| Budget Amount *help |
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2012: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2011: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
|---|
| Research Abstract |
Poly(quinoxaline.2,3.diyl)s bearing alkoxy side chains were developed and their helical screw.sense were successfully controlled to gain insight into the details of asymmetric helix induction for catalytic asymmetric synthesis.Poly(quinoxaline.2,3.diyl)s having reactive terminal groups were prepared and their screw.sense could be controlled by attaching small chiral molecules. Furthermore, we have established a quick and simple method for screening solvents for the efficient induction of a single.handed helical backbone by introducing pyrenyl groups on the side chains of poly(quinoxaline.2,3.diyl)s.
|
