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2012 Fiscal Year Final Research Report

Synthesis of Fuels and Chemicals by Catalytic Conversion of inedible Biomass

Research Project

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Project/Area Number 20226016
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Catalyst/Resource chemical process
Research InstitutionHokkaido University

Principal Investigator

FUKUOKA Atsushi  北海道大学, 触媒化学研究センター, 教授 (80189927)

Co-Investigator(Kenkyū-buntansha) KOBAYASHI Hirokazu  北海道大学, 触媒化学研究センター, 助教 (30545968)
Co-Investigator(Renkei-kenkyūsha) HARA Kenji  北海道大学, 触媒化学研究センター, 准教授 (10333593)
KOBAYASHI Hirokazu  北海道大学, 触媒化学研究センター, 助教 (30545968)
Project Period (FY) 2008 – 2012
Keywordsバイオマス / 地球温暖化ガス排出削減 / 再生可能エネルギー / 環境技術 / 触媒化学プロセス / セルロース / 加水分解 / 活性炭
Research Abstract

As countermeasures against decrease of oil resources and global warming, it is widely desired to synthesize fuel and chemicals from renewable biomass. In this work, we have developed new catalysts and catalytic reactions to effectively utilize lignocellulose consisting of cellulose, hemicellulose and lignin that are abundant and inedible biomass. We have also clarified the structure of catalytic active sites and the reaction mechanism for biomass conversion.

  • Research Products

    (34 results)

All 2013 2012 2011 2010 2009 2008 Other

All Journal Article (15 results) (of which Peer Reviewed: 15 results) Presentation (7 results) Book (6 results) Remarks (1 results) Patent(Industrial Property Rights) (5 results) (of which Overseas: 1 results)

  • [Journal Article] High-Yielding One-Pot Synthesis of Glucose from Cellulose Using Simple Activated Carbons and Trace Hydrochloric Acid2013

    • Author(s)
      H. Kobayashi, M. Yabushita, T.Komanoya, K. Hara, I. Fujita, A. Fukuoka
    • Journal Title

      ACS Catalysis

      Volume: 3 Pages: 581-587

    • DOI

      doi:10.1021/cs300845f

    • Peer Reviewed
  • [Journal Article] Phase-change of nickel phosphide catalysts in the conversion of cellulose into sorbitol2012

    • Author(s)
      P. Yang, H. Kobayashi, K. Hara, A. Fukuoka
    • Journal Title

      ChemSusChem

      Volume: 5 Pages: 920-926

    • DOI

      doi:10.1002/cssc.201100498

    • Peer Reviewed
  • [Journal Article] Conversion of lignocellulose into renewable chemicals by heterogeneous catalysis2012

    • Author(s)
      H. Kobayashi, H. Ohta, A. Fukuoka
    • Journal Title

      Catalysis Science & Technology

      Volume: 2 Pages: 869-883

    • DOI

      doi:10.1039/C2CY00500J

    • Peer Reviewed
  • [Journal Article] Conversion of cellulose into renewable chemicals by supported metal catalysis2011

    • Author(s)
      H. Kobayashi, T. Komanoya, S. K.Guha, K. Hara, A. Fukuoka
    • Journal Title

      Applied Catalysis A: General

      Volume: 409-410(合併号) Pages: 13-20

    • DOI

      doi:10.1016/j.apcata.2011.10.014

    • Peer Reviewed
  • [Journal Article] Hydrodeoxygenation of Phenols as Lignin Models under Acid-Free Conditions withCarbon-Supported Platinum Catalysts2011

    • Author(s)
      H. Ohta, H. Kobayashi, K. Hara, A. Fukuoka
    • Journal Title

      Chemical Communications

      Volume: 47 Pages: 12209-12211

    • DOI

      doi:10.1039/c1cc14859a

    • Peer Reviewed
  • [Journal Article] Catalysis and Characterization of Carbon-Supported Ruthenium for Cellulose Hydrolysis2011

    • Author(s)
      T. Komanoya, H. Kobayashi, K. Hara, W. -J. Chun, A. Fukuoka
    • Journal Title

      Applied Catalysis A: General

      Volume: 407 Pages: 188-194

    • DOI

      doi:10.1016/j.apcata.2011.08.039

    • Peer Reviewed
  • [Journal Article] Hydrogenolysis of sugar beet fiber by supported metal catalyst2011

    • Author(s)
      S. K. Guha, H. Kobayashi, K. Hara, H.Kikuchi, T. Aritsuka, A. Fukuoka
    • Journal Title

      Catalysis Communications

      Volume: 12 Pages: 980-983

    • DOI

      doi:10.1016/j.catcom.2011.02.017

    • Peer Reviewed
  • [Journal Article] Synthesis of sugaralcohols by hydrolytic hydrogenation of cellulose over supported metal catalysts2011

    • Author(s)
      H. Kobayashi, Y. Ito, T. Komanoya, Y.Hosaka, P. L. Dhepe, K. Kasai, K. Hara, A. Fukuoka
    • Journal Title

      Green Chemistry

      Volume: 13 Pages: 326-333

    • DOI

      doi:10.1039/C0GC00666A

    • Peer Reviewed
  • [Journal Article] Transfer hydrogenation of cellulose to sugar alcohols over supported ruthenium catalysts2011

    • Author(s)
      H. Kobayashi, H. Matsuhashi, T.Komanoya, K. Hara, A. Fukuoka
    • Journal Title

      Chemical Communications

      Volume: 47 Pages: 2366-2368

    • DOI

      doi:10.1039/C0CC04311G

    • Peer Reviewed
  • [Journal Article] Recent Development in the Catalytic Conversion of Cellulose into Valuable Chemicals2011

    • Author(s)
      P. Yang, H. Kobayashi, A. Fukuoka
    • Journal Title

      Chinese Journal Catalysis

      Volume: 32 Pages: 716-722

    • DOI

      doi:10.1016/S1872-2067(10)60232-x

    • Peer Reviewed
  • [Journal Article] Water-TolerantMesoporous-Carbon-Supported Ruthenium Catalysts for the Hydrolysis of Cellulose to Glucose2010

    • Author(s)
      H. Kobayashi, T. Komanoya, K. Hara, A. Fukuoka
    • Journal Title

      ChemSusChem

      Volume: 3 Pages: 440-443

    • DOI

      doi:10.1002/cssc.200900205

    • Peer Reviewed
  • [Journal Article] Sustainable Green Catalysis by Supported Metal Nanoparticles2009

    • Author(s)
      A. Fukuoka, P. L. Dhepe
    • Journal Title

      The Chemical Records

      Volume: 9 Pages: 224-235

    • DOI

      doi:10.1002/tcr.200900004

    • Peer Reviewed
  • [Journal Article] Cellulose Conversion under Heterogeneous Catalysis2008

    • Author(s)
      P. L. Dhepe, A. Fukuoka
    • Journal Title

      ChemSusChem

      Volume: 1 Pages: 969-975

    • DOI

      doi:10.1002/cssc.200800129

    • Peer Reviewed
  • [Journal Article] Synthesis and utilisation of sugar compounds derived from lignocellulosic biomass

    • Author(s)
      H. Kobayashi, A. Fukuoka
    • Journal Title

      Green Chemistry

    • DOI

      doi:10.1039/c3gc00060e

    • Peer Reviewed
  • [Journal Article] Catalytic transformation of cellulose into platform chemicals

    • Author(s)
      M. Yabushita, H. Kobayashi, A. Fukuoka
    • Journal Title

      Applied Catalysis B: Environmental

    • DOI

      doi:10.1016/j.apcatb.2013.01.052

    • Peer Reviewed
  • [Presentation] 均一系触媒と不均一系触媒それぞれの立場から2013

    • Author(s)
      福岡淳
    • Organizer
      日本化学会第93春季年会
    • Place of Presentation
      立命館大学びわこくさつキャンパス(草津市)
    • Year and Date
      2013-03-21
  • [Presentation] Depolymerization of cellulose by heterogeneous catalysis2012

    • Author(s)
      A. Fukuoka
    • Organizer
      CSIRO Cutting Edge 2012 Symposium
    • Place of Presentation
      CSIRO Theatre(オーストラリア)
    • Year and Date
      2012-11-16
  • [Presentation] Conversion of cellulose into sugar compouns by carbon-based catalysts2012

    • Author(s)
      A. Fukuoka
    • Organizer
      CAT4BIO
    • Place of Presentation
      Classical Makedonia Palace Hotel(ギリシャ)
    • Year and Date
      2012-07-10
  • [Presentation] Conversion of lignocellulose into platform chemicals by carbon and supported metal catalysts2012

    • Author(s)
      A. Fukuoka
    • Organizer
      15^<th> International Congress on Catalysis
    • Place of Presentation
      International Congress Center Munich(ドイツ)
    • Year and Date
      2012-07-05
  • [Presentation] Conversion of lignocellulose into renewable chemicals by heterogeneous catalysis2011

    • Author(s)
      A. Fukuoka
    • Organizer
      第242回アメリカ化学会年会
    • Place of Presentation
      コロラドコンベンションセンター(アメリカ)
    • Year and Date
      2011-08-28
  • [Presentation] Cellulose conversion into renewable chemicals by supported metal catalysts2010

    • Author(s)
      A. Fukuoka
    • Organizer
      6th International Conference on Environmental Catalysis
    • Place of Presentation
      北京国際学術会館(中国)
    • Year and Date
      2010-09-13
  • [Presentation] Cellulose hydrolysis by supported metal catalysts2010

    • Author(s)
      A. Fukuoka
    • Organizer
      第239回アメリカ化学会年会
    • Place of Presentation
      The Moscone Center(アメリカ)
    • Year and Date
      2010-03-24
  • [Book] Catalytic Biomass Conversion, Elsevier2013

    • Author(s)
      H. Kobayashi, A. Fukuoka
    • Publisher
      New andFuture Developments in Catalysis
  • [Book] バイオマスリファイナリー触媒技術の新展開2011

    • Author(s)
      小林広和,福岡淳
    • Total Pages
      176-182
    • Publisher
      シーエムシー出版
  • [Book] 触媒調製ハンドブック2011

    • Author(s)
      小林広和,福岡淳
    • Total Pages
      632-633
    • Publisher
      エヌ・ティー・エス出版
  • [Book] Thermochemical Conversion of Biomass to Liquid Fuels and Chemicals2010

    • Author(s)
      S. K. Guha, H. Kobayashi, A. Fukuoka
    • Total Pages
      344-364
    • Publisher
      Royal Society of Chemistry
  • [Book] 現代界面コロイド科学の事典2010

    • Author(s)
      小林広和,福岡淳
    • Total Pages
      128-129
    • Publisher
      丸善
  • [Book] 木質系有機資源の新展開2009

    • Author(s)
      小林広和,福岡淳
    • Total Pages
      176-182
    • Publisher
      シーエムシー出版
  • [Remarks]

    • URL

      http://www.cat.hokudai.ac.jp/fukuoka/

  • [Patent(Industrial Property Rights)] 植物性バイオマスの分解方法2012

    • Inventor(s)
      藤田一郎、米田正、福岡淳、小林広和、藪下瑞帆
    • Industrial Property Rights Holder
      昭和電工、北海道大学
    • Industrial Property Number
      特許、特願第275516号
    • Filing Date
      2012-12-18
  • [Patent(Industrial Property Rights)] セルロースまたはヘミセルロース の加水分解触媒、並びにこの触媒を用い る糖含有液の製造方法2010

    • Inventor(s)
      福岡淳、小林広和、駒野谷将、 米田正、藤田一郎
    • Industrial Property Rights Holder
      北海道大学、昭和電工
    • Industrial Property Number
      特許、PCT/63284号
    • Filing Date
      2010-08-05
    • Overseas
  • [Patent(Industrial Property Rights)] 糖アルコールの製造方法2010

    • Inventor(s)
      福岡淳、小林広和
    • Industrial Property Rights Holder
      北海道大学、昭和電工
    • Industrial Property Number
      特許、特願第164279号
    • Filing Date
      2010-07-21
  • [Patent(Industrial Property Rights)] 多孔性炭素材料または金属担持多孔性炭素材料を用いたセルロース分解用触媒、並びにこの触媒を用いる糖含有液の製造方法2009

    • Inventor(s)
      福岡淳、小林広和、駒野谷将
    • Industrial Property Rights Holder
      北海道大学
    • Industrial Property Number
      特許、特願第220087号
    • Filing Date
      2009-09-25
  • [Patent(Industrial Property Rights)] 農産物または農産副産物からの糖アルコール及び糖の製造方法2008

    • Inventor(s)
      菊地裕人、福岡淳
    • Industrial Property Rights Holder
      日本甜菜製糖、北海道大学
    • Industrial Property Number
      特許、特願第313590号
    • Filing Date
      2008-12-09

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Published: 2014-08-29  

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