| Budget Amount *help |
¥46,800,000 (Direct Cost: ¥36,000,000、Indirect Cost: ¥10,800,000)
Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Fiscal Year 2015: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2014: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2013: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
Fiscal Year 2012: ¥26,520,000 (Direct Cost: ¥20,400,000、Indirect Cost: ¥6,120,000)
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| Outline of Final Research Achievements |
By designing the ligand and cocatalyst, the redox features of the metal complexes as catalysts for precision radical polymerization were controlled to improve the polymerization catalytic activity as well as the tolerance to polar functional groups. In particular, we have developed active iron catalysts, robust iron catalysts, removable but active catalysts, and removable catalysts for controlled emulsion polymerization. These catalysts would lead to sustainable and environmentally benign systems for precision radical polymerization.
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