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Hydrogen magnetic refrigeration using new magnetic materials with multiple phase transition

Research Project

Project/Area Number 26420720
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeMulti-year Fund
Section一般
Research Field Structural/Functional materials
Research InstitutionKanazawa University

Principal Investigator

Matsumoto Koichi  金沢大学, 数物科学系, 教授 (10219496)

Co-Investigator(Kenkyū-buntansha) 沼澤 健則  国立研究開発法人物質・材料研究機構, 強磁場物性グループ, 主席研究員 (30354319)
阿部 聡  金沢大学, 数物科学系, 准教授 (60251914)
Co-Investigator(Renkei-kenkyūsha) ABE Satoshi  金沢大学, 数物科学系, 准教授 (60251914)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2016: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords磁気冷凍 / 磁気熱量効果 / 磁性 / 希土類 / 液体水素
Outline of Final Research Achievements

Magnetic refrigeration method makes use of the magnetocaloric effect (MCE) where some magnetic materials exhaust or absorb heat by applying or removing external magnetic fields. MCE is induced by the internal magnetic entropy change of magnetic material, thus magnetic refrigeration can operate an ideal cycle like Carnot.
In this research, we investigated new magnetic materials that will be useful for hydrogen magnetic refrigeration. It is possible to control temperature and magnetic field dependence of the MCE using magnetic materials with multiple transitions. Magnetic materials of intermetallic compounds such as (ErDy)NiAl, (Er,Dy)Al2, Er(Co,Ni)2, Er(Co,Cu)2 were synthesized. Magnetic and thermal properties of those compounds were measured in order to evaluated MCE. MCE results for oxides, sulfide that have rare-earth elements were also studied as useful materials

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report

Research Products

(18 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (1 results) Journal Article (10 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 9 results,  Acknowledgement Compliant: 3 results,  Open Access: 2 results) Presentation (6 results) (of which Int'l Joint Research: 4 results,  Invited: 1 results) Patent(Industrial Property Rights) (1 results)

  • [Int'l Joint Research] Kazan Federal University(ロシア連邦)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Thermal and magnetic properties of regenerator material Gd2O2S2017

    • Author(s)
      K Matsumoto, T Numazawa, Y Ura, T Ujiyama and S Abe
    • Journal Title

      Journal of Physics Conference Series

      Volume: 印刷中

    • NAID

      120006375097

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Magnetocaloric effect, thermal conductivity, and magnetostriction of epoxy-bonded La(Fe0.88Si0.12) 13 hydrides2017

    • Author(s)
      K Matsumoto, D Murayama, M Takeshita, Y Ura, S Abe, T Numazawa, H Takata, Y Matsumoto and T Kuriiwa
    • Journal Title

      Journal of Physics Conference Series

      Volume: 印刷中

    • NAID

      120006375096

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Large magnetocaloric effect in sintered ferromagnetic EuS2016

    • Author(s)
      Koichi Matsumoto, Liang Li, Shinji Hirai, Eiji Nakamura, Daiki Murayama, Yutaro Ura, Satoshi Abe
    • Journal Title

      Cryogenics

      Volume: 79 Pages: 45-48

    • DOI

      10.1016/j.cryogenics.2016.08.001

    • NAID

      120005851385

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Revised Measurements and Interpretation of Magnetic Properties of Oriented CeF3 Single Crystals2016

    • Author(s)
      A. V. Savinkov, S. L. Korableva1, M. S. Tagirov, H. Suzuki, K. Matsumoto, S. Abe
    • Journal Title

      Journal of Low Temperature Physics

      Volume: 185 Pages: 603-608

    • DOI

      10.1007/s10909-016-1639-0

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] 水素液化磁気冷凍システムの開発2016

    • Author(s)
      松本宏一,沼澤健則
    • Journal Title

      水素エネルギーシステム

      Volume: 41 Pages: 251-258

    • Related Report
      2016 Annual Research Report
  • [Journal Article] 水素液化磁気冷凍機の研究2015

    • Author(s)
      松本宏一,沼澤健則
    • Journal Title

      TEION KOGAKU(J. Cryo. Super. Soc. Jpn.)

      Volume: 50 Pages: 66-71

    • NAID

      130005062243

    • Related Report
      2015 Research-status Report
    • Peer Reviewed
  • [Journal Article] Nuclear Demagnetization for Ultra-low temperatures2014

    • Author(s)
      S. Abe and K. Matsumoto
    • Journal Title

      Cryogenics

      Volume: 未定 Pages: 213-220

    • DOI

      10.1016/j.cryogenics.2014.04.004

    • NAID

      120005516432

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Magnetic refrigerator for hydrogen liquefaction2014

    • Author(s)
      T. Numazawa, K. Kamiya, T. Utaki, K. Matsumoto
    • Journal Title

      Cryogenics

      Volume: 62 Pages: 185-192

    • DOI

      10.1016/j.cryogenics.2014.03.016

    • NAID

      130005062243

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Magnetocaloric materials and the optimization of cooling power density2014

    • Author(s)
      Patrick Wikus, Edgar Canavan, Sarah Trowbridge Heine, Koichi Matsumoto, Takenori Numazawa
    • Journal Title

      Cryogenics

      Volume: 62 Pages: 150-162

    • DOI

      10.1016/j.cryogenics.2014.04.005

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] Comparison of different regenerator geometries for AMR system2014

    • Author(s)
      Jing Li, T. Numazawa, K. Matsumoto Matsumoto, Y. Yanagisawa and H. Nakagome
    • Journal Title

      AIP Conference Proceedings

      Volume: 1573 Pages: 548-548

    • DOI

      10.1063/1.4860749

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Presentation] Thermal and magnetic properties of regenerator material Gd2O2S2016

    • Author(s)
      K Matsumoto, T Numazawa, Y Ura, T Ujiyama and S Abe
    • Organizer
      1st Asian ICMC
    • Place of Presentation
      金沢歌劇座(石川県、金沢市)
    • Year and Date
      2016-11-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Magnetocaloric effect, thermal conductivity, and magnetostriction of epoxy-bonded La(Fe0.88Si0.12) 13 hydrides2016

    • Author(s)
      K Matsumoto, D Murayama, M Takeshita, Y Ura, S Abe, T Numazawa, H Takata, Y Matsumoto and T Kuriiwa
    • Organizer
      1st Asian ICMC
    • Place of Presentation
      金沢歌劇座(石川県、金沢市)
    • Year and Date
      2016-11-07
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 磁気冷凍用磁性体の磁場中熱伝導率測定2016

    • Author(s)
      宇治山 崇, 裏 雄太郎, 村山 大樹, 阿部 聡, 松本 宏一
    • Organizer
      2016年度春期低温工学超電導学会
    • Place of Presentation
      タワーホール船堀(東京都、江戸川区)
    • Year and Date
      2016-05-30
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis of Valence-fluctuation Rare-earth Monosulfides and Their Specific Heat Characteristics at Very Low Temperatures2015

    • Author(s)
      L.Li, S.Hirai, K.Matsumoto, and E.Nakamura
    • Organizer
      2015 MRS Fall Meeting & Exhibition
    • Place of Presentation
      Boston, Massachusetts
    • Year and Date
      2015-11-29
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Status of development on magnetic refrigerator for hydrogen liquefaction2015

    • Author(s)
      Takenori Numazawa, Koji Kamiya and Koichi Matsumoto
    • Organizer
      International Workshop on Cooling-system for HTS Applications
    • Place of Presentation
      Matsue, Japan
    • Year and Date
      2015-11-14
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] Magnetic Refrigeration for Hydrogen Liquefaction2014

    • Author(s)
      Koichi Matsumoto, Takenori Numazawa
    • Organizer
      THERMAG VI
    • Place of Presentation
      Victoria, BC, CANADA
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
    • Invited
  • [Patent(Industrial Property Rights)] 多結晶ユーロピウム硫化物の焼結体、並びに該焼結体を用いた磁気冷凍材料及び蓄冷材2015

    • Inventor(s)
      平井伸治、中村英次、松本宏一、入江年雄、横山幸弘
    • Industrial Property Rights Holder
      平井伸治、中村英次、松本宏一、入江年雄、横山幸弘
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-11-27
    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2022-02-16  

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