Synthesis and Properties of Novel Porphyrin Derivatives Containing Heteroatoms
| Project/Area Number |
24350023
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Nagoya University |
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Principal Investigator |
Shinokubo Hiroshi 名古屋大学, 工学(系)研究科(研究院), 教授 (50281100)
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| Project Period (FY) |
2012-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥18,460,000 (Direct Cost: ¥14,200,000、Indirect Cost: ¥4,260,000)
Fiscal Year 2015: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2014: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2013: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2012: ¥7,150,000 (Direct Cost: ¥5,500,000、Indirect Cost: ¥1,650,000)
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| Keywords | ポルフィリン / コロール / ヘテロ原子 / 金属錯体 / 近赤外色素 / π共役 / 芳香族 / 反芳香族 / ジアザポルフィリン / ケイ素 / リン / 白金 / ルテニウム / レニウム / ノルコロール / シリレン / 保護基 / パイ共役 / エチニル基 / π電子化合物 / 硫黄 / 芳香族性 / 反芳香族性 / クロスカップリング / C-H活性化 |
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| Outline of Final Research Achievements |
Porphyrin is a representative functional molecule. In this research project, we focused on the synthesis of novel heteroatom-containing porphyrin analogues through coupling of dipyrrin metal complexes. The metal-templated strategy using dipyrrin metal complexes was found to be quite efficient to construct porphyrin-like cyclic π-conjugated systems consisting of the dipyrrin units and heteroatoms, which exhibit intriguing optical and electronic properties.
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Report
(5 results)
Research Products
(89 results)
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[Journal Article] Near-IR Absorbing Nickel(II) Porphyrinoids Prepared by Regioselective Insertion of Silylenes into Antiaromatic Nickel(II) Norcorrole2014
Author(s)
Takaki Fukuoka, Kenya Uchida, Young Mo Sung, Ji-Young Shin, Shintaro Ishida, Dr. Jong Min Lim, Satoru Hiroto, Ko Furukawa, Dongho Kim, Takeaki Iwamoto, Hiroshi Shinokubo
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Journal Title
Angewandte Chemie, International Edition
Volume: 53
Issue: 6
Pages: 1506-1509
DOI
Related Report
Peer Reviewed / Acknowledgement Compliant
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