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Construction of avalanche photochromic system

Planned Research

Project AreaNew Horizons of Photochromism: Customized Molecular Design and Novel Applications
Project/Area Number 19050009
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyoto University (2008-2010)
Kyushu University (2007)

Principal Investigator

MATSUDA Kenji  Kyoto University, 大学院・工学研究科, 教授 (80262145)

Co-Investigator(Kenkyū-buntansha) FUKAMINATO Tuyoshi  九州大学, 大学院・工学研究院, 助教 (80380583)
HASEGAWA Jun-ya  京都大学, 大学院・工学研究科, 講師 (30322168)
HIGASHIGUCHI Kenji  京都大学, 大学院・工学研究科, 助教 (90376583)
Project Period (FY) 2007 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥36,800,000 (Direct Cost: ¥36,800,000)
Fiscal Year 2010: ¥9,200,000 (Direct Cost: ¥9,200,000)
Fiscal Year 2009: ¥9,200,000 (Direct Cost: ¥9,200,000)
Fiscal Year 2008: ¥9,200,000 (Direct Cost: ¥9,200,000)
Fiscal Year 2007: ¥9,200,000 (Direct Cost: ¥9,200,000)
Keywordsナノ材料 / 複合材料・物性 / 光物性 / 光スイッチ / 分子コンダクタンス / STM / 2次元相分離
Research Abstract

A diarylethene-pyrene-diarylethene triad were synthesized to investigate the photoinduced two-dimensional ordering change at a solution-HOPG interface. A new ordering appeared upon irradiation with UV light and returned to the original ordering upon subsequent irradiation with visible light. The new arrangement was assigned to the ordering of the closed-closed isomers.

Report

(6 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report   Self-evaluation Report ( PDF )
  • 2008 Annual Research Report
  • 2007 Annual Research Report

Research Products

(36 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (24 results) (of which Peer Reviewed: 24 results) Presentation (8 results) Book (4 results)

  • [Journal Article] Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the SolidState2011

    • Author(s)
      T.Hirose, K.Higashiguchi, K.Matsuda
    • Journal Title

      Chem.Asian J. 6

      Pages: 1057-1063

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] π-Conjugation of Two Nitronyl Nitroxides-Attached Diarylethenes2011

    • Author(s)
      S.Yokojima, T.Kobayashi, K.Shinoda, K.Matsuda, K.Higashiguchi, S.Nakamura
    • Journal Title

      J.Phys.Chem.B 115

      Pages: 5685-5692

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] π-Conjugation of Two Nitronyl Nitroxides-Attached Diarylethenes2011

    • Author(s)
      S.Yokojima, et al.
    • Journal Title

      J.Phys.Chem.B

      Volume: 115(In press)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly and Aggregate-Induced Enhanced Emission of Amphiphilic Fluorescence Dyes in Water and in the Solid State2011

    • Author(s)
      T.Hirose, et al.
    • Journal Title

      Chem.Asian J.

      Volume: 6 Pages: 1057-1063

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Investigation on the Origin of the CD Signal Reversal for the Closed-ring Isomer of Diarylethene with Peripherical π-Conjugated Substituents2010

    • Author(s)
      T.Hirose, J.-y.Hasegawa, K.Matsuda
    • Journal Title

      Chem.Lett. 39

      Pages: 516-517

    • NAID

      10027180759

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of the β Value of the Phenylene Unit by Probing Exchange Interaction between Two Nitroxides2010

    • Author(s)
      K.Higashiguchi, et al.
    • Journal Title

      Org.Lett.

      Volume: 12 Pages: 5284-5286

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Investigation on the Origin of the CD Signal Reversal for the Closed-ring Isomer of Diarylethene with Periphericalπ-Conjugated Substituents2010

    • Author(s)
      T.Hirose, et al.
    • Journal Title

      Chem.Lett. 39

      Pages: 516-517

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains : Core-Chain Ratio Dependence on Supramolecular Structures2009

    • Author(s)
      T.Hirose, M.Irie, K.Matsuda
    • Journal Title

      Chem.Asian J. 4

      Pages: 58-66

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] The Photochromic and Self-Assembling Properties of Diarylethenes Having Chiral Amphiphilic Chains at the Reactive Carbon Atoms2009

    • Author(s)
      T.Hirose, M.Irie, K.Matsuda
    • Journal Title

      New J.Chem. 33

      Pages: 1332-1334

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission : Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment2009

    • Author(s)
      T.Hirose, K.Matsuda
    • Journal Title

      Chem.Commun.

      Pages: 5832-5834

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission: Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment2009

    • Author(s)
      T. Hirose, K. Matsuda
    • Journal Title

      Chem. Commun. 39

      Pages: 5832-5834

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly of Photochromic Diarylethenes with Amphiphilic Side Chains: Core-Chain Ratio Dependence on Supramolecular Structures2009

    • Author(s)
      T. Hirose, M. Irie, K. Matsuda
    • Journal Title

      Chem. Asian J. 4,(1)

      Pages: 58-66

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] The Photochromic and Self-Assembling Properties of Diarylethenes Having Chiral Amphiphilic Chains at the Reactive Carbon Atoms2009

    • Author(s)
      T.Hirose, et al.
    • Journal Title

      New J.Chem. 33

      Pages: 1332-1334

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Assembly of Amphiphilic Fluorescent Dyes Showing Aggregate-Induced Enhanced Emission : Temperature Dependence of Molecular Alignment and Intermolecular Interaction in Aqueous Environment2009

    • Author(s)
      T.Hirose, et al.
    • Journal Title

      Chem.Commun. 2009

      Pages: 5832-5834

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of the Photoreactivity of Diarylethene Derivatives by Quaternarization of the Pyridylethynyl Group2008

    • Author(s)
      K.Yumoto, M.Irie, K.Matsuda
    • Journal Title

      Org.Lett. 10

      Pages: 2051-2054

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution-HOPG Interface2008

    • Author(s)
      R.Arai, S.Uemura, M.Irie, K.Matsuda
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 9371-9379

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-Light Dual Control of Clouding Behavior of an Oligo(ethyleneglycol)-Diarylethene Hybrid System2008

    • Author(s)
      T.Hirose, M.Irie, K.Matsuda
    • Journal Title

      Adv.Mater. 20

      Pages: 2137-2141

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution-HOPG Interface2008

    • Author(s)
      R. Arai, S. Uemura, M. Irie, K. Matsuda
    • Journal Title

      J. Am. Chem. Soc. 130,(29)

      Pages: 9371-9379

    • Related Report
      2009 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Control of the Photoreactivity of Diarylethene Derivative by Quaternarization of the Pyridylethynyl2008

    • Author(s)
      K. Yunioto, et.al.
    • Journal Title

      Org. Lett 10

      Pages: 2051-2054

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution-HOPG Interface2008

    • Author(s)
      R. Arai, et.al.
    • Journal Title

      J. Am. Chem. Soc 130

      Pages: 9371-9379

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Temperature-Light Dual Control of Clouding Behavior of an Oligo(ethylene glycol)-Diarylethene Hybrid System2008

    • Author(s)
      T. Hirose, et. al.
    • Journal Title

      Adv. Mater. 20(In press)

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoswitching of Solvatochromism Using Diarylethenes with 2,5-Disubstituted3-Thienyl Unit2007

    • Author(s)
      N.Tanifuji, M.Irie, K.Matsuda
    • Journal Title

      Chem.Lett. 36

      Pages: 1232-1233

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photoswitching of conductance of diarylethene-Aunanoparticlenetwork2007

    • Author(s)
      M., Ikeda, et. al.
    • Journal Title

      Chem. Commun.

      Pages: 1355-1357

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Photoswitching of Solvatochromism Using Diarylethenes with 2,5-Disu bstituted 3-Thienyl Unit2007

    • Author(s)
      N., Tanifuji, et. al.
    • Journal Title

      Chem. Lett. 36

      Pages: 1232-1233

    • Related Report
      2007 Annual Research Report
    • Peer Reviewed
  • [Presentation] Self-Assembly and Photochromic Behavior of Diarylethenes Carrying Amphiphilic Side Chain2010

    • Author(s)
      K.Matsuda, T.Hirose
    • Organizer
      6th International Symposium on Organic Photochromism
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2010-10-19
    • Related Report
      2010 Final Research Report
  • [Presentation] 4-フェニルピリジンを配位したテトラフェニルポルフィリンRh錯体のSTMによるコンダクタンス測定2010

    • Author(s)
      坂野豪
    • Organizer
      第21回基礎有機化学討論会
    • Place of Presentation
      名古屋市
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Photochromic Molecules for Switching Units2009

    • Author(s)
      K.Matsuda
    • Organizer
      The 4th International Symposium on Atomic Technologies
    • Place of Presentation
      Kobe, Japan
    • Year and Date
      2009-11-19
    • Related Report
      2010 Final Research Report
  • [Presentation] Photoswitching of Diarylethene for Nanoscience2009

    • Author(s)
      K.Matsuda
    • Organizer
      International Workshop on Organic Photoswitchable Multifunctional Materials
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2009-10-25
    • Related Report
      2010 Final Research Report 2009 Annual Research Report 2009 Self-evaluation Report
  • [Presentation] 水溶液中における会合誘起増弓饒光特性を示す蛍光性色素の組織化と熱応答挙動2009

    • Author(s)
      廣瀬崇至
    • Organizer
      光化学討論会
    • Place of Presentation
      桐生市
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] Assembly of Photochromic Molecules on Interface2008

    • Author(s)
      Kenji Matsuda
    • Organizer
      JSPS-CNRS seminar "New Horizons of Photochromism"
    • Place of Presentation
      Arras, France
    • Year and Date
      2008-10-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] Photochromic Molecule as an Information Processing Unit in Molecular Optoelectronics2007

    • Author(s)
      K.Matsuda
    • Organizer
      2007Korea-Japan Symposium on Frontier Photoscience Gyeongju
    • Place of Presentation
      Korea
    • Year and Date
      2007-11-25
    • Related Report
      2010 Final Research Report
  • [Presentation] Photochiromic Diarylethene as an Information Processing Unit: Magnetic and Electric Switching2007

    • Author(s)
      K., Matsuda
    • Organizer
      12th International Symposium on Novel Aromatic Compounds
    • Place of Presentation
      淡路夢舞台国際会議場
    • Related Report
      2007 Annual Research Report
  • [Book] 有機半導体デバイス(「フォトクロミックメモリ」節)2010

    • Author(s)
      松田建児
    • Total Pages
      5
    • Publisher
      オーム社
    • Related Report
      2010 Annual Research Report
  • [Book] 水中で組織化する両親媒性ジアリールエテンによる光誘起超分子環境変化とLCST転移挙動2008

    • Author(s)
      廣瀬崇至、松田建児
    • Publisher
      光化学
    • Related Report
      2010 Final Research Report
  • [Book] 光化学 39(2)(水中で組織化する両親媒性ジアリールエテンによる光誘起超分子環境変化とLCST転移挙動)2008

    • Author(s)
      廣瀬崇至、松田建児
    • Related Report
      2009 Self-evaluation Report
  • [Book] フォトクロミックメモリ 有機半導体デバイス

    • Author(s)
      松田建児
    • Publisher
      オーム社
    • Related Report
      2010 Final Research Report

URL: 

Published: 2007-03-31   Modified: 2018-03-28  

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