| Project/Area Number |
16K17912
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer chemistry
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| Research Institution | Gunma University (2017)
Kanazawa University (2016) |
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Principal Investigator |
Ryohei Kakuchi 群馬大学, 大学院理工学府, 助教 (00743816)
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| Project Period (FY) |
2016-04-01 – 2018-03-31
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| Project Status |
Completed (Fiscal Year 2017)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2017: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2016: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 多成分連結反応 / 高分子反応 / 高分子合成 / 配列制御重合 / バイオリニューアブル |
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| Outline of Final Research Achievements |
In this work, the multi-component reactions (MCRs) were utilized for polymer synthesis in order to synthesize sequence-controlled polymers. For this, isocyanide-based MCRs such as the Passerini and the Ugi reactions were conducted with amino acid derived monomers, which enabled at least their oligomeriations. In addition, lignin-derived chemicals, such as vanillin and syringaldehyde, were successfully combined with MCR-based polymer synthesis. As a result, the successful Kabachnik-Fields three component reaction of the polymers featuring vanillin and syringaldehyde proceeded with a practically perfect consumption of the starting aldehydes, essentially affording polymeric α-amino phosphonates. These results should pave the way toward sequence-regulated constructions of polymers starting from bio-renewable compounds.
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