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Creation of molecular technology for stimuli-responsive materials consisting of inorganic nanotube

Research Project

Project/Area Number 26870179
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Composite materials/Surface and interface engineering
Polymer/Textile materials
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

Shikinaka Kazuhiro  東京農工大学, 工学(系)研究科(研究院), 助教 (00507189)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2016: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywordsナノチューブ / ゲル / 刺激応答素材 / 異方性材料 / キラリティー / 電解質素材 / 電解質材料 / 刺激応答性素材 / 刺激応答性複合材料
Outline of Final Research Achievements

We achieved following sections for creation of novel stimuli-responsive materials consisting of inorganic nanotube "Imogolite (IG)".
(1) We controlled the physical properties of strong hydrogels consisting of IG and organic network polymer by changing chemical structure of organic network polymer. (2) The control of physical properties of thixotropic gels consisting of IG and difunctional organic acid (DA) was achieved. Furthermore, mechanism of emergence of thixotropy in the gel was revealed. The thixotropic electrolyte was also obtained by changing a solvent of IG thixotropic gel from water to ionic liquid. (3) An anisotropic strong hydrogel was obtained by emergence of oriented structure of IG and creation of interpenetrated polymer network.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Research-status Report
  • 2014 Research-status Report
  • Research Products

    (49 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (12 results) (of which Peer Reviewed: 11 results,  Acknowledgement Compliant: 10 results) Presentation (28 results) (of which Int'l Joint Research: 6 results,  Invited: 9 results) Book (1 results) Remarks (6 results)

  • [Int'l Joint Research] ESPCI ParisTech(France)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] ESPCI ParisTech(France)

    • Related Report
      2015 Research-status Report
  • [Journal Article] Quasi-solid electrolyte: a thixotropic gel of imogolite and an ionic liquid2017

    • Author(s)
      Kazuhiro Shikinaka, Natsumi Taki, Keisuke Kaneda. Yoichi Tominaga
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 3 Pages: 613-616

    • DOI

      10.1039/c6cc07765j

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chiral-Linkage-Induced Hierarchical Ordering of Colloidal Achiral Nanotubes in their Thixotropic Gel2016

    • Author(s)
      Kazuhiro Shikinaka, Hiroto Kikuchi, Tei Maki, Kiyotaka Shigehara, Hiroyasu Masunaga, and Hisako Sato
    • Journal Title

      Langmuir

      Volume: - Issue: 15 Pages: 3665-3669

    • DOI

      10.1021/acs.langmuir.6b00352

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Kinetics-dominated structure and stimuli-responsiveness in the assembly of colloidal nanotubes2016

    • Author(s)
      Kazuhiro Shikinaka, Saori Mori, Kiyotaka Shigehara, Hiroyasu Masunaga, Takamasa Sakai
    • Journal Title

      RSC Advances

      Volume: 6 Issue: 58 Pages: 52950-52956

    • DOI

      10.1039/c6ra12425a

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Design of stimuli-responsive materials consisting of rigid cylindrical inorganic polymer "imogolite"2016

    • Author(s)
      Kazuhiro Shikinaka
    • Journal Title

      Polymer Journal

      Volume: 48(6) Issue: 6 Pages: 689-696

    • DOI

      10.1038/pj.2016.12

    • NAID

      40020837279

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 低次元物質群による機能性材料の創製2016

    • Author(s)
      敷中一洋
    • Journal Title

      繊維学会誌

      Volume: 72(6) Pages: 304-304

    • NAID

      130005158284

    • Related Report
      2016 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Ordered Structurization of Imogolite Clay Nanotubes by the Spatiotemporal Regulation of their Assemblies2015

    • Author(s)
      Kazuhiro Shikinaka, Kiyotaka Shigehara
    • Journal Title

      Colloids and Surfaces A

      Volume: 482 Pages: 87-91

    • DOI

      10.1016/j.colsurfa.2015.04.029

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Robust Imogolite Hydrogels with Tunable Physical Properties2015

    • Author(s)
      Kazuhiro Shikinaka, Tomomi Yokoi, Yumi Koizumi-Fujii, Masaki Shimotsuya, Kiyotaka Shigehara
    • Journal Title

      RSC Advances

      Volume: 5 Issue: 58 Pages: 46493-46500

    • DOI

      10.1039/c5ra07437a

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Nanohybrid Film Consisted of Hydrophobized Imogolite and Various Aliphatic Polyesters2015

    • Author(s)
      Kazuhiro Shikinaka, Ayaki Abe, Kiyotaka Shigehara
    • Journal Title

      Polymer

      Volume: 68 Pages: 279-283

    • DOI

      10.1016/j.polymer.2015.05.039

    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] <i>Creation of Functional Materials Consisting Nano‐Fibrous Clay Mineral / Nano‐Particulate Woody Biomass</i>2015

    • Author(s)
      敷中一洋
    • Journal Title

      Sen'i Gakkaishi

      Volume: 71 Issue: 10 Pages: P-486-P-490

    • DOI

      10.2115/fiber.71.P-486

    • NAID

      130005102599

    • ISSN
      0037-9875, 1884-2259
    • Related Report
      2015 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Mechanical/Optical Behaviors of Imogolite Hydrogels Depending on their Compositions and Oriented Structures2015

    • Author(s)
      Kazuhiro Shikinaka, Yumi Koizumi, Kiyotaka Shigehara
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 132 Issue: 12

    • DOI

      10.1002/app.41691

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Flow-Orientation of Internal Structure and Anisotropic Properties on Hydrogels Consisted of Imogolite Hollow Nanofibers2014

    • Author(s)
      Keisuke Kaneda, Keisuke Uematsu, Hiroyasu Masunaga, Yoichi Tominaga, Kiyotaka Shigehara, Kazuhiro Shikinaka
    • Journal Title

      Sen'i Gakkaishi

      Volume: 70 Issue: 7 Pages: 137-144

    • DOI

      10.2115/fiber.70.137

    • NAID

      130004434608

    • ISSN
      0037-9875, 1884-2259
    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Reversible Viscosity Change of Nanotubular Colloidal Aqueous Suspensions Responding to an Electric Field2014

    • Author(s)
      Kazuhiro SHIKINAKA, Hiroshi KIMURA
    • Journal Title

      Colloids and Surfaces A: Physicochemical and Engineering Aspects

      Volume: 459 Pages: 1-3

    • DOI

      10.1016/j.colsurfa.2014.06.035

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] Smart Gel Consisting of Cylindrical Inorganic Polymer2017

    • Author(s)
      Kazuhiro Shikinaka
    • Organizer
      FiMPART 2017
    • Place of Presentation
      Bordeaux convention centre(Bordeaux, France)
    • Year and Date
      2017-07-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 剛直円筒状無機高分子による機能性素材の創製2017

    • Author(s)
      敷中一洋
    • Organizer
      第66回高分子学会年次大会
    • Place of Presentation
      幕張メッセ(千葉県千葉市美浜区)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 剛直円筒状無機高分子とイオン液体による刺激応答性ゲルの創製2016

    • Author(s)
      敷中一洋、滝夏摘、富永洋一
    • Organizer
      第27回ゲル研究討論会
    • Place of Presentation
      東京大学 (東京都文京区)
    • Year and Date
      2016-01-18
    • Related Report
      2015 Research-status Report
  • [Presentation] Functional Materials Consisted of Rigid Cylindrical Inorganic Polymer "Imogolite"2016

    • Author(s)
      Kazuhiro Shikinaka
    • Organizer
      The EMN meeting on Polymer (Polymer 2016)
    • Place of Presentation
      Eaton Hotel (Hong Kong)
    • Year and Date
      2016-01-12
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research / Invited
  • [Presentation] 剛直円筒状無機高分子とイオン液体による刺激応答性ゲルの創製2016

    • Author(s)
      敷中一洋、滝夏摘、富永洋一
    • Organizer
      平成28年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 剛直棒状無機高分子から成る機能性材料の創製2016

    • Author(s)
      敷中一洋
    • Organizer
      西日本ナノシート研究会サマーキャンプ2016
    • Place of Presentation
      シーサイドホテル屋久島(鹿児島県熊毛郡屋久島町)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 超分子キラリティー発現によるイモゴライトチクソトロピー性ゲルの高次秩序化2016

    • Author(s)
      敷中一洋・菊地洋人・増永啓康・牧偵・佐藤久子・重原淳孝
    • Organizer
      第60回粘土科学討論会
    • Place of Presentation
      九州大学(福岡県東区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Stimuli-Responsive Hydrogels Consisting of Cylindrical Inorganic Polymer2016

    • Author(s)
      Kazuhiro Shikinaka, Keisuke Kaneda, Tei Maki, Hiroyasu Masunaga, Yoshihito Osada, Kiyotaka Shigehara
    • Organizer
      The International Rubber Conference 2016
    • Place of Presentation
      北九州国際会議場(福岡県北九州市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 剛直円筒状無機高分子イモゴライトと有機酸による機能性ハイブリッドゲルの創製2016

    • Author(s)
      敷中一洋、金田恵介、増永啓康、富永洋一、重原淳孝
    • Organizer
      第35回無機高分子研究討論会
    • Place of Presentation
      東京理科大学森戸記念館(東京都新宿区)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 硬い円筒状粘土鉱物が作る柔らかな刺激応答性材料2016

    • Author(s)
      敷中一洋
    • Organizer
      第26回Clayteamセミナー
    • Place of Presentation
      産業技術総合研究所東北センター(宮城県仙台市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Stimuli-responsive materials consisting of cylindrical clay mineral “imogolite”2016

    • Author(s)
      Kazuhiro Shikinaka
    • Organizer
      The 2nd Japan-Taiwan Joint Workshop on Nanospace Materials
    • Place of Presentation
      NIMS(茨城県つくば市)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Stimuli-responsible gel consisted of rigid inorganic nanotube “imogolite”2015

    • Author(s)
      Kazuhiro Shikinaka, Keisuke Kaneda, Tei Maki, Hiroyasu Masunaga, Yoshihito Osada, Kiyotaka Shigehara
    • Organizer
      PACIFICHEM2015
    • Place of Presentation
      Hawaii Convention Center (USA)
    • Year and Date
      2015-12-18
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] 低次元物質群が織り成す機能性自己組織化材料2015

    • Author(s)
      敷中一洋
    • Organizer
      第30回中国四国地区高分子若手研究会
    • Place of Presentation
      道後温泉にぎたつ会館 (愛媛県松山市)
    • Year and Date
      2015-11-05
    • Related Report
      2015 Research-status Report
    • Invited
  • [Presentation] 剛直円筒状無機高分子イモゴライトと有機高分子による刺激応答性ゲルの力学/光学特性制御2015

    • Author(s)
      敷中一洋、横井友美、下津谷将樹、重原淳孝
    • Organizer
      第63回レオロジー討論会
    • Place of Presentation
      神戸大学 (兵庫県神戸市)
    • Year and Date
      2015-09-25
    • Related Report
      2015 Research-status Report
  • [Presentation] イモゴライトと二塩基酸から成るチクソトロピー性ゲル形成過程の速度論的考察2015

    • Author(s)
      敷中一洋、森佐織、重原淳孝、増永啓康
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学 (宮城県仙台市)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Research-status Report
  • [Presentation] イモゴライト水分散系の電気伝導性と電気粘性効果2015

    • Author(s)
      敷中一洋、富永洋一、木村浩
    • Organizer
      第59回粘土科学討論会
    • Place of Presentation
      山口大学 (山口県山口市)
    • Year and Date
      2015-09-04
    • Related Report
      2015 Research-status Report
  • [Presentation] Stimuli-Responsible Hydrogels Formed by Rigid Cylindrical Clay Mineral “Imogolite”2015

    • Author(s)
      Kazuhiro Shikinaka, Keisuke Kaneda, Tei Maki, Hiroyasu Masunaga, Yoshihito Osada, Kiyotaka Shigehara
    • Organizer
      EUROCLAY2015
    • Place of Presentation
      The Appleton Tower complex of the University of Edinburgh (Scotland)
    • Year and Date
      2015-07-10
    • Related Report
      2015 Research-status Report
    • Int'l Joint Research
  • [Presentation] イモゴライトとジカルボン酸によるヒドロゲルにおけるチクソトロピー性発現機構2015

    • Author(s)
      敷中一洋、森佐織、重原淳孝
    • Organizer
      平成27年繊維学会年次大会
    • Place of Presentation
      タワーホール船堀 (東京都江戸川区)
    • Year and Date
      2015-06-10
    • Related Report
      2015 Research-status Report
  • [Presentation] 二塩基酸への不斉導入によるイモゴライトチクソトロピー性ゲルの秩序構造化2015

    • Author(s)
      敷中一洋、菊地洋人、増永啓康、牧偵、重原淳孝
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター (北海道札幌市)
    • Year and Date
      2015-05-28
    • Related Report
      2015 Research-status Report
  • [Presentation] Thixotropic hydrogels consisted of rigid inorganic nanotube “Imogolite”2015

    • Author(s)
      Kazuhiro Shikinaka
    • Organizer
      BIT's 1st Annual World Congress of Smart Materials-2015 (WCSM-2015)
    • Place of Presentation
      Busan Exhibition & Convention Center, Busan
    • Year and Date
      2015-03-23 – 2015-03-25
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Stimuli-Responsible Hydrogels Consisted of Rigid Inorganic Nanotube “Imogolite” and Organic Acids2015

    • Author(s)
      Kazuhiro Shikinaka
    • Organizer
      2015 Symposium for the Promotion of Applied Research Collaboration in Asia (SPARCA 2015)
    • Place of Presentation
      Sunworld Dynasty Taipei Hotel, Taipei
    • Year and Date
      2015-02-08 – 2015-02-11
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] イモゴライト含有刺激応答性高強度ゲル2015

    • Author(s)
      敷中一洋、金田恵介、小泉由美、横井友美、重原淳孝
    • Organizer
      第26回ゲル研究討論会
    • Place of Presentation
      東京大学
    • Year and Date
      2015-01-19 – 2015-01-20
    • Related Report
      2014 Research-status Report
  • [Presentation] 剛直無機ナノチューブの自己組織化による機能性材料2014

    • Author(s)
      敷中一洋
    • Organizer
      西日本ナノシート研究会ワークショップ2014
    • Place of Presentation
      山口大学
    • Year and Date
      2014-12-12 – 2014-12-13
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Thixotropic Hydrogel Consisted of Rigid Rod-Like Polyelectrolyte2014

    • Author(s)
      Kazuhiro Shikinaka, Keisuke Kaneda, Saori Mori, Tei Maki, Hiroyasu Masunaga, Yoshihito Osada, Kiyotaka Shigehara
    • Organizer
      PN & G 2014
    • Place of Presentation
      東京大学
    • Year and Date
      2014-11-10 – 2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] イモゴライト網目から成るゲルにおけるチクソトロピー性と構造形成過程の関係2014

    • Author(s)
      敷中一洋、森佐織、金田恵介、重原淳孝、酒井崇匡、増永啓康
    • Organizer
      第62回レオロジー討論会
    • Place of Presentation
      福井市交流プラザ
    • Year and Date
      2014-10-15 – 2014-10-17
    • Related Report
      2014 Research-status Report
  • [Presentation] Robust hydrogel reinforced by an addition of imogolite which shows strain-induced reversible isotropic-anisotropic structural transition2014

    • Author(s)
      Kazuhiro Shikinaka, Tomomi Yokoi, Keisuke Kaneda, Yoshihito Osada, Hiroyasu Masunaga, Kiyotaka Shigehara
    • Organizer
      International Symposium on Fiber Science and Technology (ISF2014)
    • Place of Presentation
      東京ファッションタウンビル
    • Year and Date
      2014-09-28 – 2014-10-01
    • Related Report
      2014 Research-status Report
  • [Presentation] イモゴライト水分散液のエレクトロレオロジー効果2014

    • Author(s)
      敷中一洋、木村浩
    • Organizer
      第58回粘土科学討論会
    • Place of Presentation
      福島市A・O・Z
    • Year and Date
      2014-09-24 – 2014-09-27
    • Related Report
      2014 Research-status Report
  • [Presentation] 剛直棒状無機分子の架橋によるチクソトロピー性ハイドロゲルの創製2014

    • Author(s)
      敷中一洋、金田恵介、森佐織、牧禎、増永啓康、長田義仁、重原淳孝
    • Organizer
      レオロジー学会第41回年会
    • Place of Presentation
      東京大学
    • Year and Date
      2014-05-15 – 2014-05-16
    • Related Report
      2014 Research-status Report
  • [Book] Functionalization of Molecular Architectures: Advances and Applications on Low-dimensional Compounds2017

    • Author(s)
      1.Kazuhiro Shikinaka, Yoshiro Kaneko, Yoshiyuki Kuroda, Nobuyoshi Miyamoto
    • Publisher
      Pan Stanford Publishing Pte. Ltd.
    • Related Report
      2016 Annual Research Report
  • [Remarks] 自由成形が可能な電解質素材の開発に成功

    • URL

      http://www.tuat.ac.jp/outline/disclosure/pressrelease/2016/20161221_01.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] Polymer Journalにおける総説が2016年6月号の表紙として採用

    • URL

      http://www.nature.com/pj/journal/v48/n6/covers/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東京農工大学 教職員データベース

    • URL

      http://kenkyu-web.tuat.ac.jp/Profiles/29/0002822/profile.html

    • Related Report
      2015 Research-status Report
  • [Remarks] 研究者 (敷中一洋) 個人HP

    • URL

      http://kazuhiro-shikinaka.jimdo.com/

    • Related Report
      2015 Research-status Report
  • [Remarks] 敷中一洋助教が「平成26年度 繊維学会奨励賞」を受賞

    • URL

      http://www.tuat.ac.jp/news/20150611102035/index.html

    • Related Report
      2015 Research-status Report
  • [Remarks] 敷中一洋助教が「平成26年度高分子研究奨励賞」を受賞

    • URL

      http://www.tuat.ac.jp/news/20150525135145/index.html

    • Related Report
      2015 Research-status Report

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Published: 2014-04-04   Modified: 2018-03-22  

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