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Vacuum electrochemical atomic force microscopy on ionic-liquid/electrode interfaces

Research Project

Project/Area Number 26286050
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Thin film/Surface and interfacial physical properties
Research InstitutionKyoto University

Principal Investigator

Ichii Takashi  京都大学, 工学(系)研究科(研究院), 准教授 (30447908)

Co-Investigator(Kenkyū-buntansha) 杉村 博之  京都大学, 工学(系)研究科(研究院), 教授 (10293656)
邑瀬 邦明  京都大学, 工学(系)研究科(研究院), 教授 (30283633)
Research Collaborator UTSUNOMIYA Toru  京都大学, 大学院工学研究科, 助教 (70734979)
KITTA Mitsunori  国立研究開発法人産業技術総合研究所, エネルギー・環境領域 電池技術研究部門, 研究員 (90586546)
UCHIDA Tatsunori  京都大学, 大学院工学研究科
TAKARA Yuuya  京都大学, 大学院工学研究科
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000)
Fiscal Year 2016: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2015: ¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2014: ¥6,110,000 (Direct Cost: ¥4,700,000、Indirect Cost: ¥1,410,000)
Keywords原子間力顕微鏡 / 走査プローブ顕微鏡 / 電気化学 / 固液界面 / イオン液体
Outline of Final Research Achievements

We investigated interfaces between ionic liquid (IL) and an electrode by vacuum electrochemical atomic force microscopy (vacuum EC-AFM). A lithium titanate, which is known as a negative electrode material for lithium ion battery, was used as a sample, and atomic resolution was successfully achieved in IL-based electrolyte.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (21 results)

All 2017 2016 2015 2014 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 2 results,  Open Access: 1 results) Presentation (17 results) (of which Int'l Joint Research: 5 results,  Invited: 6 results) Remarks (1 results)

  • [Journal Article] Two-step Sharpening Process for Silicon Probe in Quartz-based Atomic Force Microscopy Sensor2015

    • Author(s)
      Takashi Ichii, Nobumasa Tagai, Kohei Omori, Tatsunori Uchida, Toru Utsunomiya, Hiroyuki Sugimura
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 54 Issue: 9 Pages: 098005-098005

    • DOI

      10.7567/jjap.54.098005

    • NAID

      210000145696

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] True Molecular-resolution Imaging on Alkanethiol Self-assembled Monolayers in Ionic Liquids by Frequency Modulation Atomic Force Microscopy Utilizing a Quartz Tuning Fork Sensor2015

    • Author(s)
      Takashi Ichii, Yoshihisa Furutani, Masahiro Negami, Toru Utsunomiya, Kuniaki Murase, Hiroyuki Sugimura
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 4 Pages: 459-461

    • DOI

      10.1246/cl.141107

    • NAID

      130005062156

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Atomic-Resolution Imaging on Alkali Halide Surfaces in Viscous Ionic Liquid Using Frequency Modulation Atomic Force Microscopy2014

    • Author(s)
      Takashi Ichii, Masahiro Negami, Hiroyuki Sugimura
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 118 Issue: 46 Pages: 26803-26807

    • DOI

      10.1021/jp5078505

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Li+イオン挿入過程におけるLTO/イオン液体界面のFM-AFM構造解析2017

    • Author(s)
      寶雄也,橘田晃宜,一井崇,宇都宮徹,杉村博之
    • Organizer
      第64回応用物理学会春季学術講演会
    • Place of Presentation
      パシフィコ横浜
    • Year and Date
      2017-03-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] QPlus AFM for Investigation in Viscous Liquid2017

    • Author(s)
      Takashi Ichii
    • Organizer
      The 2nd International Symposium on "Recent Trends in Analysis Techniques for Functional Materials and Devices"
    • Place of Presentation
      Osaka University
    • Year and Date
      2017-01-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] イオン液体電解液中におけるチタン酸リチウム表面の原子スケールAFM構造分析2016

    • Author(s)
      一井 崇,内田 辰徳,橘田 晃宜,宇都宮 徹,杉村 博之
    • Organizer
      電気化学会第83回大会
    • Place of Presentation
      大阪大学
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高粘度イオン液体中での高分解能原子間力顕微鏡分析2016

    • Author(s)
      一井 崇
    • Organizer
      神戸大学統合研究拠点「次世代サブサーフェスイメージングシステム研究」プロジェクトスタートアップセミナー
    • Place of Presentation
      神戸大学
    • Year and Date
      2016-03-23
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] LTO表面のイオン液体中におけるFM-AFM構造解析2016

    • Author(s)
      寶雄也,内田辰徳,橘田晃宜,一井崇,宇都宮徹,杉村博之
    • Organizer
      平成28年度 鉄鋼プロセス研究会・材料化学研究会 第2回合同研究会
    • Place of Presentation
      大阪大学中之島センター
    • Related Report
      2016 Annual Research Report
  • [Presentation] Structural analysis of Li4Ti5O12(111) surfaces in ionic liquid by frequency modulation atomic force microscopy2015

    • Author(s)
      Tatsunori Uchida, Mitsunori Kitta, Takashi Ichii, Toru Utsunomiya, Hiroyuki Sugimura
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      Honolulu, Hawaii
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Atomic-resolution Imaging of a Spinel Li4Ti5O12(111) Surface in Ionic Liquid by FM-AFM2015

    • Author(s)
      Takashi Ichii, Tatsunori Uchida, Mitsunori Kitta, Toru Utsunomiya, Hiroyuki Sugimura
    • Organizer
      The 23rd International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      Niseko, Hokkaido, Japan
    • Year and Date
      2015-12-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Atomic-resolution Imaging of a Spinel Li4Ti5O12(111) Surface in Ionic Liquid by Frequency Modulation Atomic Force Microscopy2015

    • Author(s)
      Takashi Ichii, Tatsunori Uchida, Mitsunobu Kitta, Toru Utsunomiya, Hiroyuki Sugimura
    • Organizer
      The international symposium on “Recent Trends in Analysis Techniques for Functional Materials and Devices”
    • Place of Presentation
      Osaka University
    • Year and Date
      2015-12-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 周波数変調AFMによるLi塩添加イオン液体電解液/チタン酸リチウムLi4Ti5O12(111)界面の構造分析2015

    • Author(s)
      内田辰徳,橘田晃宜,一井崇,宇都宮徹,杉村博之
    • Organizer
      第6回イオン液体討論会
    • Place of Presentation
      同志社大学
    • Year and Date
      2015-10-26
    • Related Report
      2015 Annual Research Report
  • [Presentation] リチウム塩添加イオン液体電解液中におけるチタン酸リチウムLi4Ti5O12( 111)表面のFM–AFM構造解析2015

    • Author(s)
      内田 辰徳,橘田 晃宣,一井 崇,宇都宮 徹,杉村 博之
    • Organizer
      第76回応用物理学会秋季学術講演会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2015-09-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Atomic-resolution Imaging of a Spinel Li4Ti5O12(111) Surface in Ionic Liquid by FM-AFM2015

    • Author(s)
      Takashi Ichii, Tatsunori Uchida, Mitsunori Kitta, Toru Utsunomiya, Hiroyuki Sugimura
    • Organizer
      18th International conference on noncontact atomic force microscopy
    • Place of Presentation
      Cassis, France
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] チタン酸リチウムLi4Ti5O12(111)表面のイオン液体中FM–AFM観察2015

    • Author(s)
      内田 辰徳,橘田 晃宣,一井 崇,宇都宮 徹,杉村 博之
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] Si Probe Attached QPlus Sensor for Imaging in Liquid Environment2014

    • Author(s)
      T. Ichii, K. Omori, N. Tagai, T. Uchida, T. Utsunomiya and H. Sugimura
    • Organizer
      The 22nd International Colloquium on Scanning Probe Microscopy
    • Place of Presentation
      Atagawa, Japan
    • Year and Date
      2014-12-11 – 2014-12-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン液体中での高分解能原子間力顕微鏡観察2014

    • Author(s)
      一井 崇
    • Organizer
      日本顕微鏡学会第58回シンポジウム テーマ: ナノとマクロを繋ぐ顕微鏡学
    • Place of Presentation
      九州大学
    • Year and Date
      2014-11-16 – 2014-11-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] FM-AFMによるイオン液体–電極界面・イオン液体–アルカリハライド界面の構造解析2014

    • Author(s)
      一井 崇
    • Organizer
      日本学術振興会ナノプローブテクノロジー第167委員会 第76回研究会 「ナノスケール固液界面研究の最先端」
    • Place of Presentation
      キャンパスプラザ京都
    • Year and Date
      2014-10-23 – 2014-10-24
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] High-resolution Structural Analysis on Ionic-Liquid/Ionic-Crystal Interfaces by Frequency Modulation Atomic Force Microscopy2014

    • Author(s)
      Takashi Ichii, Masahiro Negami, Tatsunori Uchida, Hiroyuki Sugimura
    • Organizer
      30th European Conference on Surface Science
    • Place of Presentation
      Antalya, Turkey
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] イオン液体中における高分解能原子間力顕微鏡観察2014

    • Author(s)
      一井 崇
    • Organizer
      応用物理学会関西支部平成26年度第1回講演会 「プローブ顕微鏡と有機エレクトロニクス~関西若手研究者からの情報発信~」
    • Place of Presentation
      京都大学
    • Year and Date
      2014-06-26
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Remarks] 京都大学大学院工学研究科 材料工学専攻機能構築学分野HP

    • URL

      http://www.nsa.mtl.kyoto-u.ac.jp/

    • Related Report
      2016 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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