Re-establishments of Actinide Chemistry on basis of Phthalocyanine complexes : Application to nuclear medicine and Single molecular analysis.

2017 Fiscal Year Final Research Report

• Project/Area Number: 16K14533
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Nuclear engineering
• Research Institution: Tohoku University
• Principal Investigator: Yamamura Tomoo 東北大学, 金属材料研究所, 准教授 (20281983)
• Co-Investigator(Kenkyū-buntansha): 福田 貴光 大阪大学, 理学研究科, 准教授 (40344741) ; 大槻 勤 京都大学, 原子炉実験所, 教授 (50233193) ; 笠松 良崇 大阪大学, 理学研究科, 講師 (70435593) ; 白崎 謙次 東北大学, 金属材料研究所, 技術専門職員 (70447176) ; 鷲山 幸信 福島県立医科大学, 公私立大学の部局等, 准教授 (80313675)
• Project Period (FY): 2016-04-01 – 2018-03-31
• Keywords: フタロシアニン / アクチノイド / アルファ放射体核医薬

Outline of Final Research Achievements

UPc2 complexes were successfully prepared by using the newly-developed heating-block method. Phthalocyanine complexes were successfully purified and its single crystals were obtained by sublimation process. Also, single crystals of [UPc]+ were prepared by electrolysis and the purified complex of superphthalocyanine UO2SPc were prepared. These sublimation transferring method process were developed for samples for AFM. All the processes were designed to be dealt in the glove-box for alpha-emitters.

Free Research Field

アクチノイド化学