Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2017: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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Outline of Final Research Achievements |
Although some attempts to obtain optically active products have already been made using chiral compounds as solvents, examples exhibiting high enantioselectivities are still limited. In this study, we have tried to develop asymmetric reactions based on the chirality transfer from chiral solvents to the macromolecular backbones. Firstly, we have demonstrated that the induction of the single-handed conformation of polymer-based catalysts. Consequently, high enantioselectivities were observed in various catalytic reactions using the single-handed polymer-based catalysts.
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