Synthesis of Hypervalent Organobromanes(III) and Their Synthetic Organic Reactions
| Project/Area Number |
20390005
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemical pharmacy
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| Research Institution | The University of Tokushima |
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Principal Investigator |
OCHIAI Masahito The University of Tokushima, 大学院・ヘルスバイオサイエンス研究部, 教授 (50127065)
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| Co-Investigator(Kenkyū-buntansha) |
MIYAMOTO Kazunori 徳島大学, 大学院・ヘルスバイオサイエンス研究部, 助教 (40403696)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥19,760,000 (Direct Cost: ¥15,200,000、Indirect Cost: ¥4,560,000)
Fiscal Year 2010: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2009: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Fiscal Year 2008: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
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| Keywords | イリド / 臭素 / ヨウ素 / カルベン / ナイトレン / 超原子価 / アジリジン / 芳香族炭化水素 / ヨードベンゼン / オレフィン / シクロプロパン / C-H挿入反応 / ピリジニウム塩 |
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| Research Abstract |
We have developed the following new chemistry of hypervalent organobromane (III).
(1) Thermal generation of singlet carbene (carbenoid) from hypervalent bromonium ylides.
(2) The first synthesis of hypervalent organo iminobromane(III).
(3) Development of new reactions using hypervalent iminobromane(III) as an organonitrenoid.
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Report
(4 results)
Research Products
(113 results)
