Synthesis of Hypervalent Organobromanes(III) and Their Synthetic Organic Reactions

• Project/Area Number: 20390005
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Chemical pharmacy
• Research Institution: The University of Tokushima
• Principal Investigator: OCHIAI Masahito The University of Tokushima, 大学院・ヘルスバイオサイエンス研究部, 教授 (50127065)
• Co-Investigator(Kenkyū-buntansha): MIYAMOTO Kazunori 徳島大学, 大学院・ヘルスバイオサイエンス研究部, 助教 (40403696)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000); Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000); Fiscal Year 2009: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000); Fiscal Year 2008: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
• Keywords: イリド / 臭素 / ヨウ素 / カルベン / ナイトレン / 超原子価 / アジリジン / 芳香族炭化水素 / ヨードベンゼン / オレフィン / シクロプロパン / C-H挿入反応 / ピリジニウム塩

Research Abstract

We have developed the following new chemistry of hypervalent organobromane (III).
(1) Thermal generation of singlet carbene (carbenoid) from hypervalent bromonium ylides.
(2) The first synthesis of hypervalent organo iminobromane(III).
(3) Development of new reactions using hypervalent iminobromane(III) as an organonitrenoid.

Research Products

• [Journal Article] Hypervalent phenyl-λ^3-iodane-mediated para-selective aromatic fluorination of 3-phenylpropyl ethers. (2011)
  • Author(s): M.Saito, K.Miyamoto, M.Ochiai
  • Journal Title: Chem.Commun. in press.
  • Peer Reviewed
• [Journal Article] Synthesis and Structure of Aliphatic Phenylchloronium Ylide. (2011)
  • Author(s): M.Ochiai, N.Tada, K.Miyamoto, M.Shiro
  • Journal Title: Heteroatom Chem. in press.
  • Peer Reviewed
• [Journal Article] Weakly Nucleophilic Conjugate Bases of Superacids as Powerful Nucleophiles in Vinylic Bimolecular Nucleophilic Substitutions of Simple β-Alkylvinyl-(aryl)-λ^3-bromanes. (2011)
  • Author(s): M.Ochiai, T.Okubo, K.Miyamoto
  • Journal Title: J.Am.Chem.Soc. in press.
  • Peer Reviewed
• [Journal Article] Highly Regioselective Amination of Unactivated Alkanes by Hypervalent Sulfonylimino-λ^3-Bromane. (2011)
  • Author(s): M.Ochiai, K.Miyamoto, T.Kaneaki, S.Hayashi, W.Nakanishi
  • Journal Title: Science in press.
  • Peer Reviewed
• [Journal Article] Effects of stereochemistry and β-substituents on the rates of vinylic S_N2 reaction of hypervalent vinyl(phenyl)-λ^3-iodanes with tetra-butylammonium halides. (2010)
  • Author(s): K.Miyamoto, T.Okubo, M.Hirobe, M.Kunishima, M.Ochiai
  • Journal Title: Tetrahedron 66 Pages: 5819-5826
  • Peer Reviewed
• [Journal Article] Hypervalent λ^3-Bromane Strategy for Baeyer-Villiger Oxidation : Selective Transformation of Primary Aliphatic and Aromatic Aldehydes to Formates, Which is Missing in the Classical Baeyer-Villiger Oxidation. (2010)
  • Author(s): M.Ochiai, A.Yoshimura, K.Miyamoto, S.Hayashi, W.Nakanishi
  • Journal Title: J.Am.Chem.Soc. 132 Pages: 9236-9239
  • Peer Reviewed
• [Journal Article] Imination of Sulfides and Sulfoxides with Sulfonylimino-λ^3-Bromane under Mild, Metal-Free Conditions. (2010)
  • Author(s): M.Ochiai, M.Naito, K.Miyamoto, S.Hayashi, W.Nakanishi
  • Journal Title: Chem.Eur.J. 16 Pages: 8713-8718
  • Peer Reviewed
• [Journal Article] Hypervalent N-sulfonylimino-λ^3-bromane : active nitrenoid species at ambient temperature under metal-free conditions. (2010)
  • Author(s): M.Ochiai, K.Miyamoto, S.Hayashi, W.Nakanishi
  • Journal Title: Chem.Commun. 46 Pages: 511-521
  • Peer Reviewed
• [Journal Article] 有機触媒による酸化的炭素-炭素二重結合切断反応 (2010)
  • Author(s): 宮本和範、落合正仁
  • Journal Title: 有機合成化学協会誌 68 Pages: 228-237
  • NAID: 10026868188
  • Peer Reviewed
• [Journal Article] Effects of stereochemistry and β-substituents on the rates of vinylic S_N2 reaction of hypervalent vinyl(phenyl)-λ^3-iodanes with tetrabutylammonium halides (2010)
  • Author(s): Miyamoto K, et al.
  • Journal Title: Tetrahedron Volume: 66 Pages: 5819-5826
  • Peer Reviewed
• [Journal Article] Hypervalent λ^3-Bromane Strategy for Baeyer-Villiger Oxidation : Selective Transformation of Primary Aliphatic and Aromatic Aldehydes to Formates, Which is Missing in the Classical Baeyer-Villiger Oxidation (2010)
  • Author(s): Ochiai M, et al.
  • Journal Title: J.Am.Chem.Soc. Volume: 132 Pages: 9236-9239
  • Peer Reviewed
• [Journal Article] Imination of Sulfides and Sulfoxides with Sulfonylimino-λ^3-Bromane under Mild, Metal-Free Conditions (2010)
  • Author(s): Ochiai M, et al.
  • Journal Title: Chem.Eur.J. Volume: 16 Pages: 8713-8718
  • Peer Reviewed
• [Journal Article] Hypervalent N-sulfonylimino-λ^3-bromane : active nitrenoid species at ambient temperature under metal-free conditions (2010)
  • Author(s): Ochiai M, et al.
  • Journal Title: Chem.Commun. Volume: 46 Pages: 511-521
  • Peer Reviewed
• [Journal Article] 有機触媒による酸化的炭素-炭素二重結合切断反応 (2010)
  • Author(s): 宮本和範, 他
  • Journal Title: 有機合成化学協会誌 Volume: 68 Pages: 228-237
  • NAID: 10026868188
  • Peer Reviewed
• [Journal Article] Direct Transfer of Sulfonylimino Group of Imino-λ^3-Bromane to N-Heterocycles and Trialkylamines : Synthesis of N-Iminoammonium Ylides under Metal-Free Conditions. (2009)
  • Author(s): M.Ochiai Y.Kawano, T.Kaneaki, N.Tada, K.Miyamoto
  • Journal Title: Org.Lett. 11 Pages: 281-284
  • Peer Reviewed
• [Journal Article] Imido transfer of sulfonylimino-λ^3-bromane makes possible the synthesis of sulfonylimino-λ^3-iodanes. (2009)
  • Author(s): M.Ochiai, A.Nakano, A.Yoshimura, K.Miyamoto, S.Hayashi,W.Nakanishi
  • Journal Title: Chem.Commun. Pages: 959-961
  • Peer Reviewed
• [Journal Article] Iodomesitylene-Catalyzed Oxidative Cleavage of Carbon-Carbon Double and Triple Bonds Using m-Chloroperbenzoic Acid as a Terminal Oxidant. (2009)
  • Author(s): K.Miyamoto, Y.Sei, K.Yamaguchi, M.Ochiai
  • Journal Title: J.Am.Chem.Soc. 131 Pages: 1382-1383
  • Peer Reviewed
• [Journal Article] Difluoro-λ^3-bromane-Induced Hofmann Rearrangement of Sulfonamides : Synthesis of Sulfamoyl Fluorides. (2009)
  • Author(s): M.Ohiai, T.Okada, N.Tada, A.Yoshimura, K.Miyamoto, M.Shiro
  • Journal Title: J.Am.Chem.Soc. 131 Pages: 8392-8393
  • Peer Reviewed
• [Journal Article] Oxidation of Benzyl Alcohols with Difluoro(aryl)-λ^3-bromane : Formation of Benzyl Fluoromethyl Ethers via Oxidative Rearrangement. (2009)
  • Author(s): M.Ohiai, A.Yoshimura, K.Miyamoto
  • Journal Title: Tetrahedron Lett. 50 Pages: 4792-4795
  • Peer Reviewed
• [Journal Article] Facile Generation of a Strained Cyclic Vinyl Cation by Thermal Solvolysis of Cyclopent-1-enyl-λ^3-bromanes. (2009)
  • Author(s): K.Miyamoto, M.Shiro, M.Ohiai
  • Journal Title: Angew.Chem.Int.Ed. 48 Pages: 8931-8934
  • Peer Reviewed
• [Journal Article] Hypervalent Aryl, Alkynyl, and Alkenyl-λ^3-bromanes. (2009)
  • Author(s): 落合正仁
  • Journal Title: Synlett Pages: 159-173
  • Peer Reviewed
• [Journal Article] Hypervalent Halogans and Their Reactions in Organic Synthesis. (2009)
  • Author(s): 落合正仁
  • Journal Title: Yakugaku Zasshi 129 Pages: 321-334
  • NAID: 110007123172
  • Peer Reviewed
• [Journal Article] Difluoro-λ^3-bromane-Induced Hofmann Rearrangement of Sulfo namides : Synthesis of Sulfamoyl Fluorides (2009)
  • Author(s): Ochiai M, et al.
  • Journal Title: J.Am.Chem.Soc. 131 Pages: 8392-8393
  • Peer Reviewed
• [Journal Article] Oxidation of Benzyl Alcohols with Difluoro(aryl)-)-λ^3-bromane : Formation of Benzyl Fluoromethyl Ethers via Oxidative Rearrangement (2009)
  • Author(s): Ochiai M, et al.
  • Journal Title: Tetrahedron Lett. 50 Pages: 4792-4795
  • Peer Reviewed
• [Journal Article] Facile Generation of a Strained Cyclic Vinyl Cation by Thermal Solvolysis of Cyclopent-1-enyl-λ^3-bromanes (2009)
  • Author(s): Ochiai M, et al.
  • Journal Title: Angew.Chem.Int.Ed. 48 Pages: 8931-8934
  • Peer Reviewed
• [Journal Article] Hypervalent Aryl, Alkynyl, and Alkenyl-λ^3-bromanes (2009)
  • Author(s): Ochiai M, et al.
  • Journal Title: Synlett Pages: 159-173
  • Peer Reviewed
• [Journal Article] Hypervalent N-sulfonylimino-λ^3-bromane : active nitrenoid species at ambient temperature under metal-free conditions (2009)
  • Author(s): Ochiai M, et al.
  • Journal Title: Chem.Commun. 46 Pages: 511-521
  • Peer Reviewed
• [Journal Article] 有機触媒による酸化的炭素-炭素二重結合切断反応 (2009)
  • Author(s): 落合正仁, 他
  • Journal Title: 有機合成化学協会誌 68 Pages: 228-237
  • NAID: 10026868188
  • Peer Reviewed
• [Journal Article] Direct Transfer of Sulfonylimino Group of Imino^-λ^<3->Bromane to N-Heterocycles and Trialkylamines : Synthesis of N-Iminoammnonium Ylides under Metal-Free Conditions (2009)
  • Author(s): Masahito Ochiai
  • Journal Title: Org. Lett. 11 Pages: 281-284
  • Peer Reviewed
• [Journal Article] Imido transfer of sulfonylimino^-λ^<3->bromane makes possible the synthesis of sulfonylimino^-λ^<3->iodanes (2009)
  • Author(s): Masahito Ochiai
  • Journal Title: Chem. Commun. Pages: 959-961
  • Peer Reviewed
• [Journal Article] Iodomesitylene Catalyzed Oxidative Cleavage of Carbon-Carbon Double and Triple Bonds Using m-Chloroperbenzoic Acid as a Terminal Oxidant (2009)
  • Author(s): Kazunori Miyamoto
  • Journal Title: J. Am. Chem. Soc. 131 Pages: 1382-1383
  • Peer Reviewed
• [Journal Article] Hypervalent Halogans and Their Reactions in Organic Synthesis (2009)
  • Author(s): Masahito Ochiai
  • Journal Title: Yakugaku Zasshi 129 Pages: 321-334
  • NAID: 110007123172
  • Peer Reviewed
• [Journal Article] Thermal and Catalytic Transylidations between Halonium Ylides and Synthesis and Reaction of Stable Aliphatic Chloronium Ylides. (2008)
  • Author(s): M.Ohiai, N.Tada, T.Okada, A.Sota, K.Miyamoto
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 2118-2119
  • Peer Reviewed
• [Journal Article] Rhodium(II)-Catalyzed Transylidation of Aryliodonium Ylides : Electronic Effects of Aryl Groups Determine Their Thermodynamic Stabilities. (2008)
  • Author(s): M.Ohiai, T.Okada, N.Tada, A.Yoshimura
  • Journal Title: Org.Lett. 10
  • Peer Reviewed
• [Journal Article] Difluoro-λ^3-Bromane-Induced Oxidative Carbon-Carbon Bond-Forming Reactions : Ethanol as an Electrophilic Partner and Alkynes as Nucleophiles. (2008)
  • Author(s): M.Ohiai, A.Yoshimura, T.Mori, Y.Nishi, M.Hirobe
  • Journal Title: J.Am.Chem.Soc. 130 Pages: 3742-3743
  • Peer Reviewed
• [Journal Article] Catalytic Version of and Reuse in Hypervalent Organo-λ^3- and λ^5-Iodane Oxidation. (2008)
  • Author(s): 落合正仁, 宮本和範
  • Journal Title: Eur.J.Org.Chem. Pages: 4229-4239
  • Peer Reviewed
• [Journal Article] Thermal and Catalytic Transylidations between Halonium Ylides and Synthesis and Reaction of stable Aliphatic Chloronium Ylides (2008)
  • Author(s): Masahito Ochiai
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 2118-2119
  • Peer Reviewed
• [Journal Article] Rhodium(II)-Catalyzed Transylidation of Aryliodonium Ylides : Electronic Effects of Aryl Groups Determine Their Thermodynamic Stabilities (2008)
  • Author(s): Masahito Ochiai
  • Journal Title: Org. Lett. 10 Pages: 1425-1428
  • Peer Reviewed
• [Journal Article] Difluoro^-λ^<3->Bromane-Induced Oxidative Carbon-Carbon Bond-Forming Reactions : Ethanol as an Electrophilic Partner and Alkynes as Nucleophiles (2008)
  • Author(s): Masahito Ochiai
  • Journal Title: J. Am. Chem. Soc. 130 Pages: 3742-3743
  • Peer Reviewed
• [Journal Article] Catalytic Version of and Reuse in Hypervalent Organo^-λ^<3->and λ^<5->Iodane Oxidation (2008)
  • Author(s): Masahito Ochiai
  • Journal Title: Eur. J. Org. Chem. Pages: 4229-4239
  • Peer Reviewed
• [Presentation] Aziridination of olefins with Sulfonamides and diacetoxybromane(III) (2011)
  • Author(s): Md.Mahbubul Hoque
  • Organizer: 日本薬学会第131年会
  • Place of Presentation: 静岡市
  • Year and Date: 2011-03-29
• [Presentation] ビストリフリルカルベンとオレフィンとの反応 (2011)
  • Author(s): 岩崎進
  • Organizer: 日本薬学会第131年会
  • Place of Presentation: 静岡市
  • Year and Date: 2011-03-29
• [Presentation] 超原子価イミノブロマンと芳香族化合物との反応 (2011)
  • Author(s): 齊藤基道
  • Organizer: 日本薬学会第131年会
  • Place of Presentation: 静岡市
  • Year and Date: 2011-03-29
• [Presentation] イミノブロマン(III)によるアルデヒドのアミド化反応 (2011)
  • Author(s): 高田真也
  • Organizer: 日本薬学会第131年会
  • Place of Presentation: 静岡市
  • Year and Date: 2011-03-29
• [Presentation] イミノブロマン(III)によるエーテルC-H挿入反応 (2011)
  • Author(s): 山根真一
  • Organizer: 日本薬学会第131年会
  • Place of Presentation: 静岡市
  • Year and Date: 2011-03-29
• [Presentation] 活性反応種フェニルカチオンの新しい発生法 (2011)
  • Author(s): 山下泰生
  • Organizer: 日本薬学会第131年会
  • Place of Presentation: 静岡市
  • Year and Date: 2011-03-29
• [Presentation] Synthesis of 2-Alkylviny1-λ^3-Bromanes and its Vinylic S_N2 Reaction with Conjugate Bases of Superacids (2010)
  • Author(s): Okubo Takuji
  • Organizer: The Second Decennial Meeting Between The University of Tokushima and Seoul National University on Pharmaceutical Sciences
  • Place of Presentation: Awaji
  • Year and Date: 2010-12-22
• [Presentation] Generation of ortho-(Trimethylsilyl)phenyl Cation (2010)
  • Author(s): Yamashita Hiroki
  • Organizer: The Second Decennial Meeting Between The University of Tokushima and Seoul National University on Pharmaceutical Sciences
  • Place of Presentation: Awaji
  • Year and Date: 2010-12-22
• [Presentation] Direct para-Selective Fluorination of Alkoxyalkylarenes with Activated Iodosylbenzene Monomer (2010)
  • Author(s): Saito Motomichi
  • Organizer: The Second Decennial Meeting Between The University of Tokushima and Seoul National University on Pharmaceutical Sciences
  • Place of Presentation: Awaji
  • Year and Date: 2010-12-22
• [Presentation] Metal Free C-H Amination of Ethers with Imino-λ^3-bromane (2010)
  • Author(s): Yamane Shinichi
  • Organizer: The Second Decennial Meeting Between The University of Tokushima and Seoul National University on Pharmaceutical Sciences
  • Place of Presentation: Awaji
  • Year and Date: 2010-12-22
• [Presentation] Generation of a Strained Cyclopent-1-enyl Cation by Thermal Solvolysis of Cyclopent-1-eny1-λ^3-bromanes (2010)
  • Author(s): Miyamoto Kazunori
  • Organizer: The Second Decennial Meeting Between The University of Tokushima and Seoul National University on Pharmaceutical Sciences
  • Place of Presentation: Awaji
  • Year and Date: 2010-12-22
• [Presentation] 超原子価シクロペンテニルブロマンの熱分解によるシクロペンテニルカチオンの生成 (2010)
  • Author(s): 宮本和範
  • Organizer: 2010臭素化学懇話会年会
  • Place of Presentation: 山口市
  • Year and Date: 2010-11-26
• [Presentation] ビニルブロマン(III)のS_N2反応:超強酸の共役塩基との反応 (2010)
  • Author(s): 大久保琢爾
  • Organizer: 第37回有機典型元素化学討論会
  • Place of Presentation: 室蘭市
  • Year and Date: 2010-11-25
• [Presentation] 高活性ヨードシルベンゼンによる芳香族化合物のパラ位選択的直接フッ素化反応 (2010)
  • Author(s): 齊藤基道
  • Organizer: 第13回ヨウ素学会シンポジウム
  • Place of Presentation: 千葉市
  • Year and Date: 2010-11-09
• [Presentation] イミノブロマン(III)を用いたアミノ基のエーテルα位C-H挿入反応 (2010)
  • Author(s): 山根真一
  • Organizer: 第49回日本薬学会中四国支部大会
  • Place of Presentation: 米子市
  • Year and Date: 2010-11-06
• [Presentation] Hypervalent Diacetoxybromane(III)-Mediated Aziridination of Olefins with Amides (2010)
  • Author(s): MD.Mahbubul Hoque
  • Organizer: 第49回日本薬学会中四国支部大会
  • Place of Presentation: 米子市
  • Year and Date: 2010-11-06
• [Presentation] 超原子価イミノブロマンを活用するアルデヒドの直接アミド化反応 (2010)
  • Author(s): 高田真也
  • Organizer: 第49回日本薬学会中四国支部大会
  • Place of Presentation: 米子市
  • Year and Date: 2010-11-06
• [Presentation] ブロモニウムイリドのオレフィン中での熱分解反応 (2010)
  • Author(s): 岩崎進
  • Organizer: 第49回日本薬学会中四国支部大会
  • Place of Presentation: 米子市
  • Year and Date: 2010-11-06
• [Presentation] Baeyer-Villiger酸化の新しい方法論:芳香族及び脂肪族一級アルデヒドの反応 (2010)
  • Author(s): 宮本和範
  • Organizer: 第36回反応と合成の進歩シンポジウム
  • Place of Presentation: 名古屋市
  • Year and Date: 2010-11-02
• [Presentation] ジフルオロ(アリール)-λ^3-ブロマンを活用する有機合成反応 (2010)
  • Author(s): 落合正仁
  • Organizer: 第34回フッ素化学討論会
  • Place of Presentation: 札幌市
  • Year and Date: 2010-10-18
• [Presentation] Chemistry of Hypervalent Organoiodane(III) and Bromane(III), ICHIC2010. (2010)
  • Author(s): 落合正仁
  • Organizer: 3rd International Conference on Hypervalent Iodine Chemistry
  • Place of Presentation: Bordeaux, France
  • Year and Date: 2010-07-05
• [Presentation] Chemistry of Hypervalent Organoiodane(III) and Bromane(III) (2010)
  • Author(s): Ochiai Masahito
  • Organizer: 3rd International Conference on Hypervalent Iodine Chemistry
  • Place of Presentation: Bordeaux, France
  • Year and Date: 2010-07-05
• [Presentation] Facile room temperature generation of a strained cyclopent-1-enyl cation by theymal solvolysis of cyclopent-1-enyl-λ^3-bromanes (2010)
  • Author(s): Miyamoto Kazunori
  • Organizer: 3rd International Conference on Hypervalent Iodine Chemistry
  • Place of Presentation: Bordeaux, France
  • Year and Date: 2010-07-05
• [Presentation] Vinylic S_N2 reaction of 2-alkylvinyl-λ^3-bromanes (2010)
  • Author(s): Okubo Takuji
  • Organizer: 3rd International Conference on Hypervalent Iodine Chemishy
  • Place of Presentation: Bordeaux, France
  • Year and Date: 2010-07-05
• [Presentation] Chemistry of Hypervalent Organoiodane(III) and Bromane(III) (2010)
  • Author(s): 落合正仁
  • Organizer: The 21st French-Japanese Symposium on Medicinal and Fine Chemistry
  • Place of Presentation: Kyoto City
  • Year and Date: 2010-05-10
• [Presentation] Catalytic and stoichiometric reactions of hypervalent organoiodanes(III) and bromanes(III) (2010)
  • Author(s): Ochiai Masahito
  • Organizer: The 21st French-Japanese Symposium on Medicinal and Fine Chemistry
  • Place of Presentation: Kyoto
  • Year and Date: 2010-05-10
• [Presentation] 低求核性アニオンによるビニルブロマンのビニル位S_N2反応 (2010)
  • Author(s): 大久保琢爾
  • Organizer: 日本薬学会第130年会
  • Place of Presentation: 岡山市
  • Year and Date: 2010-03-28
• [Presentation] イリドカルベノイドの脂肪族及び芳香族G-H挿入反応 (2010)
  • Author(s): 河野由布子
  • Organizer: 日本薬学会第130年会
  • Place of Presentation: 岡山市
  • Year and Date: 2010-03-28
• [Presentation] オルトトリメチルシリルフェニルカチオン (2010)
  • Author(s): 山下泰生
  • Organizer: 日本薬学会第130年会
  • Place of Presentation: 岡山市
  • Year and Date: 2010-03-28
• [Presentation] イミノブロマンを活用するエーテルα位の直接アミノ化反応 (2010)
  • Author(s): 山根真一
  • Organizer: 日本薬学会第130年会
  • Place of Presentation: 岡山市
  • Year and Date: 2010-03-28
• [Presentation] イミノブロマンによる芳香族化合物のC-Hアミノ化反応 (2010)
  • Author(s): 長谷川雄一
  • Organizer: 日本薬学会第130年会
  • Place of Presentation: 岡山市
  • Year and Date: 2010-03-28
• [Presentation] プロモニウムイリドを用いた一重項ビス(トリフリル)カルベンの熱的発生反応 (2010)
  • Author(s): 土井龍輔
  • Organizer: 日本薬学会第130年会
  • Place of Presentation: 岡山市
  • Year and Date: 2010-03-28
• [Presentation] Baeyer-Villiger酸化の新戦略:脂肪族一級アルデヒドの反応 (2009)
  • Author(s): 吉村祥
  • Organizer: 第36回有機典型元素化学討論会
  • Place of Presentation: 鳥取市
  • Year and Date: 2009-12-11
• [Presentation] ヨードベンゼンを有機触媒とする有機合成化学反応 (2009)
  • Author(s): 落合正仁
  • Organizer: 日本プロセス化学会2009ウィンターシンポジウム
  • Place of Presentation: 京都市
  • Year and Date: 2009-12-04
• [Presentation] 高反応性ナイトレノイドイミノブロマンの脂肪族C-Hアミノ基挿入反応 (2009)
  • Author(s): 宮本和範
  • Organizer: 第35回反応と合成の進歩シンポジウム
  • Place of Presentation: 金沢市
  • Year and Date: 2009-11-16
• [Presentation] The Last Baeyer-Villiger Oxidation (BVO) of Primary Aliphatic Aldehydes : Mechanistically Unique BVO (2009)
  • Author(s): Akira Yoshimura
  • Organizer: The 11th International Kyoto Conference on New Aspects of Organic Chemistry
  • Place of Presentation: Kyoto
  • Year and Date: 2009-11-10
• [Presentation] 超強酸の共役塩基によるオレフィン2分子求核置換反応 (2009)
  • Author(s): 大久保琢爾
  • Organizer: 第48回日本薬学会中四国支部大会
  • Place of Presentation: 徳島市
  • Year and Date: 2009-11-07
• [Presentation] 有機触媒ヨードベンゼンを活用するHofmann転位反応 (2009)
  • Author(s): 酒井祐太
  • Organizer: 第48回日本薬学会中四国支部大会
  • Place of Presentation: 徳島市
  • Year and Date: 2009-11-07
• [Presentation] プロモニウムイリドを用いた熱的カルベンC-H挿入反応 (2009)
  • Author(s): 河野由布子
  • Organizer: 第48回日本薬学会中四国支部大会
  • Place of Presentation: 徳島市
  • Year and Date: 2009-11-07
• [Presentation] ヨードベンゼンを触媒として使用する一級アミドのHofmann転位反応 (2009)
  • Author(s): 酒井祐太
  • Organizer: 第12回ヨウ素学会シンポジウム
  • Place of Presentation: 千葉市
  • Year and Date: 2009-10-29
• [Presentation] 有機触媒ヨードメシチレンを活用する炭素一炭素二重結合の酸化的切断反応 (2009)
  • Author(s): 宮本和範
  • Organizer: 第2回有機触媒シンポジウム
  • Place of Presentation: 京都市
  • Year and Date: 2009-09-25
• [Presentation] プロモニウムイリドによるC-H挿入反応 (2009)
  • Author(s): 河野由布子
  • Organizer: 第25回若手研究者のための化学道場
  • Place of Presentation: 松山市
  • Year and Date: 2009-09-07
• [Presentation] 超原子価プロマンによるBaeyer-Villiger酸化 (2009)
  • Author(s): 吉村祥
  • Organizer: 第25回若手研究者のための化学道場
  • Place of Presentation: 松山市
  • Year and Date: 2009-09-07
• [Presentation] イミノ-λ^3-プロマンを用いたスルフィド及びスルホキシドへのトランスイミノ化反応 (2009)
  • Author(s): 内藤将夫
  • Organizer: 第25回若手研究者のための化学道場
  • Place of Presentation: 松山市
  • Year and Date: 2009-09-07
• [Presentation] 超強酸の共役塩基を用いたビニル位S_N2反応 (2009)
  • Author(s): 大久保琢爾
  • Organizer: 第25回若手研究者のための化学道場
  • Place of Presentation: 松山市
  • Year and Date: 2009-09-07
• [Presentation] (E)-2-アルキルビニルブロマンのビニル位S_N2反応 (2009)
  • Author(s): 大久保琢爾
  • Organizer: 日本薬学会第129年会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-27
• [Presentation] イミノブロマンの反応 : 混ぜるだけで進行するアルカンC-Hアミノ化反応 (2009)
  • Author(s): 宮本和範
  • Organizer: 日本薬学会第129年会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-27
• [Presentation] ジフルオロブロマンによる脂肪族アルデヒドのBaeyer-Villiger酸化 (2009)
  • Author(s): 吉村祥
  • Organizer: 日本薬学会第129年会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-27
• [Presentation] ヨードベンゼンを用いたアミドの触媒的Hofmann転位反応 (2009)
  • Author(s): 酒井祐太
  • Organizer: 日本薬学会第129年会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-27
• [Presentation] イミノブロマンの反応 : スルフィド、スルホキシドへのイミノ基転位反応 (2009)
  • Author(s): 内藤将夫
  • Organizer: 日本薬学会第129年会
  • Place of Presentation: 京都
  • Year and Date: 2009-03-27
• [Presentation] Catalytic and stoichiometric reactions of hypervalent organoiodanes(III) and bromanes(III) (2009)
  • Author(s): 落合正仁
  • Organizer: 237th American Chemical Society National Meeting
  • Place of Presentation: Salt Lake City, UT
  • Year and Date: 2009-03-25
• [Presentation] Catalytic and stoichiometric reactions of hypervalent organoiodanes (III) and bromanes(III) (2009)
  • Author(s): Masahito Ochiai
  • Organizer: 237th American Chemical Society National Meeting
  • Place of Presentation: Salt Lake City, UT, USA
  • Year and Date: 2009-03-25
• [Presentation] イミノブロマンの反応特性 : 反応過程解析と遷移状態のAIM解析 (2008)
  • Author(s): 林聡子
  • Organizer: 第35回有機典型元素化学討論会
  • Place of Presentation: 八王子
  • Year and Date: 2008-12-11
• [Presentation] イミノブロマン(III)と活性メチレン化合物との反応 (2008)
  • Author(s): 中村友美
  • Organizer: 第47回日本薬学会中四国支部大会
  • Place of Presentation: 岡山
  • Year and Date: 2008-11-08
• [Presentation] ヨードメシチレンを用いた触媒的炭素一炭素二重結合及び三重結合切断反応 (2008)
  • Author(s): 宮本和範
  • Organizer: 第47回日本薬学会中一四国支部大会
  • Place of Presentation: 岡山
  • Year and Date: 2008-11-08
• [Presentation] ジフルオロブロマン(III)による酸化反応 (2008)
  • Author(s): 吉村祥
  • Organizer: 第47回日本薬学会中四国支部大会
  • Place of Presentation: 岡山
  • Year and Date: 2008-11-08
• [Presentation] 2-アルキニルビニルブロマン(III)の合成と構造 : ビニル位S_N2反応 (2008)
  • Author(s): 大久保琢爾
  • Organizer: 第47回日本薬学会中四国支部大会
  • Place of Presentation: 岡山
  • Year and Date: 2008-11-08
• [Presentation] ヨードメシチレンを用いた触媒的炭素一炭素多重結合切断反応 (2008)
  • Author(s): 宮本和範
  • Organizer: 第11回ヨウ素学会シンポジウム
  • Place of Presentation: 千葉
  • Year and Date: 2008-11-07
• [Presentation] イミノブロマンのトランスイミノ化反応 : イミノヨーダンの合成 (2008)
  • Author(s): 中野愛子
  • Organizer: 第34回反応と合成の進歩シンポジウム
  • Place of Presentation: 京都
  • Year and Date: 2008-11-04
• [Presentation] ゴールド(Z)-エンチオラートの立体選択的合成とその反応 (2008)
  • Author(s): 廣部雅也
  • Organizer: 第34回反応と合成の進歩シンポジウム
  • Place of Presentation: 京都
  • Year and Date: 2008-11-04
• [Presentation] 三価のブロマニル超脱離基を活用するシクロペンテニルカチオン発生反応 (2008)
  • Author(s): 宮本和範
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 吹田
  • Year and Date: 2008-10-04
• [Presentation] Iodomesitylene-Catalyzed Oxidative Cleavage of Carbon-Carbon Double Bond (2008)
  • Author(s): Masahito Ochiai
  • Organizer: 2nd EuCheMS Chemistry Congress
  • Place of Presentation: Torino, Italy
  • Year and Date: 2008-09-18
• [Presentation] 超原子価臭素によるアルコールやアルデヒドの酸化 (2008)
  • Author(s): 吉村祥
  • Organizer: 第24回若手化学者のための化学道場
  • Place of Presentation: 徳島
  • Year and Date: 2008-09-11
• [Presentation] ビニルブロマン(III)の合成とオレフィンS_N2反応 (2008)
  • Author(s): 大久保琢爾
  • Organizer: 第24回若手化学者のための化学道場
  • Place of Presentation: 徳島
  • Year and Date: 2008-09-11
• [Presentation] イミノヨーダンの合成 : イミノブロマンのトランスイ、ミノ化 (2008)
  • Author(s): 中野愛子
  • Organizer: 第24回若手化学者のための化学道場
  • Place of Presentation: 徳島
  • Year and Date: 2008-09-11
• [Presentation] イミノブロマンとスルフィド、スルホキシドとの反応 (2008)
  • Author(s): 内藤将夫
  • Organizer: 第24回若手化学者のための化学道場
  • Place of Presentation: 徳島
  • Year and Date: 2008-09-11
• [Presentation] ゴールド(Z)-エンチオラートの合成とその反応 (2008)
  • Author(s): 廣部雅也
  • Organizer: 第24回若手化学者のための化学道場
  • Place of Presentation: 徳島
  • Year and Date: 2008-09-11
• [Presentation] 超原子価臭素とヨウ素の化学 (2008)
  • Author(s): 落合正仁
  • Organizer: 第1回臭素化学懇話会
  • Place of Presentation: 松山市
  • Year and Date: 2008-09-05
• [Presentation] 超原子価臭素とヨウ素の化学 (2008)
  • Author(s): 落合正仁
  • Organizer: 第1回臭素化学懇話会
  • Place of Presentation: 松山
  • Year and Date: 2008-09-05
• [Presentation] Stereoselective Synthesis and Reaction of Gold (Z)-Enethiolates (2008)
  • Author(s): Masaya Hirobe
  • Organizer: 23rd International Symposium on the Organic Chemistry of Sulfur
  • Place of Presentation: Moscow, Russia
  • Year and Date: 2008-07-01
• [Presentation] 超原子価ハロゲン族化合物の合成とその特性を活用する有機合成反応の開発研究 (2008)
  • Author(s): 落合正仁
  • Organizer: 日本薬学会第128年会
  • Place of Presentation: 横浜市
  • Year and Date: 2008-03-26
• [Remarks] ホームページ等
  • URL: http://www.ph.tokushima-u.ac.jp/article/0015097.html
• [Remarks]
  • URL: http://www.ph.tokushima-u.ac.jp/article/0015097.html