| Project/Area Number |
24655034
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| Research Category |
Grant-in-Aid for Challenging Exploratory Research
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| Allocation Type | Single-year Grants |
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| Research Field |
Organic chemistry
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| Research Institution | Nara Institute of Science and Technology |
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Principal Investigator |
YAMADA Hiroko 奈良先端科学技術大学院大学, 物質創成科学研究科, 教授 (20372724)
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| Co-Investigator(Kenkyū-buntansha) |
KUZUHARA Daiki 奈良先端科学技術大学院大学, 物質創成科学研究科, 助教 (00583717)
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| Project Period (FY) |
2012-04-01 – 2014-03-31
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| Project Status |
Completed (Fiscal Year 2013)
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| Budget Amount *help |
¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2012: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | トリフィリン / 錯体 / 芳香族 / ポルフィリノイド / 励起状態 / ポルフィリン / 核置換 / チオフェン / 金属錯体 / 白金 / X線結晶構造解析 |
|---|
| Research Abstract |
Pt(II), Fe(II) and B complexes of [14]triphyrin(2.1.1) were prepared. The stability and oxidative properties of Pt(II) complex was investigated. (Trip)(Cp)Fe(II) sandwich-type complex was also prepared. The reversible redox properties of the complex was investigated. The boron complex was also prepared. Thiatriphyrin was also prepared. Because of the steric hindrance between lone pairs of nitrogens, it is too unstable to be isolated and highly reactive with nucleophiles at meso-position. The dynamics of the singlet excited state of tiphyrin was also investigated.
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