中における会合誘起増弓饒光特性を示す蛍光性色素の組織化と熱応答挙動 (2009)
  • Author(s): 廣瀬崇至
  • Organizer: 光化学討論会
  • Place of Presentation: 桐生市
  • Year and Date: 2009-09-16
• [Presentation] Assembly of Photochromic Molecules on Interface (2008)
  • Author(s): Kenji Matsuda
  • Organizer: JSPS-CNRS seminar "New Horizons of Photochromism"
  • Place of Presentation: Arras, France
  • Year and Date: 2008-10-13
• [Presentation] Photochromic Molecule as an Information Processing Unit in Molecular Optoelectronics (2007)
  • Author(s): K.Matsuda
  • Organizer: 2007Korea-Japan Symposium on Frontier Photoscience Gyeongju
  • Place of Presentation: Korea
  • Year and Date: 2007-11-25
• [Presentation] Photochiromic Diarylethene as an Information Processing Unit: Magnetic and Electric Switching (2007)
  • Author(s): K., Matsuda
  • Organizer: 12th International Symposium on Novel Aromatic Compounds
  • Place of Presentation: 淡路夢舞台国際会議場
• [Book] 有機半導体デバイス(「フォトクロミックメモリ」節) (2010)
  • Author(s): 松田建児
  • Total Pages: 5
  • Publisher: オーム社
• [Book] 水中で組織化する両親媒性ジアリールエテンによる光誘起超分子環境変化とLCST転移挙動 (2008)
  • Author(s): 廣瀬崇至、松田建児
  • Publisher: 光化学
• [Book] 光化学 39(2)(水中で組織化する両親媒性ジアリールエテンによる光誘起超分子環境変化とLCST転移挙動) (2008)
  • Author(s): 廣瀬崇至、松田建児
• [Book] フォトクロミックメモリ 有機半導体デバイス
  • Author(s): 松田建児
  • Publisher: オーム社